Journal
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 4, Issue 7, Pages 3757-3765Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.6b00397
Keywords
Polylactide; Biodegradable; Stereocomplex; Homocomposites; Impact modifier
Categories
Funding
- Swedish Research Council, VR [A0347801]
- ERC Advance Grant, PARADIGM [246776]
- European Commission
- Region Wallonne FEDER program in the frame of Pole d'Excellence Materia Nova
- OPTI2MAT program of excellence
- Interuniversity Attraction Poles program
- Belgian Federal Science Policy Office [PAI P7/05]
- FNRS-FRFC
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Restrained properties of green degradable products drive the creation of materials with innovative structures and retained eco-attributes. Herein, we introduce the creation of impact modifiers in the form of core-shell (CS) particles toward the creation of green composite materials. Particles with CS structure constituted of PLA stereocomplex (PLASC) and a rubbery phase of poly(epsilon-caprolactone-co-D,L-lactide) (P[CL-co-LA]) were successfully achieved by spray droplet atomization. A synergistic association of the soft P[CL-co-LA] and hard PLASC domains in the core-shell structure induced unique thermo-mechanical effects on the PLA-based composites. The core-shell particles enhanced the crystallization of PLA matrices by acting as nucleating agents. The core-shell particles functioned efficiently as impact modifiers with minimal effect on the composites stiffness and strength. These findings provide a new platform for scalable design of polymeric-based structures to be used in the creation of advanced degradable materials.
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