4.6 Article

A high-rate cathode material hybridized by in-site grown Ni-Fe layered double hydroxides and carbon black nanoparticles

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 4, Issue 13, Pages 4877-4881

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ta00842a

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Funding

  1. Key Project of Hunan Provincial Science and Technology Plan of China [2014FJ2007]
  2. Fundamental Research Funds for the Central Universities [2011JQ024]

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A facile hydrothermal fabrication was applied to hybridize in-site grown flower-like Ni-Fe layered double hydroxides (Ni-Fe LDHs) and carbon black (CB) nanoparticles. The well-conductive CB particles were dispersed homogeneously onto the petals of the Ni-Fe LDH flowers via a combination of electrostatic forces and ripening growth, and remarkably promoted the charge-transfer capability of the LDHs. The hybridized Ni-Fe LDH/ CB composite electrode exhibited excellent rate performance that retained both a high capacity and steady cycle life at a large charge-discharge current, and was highly competitive serving as a high-rate alkaline battery cathode.

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