4.7 Article

Rapid Determination of Polymer Stereoregularity Using Band Selective 2D HSQC

Journal

ACS MACRO LETTERS
Volume 5, Issue 2, Pages 181-184

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsmacrolett.5b00866

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Funding

  1. National Science Foundation [CHE-1413862]
  2. Direct For Mathematical & Physical Scien
  3. Division Of Chemistry [1413862] Funding Source: National Science Foundation

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We report the use of band-selective 2D HSQC NMR spectroscopy to rapidly determine the stereoregularity of polymers usually analyzed by 1D C-13 NMR spectroscopy. This approach reduced the time required to characterize the triad stereosequences of polyacrylonitrile from about an hour to a few minutes, and can be performed with sufficient C-13 resolution to resolve higher-order stereosequences, such as the pentads of polypropylene.

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