Article
Energy & Fuels
Yuanfei Bao, Jianliang Liu, Yige Zhang, Liping Zheng, Jiacong Ma, Fei Zhang, Yubing Xiong, Xiangju Meng, Zhifeng Dai, Feng-Shou Xiao
Summary: In this study, porous organic polymers (POPs) with diverse quaternary phosphonium units were synthesized and used as catalysts for cycloaddition reaction of CO2 and epoxides. The POPs exhibited excellent catalytic properties even under mild conditions and without the need for a co-catalyst. The catalytic activities of the POPs were found to increase with the steric hindrance of the quaternary phosphonium units.
Article
Chemistry, Applied
Siraprapa Somsri, Mohan Gopalakrishnan, Thanchanok Ratvijitvech, Thanapat Worakul, Panida Surawatanawong, Naoto Kuwamura, Takumi Konno, Bunyarat Rungtaweevoranit, Preeyanuch Sangtrirutnugul
Summary: The utilization of CO2 to produce value-added products is a promising strategy to reduce CO2 emissions. Nitrogen-rich porous polymers were prepared using copper-catalyzed azide-alkyne cycloaddition and Huisgen cycloaddition, exhibiting high copper loading ability and high CO2 selectivity.
REACTIVE & FUNCTIONAL POLYMERS
(2023)
Article
Chemistry, Physical
Xiaofeng Zhang, Junhao Ding, Bo Qiu, Dajian Li, Yunpeng Bian, Dandan Zhu, Shimin Wang, Wenpeng Mai, Shujun Ming, Jian Chen, Tao Li
Summary: The study developed a green synthesis method to prepare porous organic polymers and designed efficient catalysts for the fixation of CO2 into cyclic carbonates. This provided an effective strategy for addressing the key challenge of CO2 transformation.
Article
Chemistry, Multidisciplinary
Basiram Brahma Narzary, Ulzhalgas Karatayeva, Jerry Mintah, Marcos Villeda-Hernandez, Charl F. J. Faul
Summary: Two metal-free perylene-based porous polyimides (pPIs) were synthesized, which exhibited excellent catalytic activities for cycloaddition of CO2 and electroreduction of CO2 to formate and methanol. The pPIs can be recycled and reused multiple times without loss of catalytic activity.
MATERIALS CHEMISTRY FRONTIERS
(2023)
Article
Polymer Science
Zhenwei Zhang, Xiaochen Shen, Ziping Li, Si Ma, Hong Xia, Xiaoming Liu
Summary: The study obtained a series of high-performance chiral cationic porous organic polymers, which have excellent pore structure and chemical stability, and exhibit good catalytic performance as organocatalysts in reactions.
Article
Chemistry, Multidisciplinary
Mingan Chen, Hui Yang, Ming Wah Wong
Summary: Our study reveals a new mechanism for CO2 fixation onto cyclic carbonates, which differs from the commonly accepted mechanism with alternate epoxide and CO2 activation steps and a nested CO2 activation pathway. The general applicability of this mechanism was demonstrated through reactions catalyzed by two different catalysts.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Physical
Sangita Karanjit, Emiko Tanaka, Lok Kumar Shrestha, Atsushi Nakayama, Katsuhiko Ariga, Kosuke Namba
Summary: A silica-supported bifunctional heterogeneous catalytic system was developed for efficient carboxylative cyclization of alcohols using CO2. The catalyst is stable, versatile, and can be easily stored and reused.
CATALYSIS SCIENCE & TECHNOLOGY
(2022)
Article
Engineering, Chemical
Yaju Chen, Qinggang Ren, Xiaojing Zeng, Leiming Tao, Xiantai Zhou, Hongbing Ji
Summary: This work describes a pre- and post-synthetic strategy to design metalloporphyrin-based azo-hierarchical porous ionic polymers, which showed great CO2 uptake and catalytic conversion efficiency. The synthesized polymer exhibited features like improved surface area, hierarchical porosity, high-density active sites, along with recyclability and retention of activity over multiple cycles. Additionally, it demonstrated effective catalytic activity in converting diluted CO2 to produce desired products under mild conditions.
CHEMICAL ENGINEERING SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Ya-Li Wan, Zemin Zhang, Chao Ding, Lili Wen
Summary: This study developed a facile method for preparing hydrogen bond donors functionalized porous ionic polymers using free-radical polymerization and HBDs functionalization reactions. Among the synthesized bifunctional PIPs, the catalyst with carboxyl groups showed better catalytic performance in CO2 cycloaddition compared to the one with hydroxyl groups, and the HBDs-free catalyst exhibited the lowest activity. The catalyst with carboxyl groups demonstrated high catalytic activity, excellent reusability, and broad substrate tolerance under atmospheric CO2 pressure and co-catalyst free conditions.
JOURNAL OF CO2 UTILIZATION
(2021)
Article
Chemistry, Applied
Gen Li, Xue Zhou, Zhonggang Wang
Summary: In this study, porous polyaminals based on porphyrins and cobalt (II)-metallated porphyrins were synthesized and shown to exhibit excellent performance in CO2 adsorption and cycloaddition reactions.
MICROPOROUS AND MESOPOROUS MATERIALS
(2022)
Article
Engineering, Chemical
Changqing Guo, Guanghui Chen, Ning Wang, Shougui Wang, Yuwen Gao, Jipeng Dong, Qing Lu, Fei Gao
Summary: Several multifunctional histidine-based hypercrosslinked ionic polymers (HIPs) were synthesized via a one-pot copolymerization strategy, and their CO2 adsorption and conversion properties were investigated. The HIPs exhibited hierarchical pore structure and incorporated abundant hydrogen bond donors, nucleophilic ionic sites, and Lewis bases. The optimized HIP-Br-His showed a high CO2 capture capacity and excellent catalytic activity in the cycloaddition of CO2 to propylene oxide, highlighting its potential as a heterogeneous catalyst for efficient CO2 capture and conversion.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Chemistry, Physical
Lin Gong, Ji Sun, Yousong Liu, Guangcheng Yang
Summary: This study demonstrates the efficient use of solar energy to drive CO2 cycloaddition conversion under mild reaction conditions using a Zn single-atom-loaded N-doped carbon catalyst. The catalyst shows high catalytic activity with almost complete CO2 conversion yields, providing unprecedented findings for the future design and application of single-atom catalysts in photoinduced CO2 cycloaddition catalysis or other catalytic reactions.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Applied
Shilin Lai, Jinbin Gao, Xingquan Xiong
Summary: Efficient, green, and recyclable heterogeneous catalysts for the conversion of CO2 into cyclic carbonates under atmospheric pressure conditions are challenging to develop. In this study, rosin-based porous heterogeneous catalysts MPAc-Br and MPAc-OH-Br were synthesized and the bifunctional catalyst MPAc-OH-Br showed higher catalytic activity (up to 99% yields) for CO2 conversion. The catalyst exhibited good stability and reusability, making it a promising candidate for sustainable CO2 conversion processes.
REACTIVE & FUNCTIONAL POLYMERS
(2021)
Article
Chemistry, Applied
Zhifeng Dai, Yongquan Tang, Fei Zhang, Yubing Xiong, Sai Wang, Qi Sun, Liang Wang, Xiangju Meng, Leihong Zhao, Feng-Shou Xiao
Summary: The study focuses on the transformation of CO2 into cyclic carbonates, using a series of porous organic catalysts that show excellent recyclability and catalytic performance. These catalysts hold promise for converting industrially generated CO2 into high value-added chemicals.
CHINESE JOURNAL OF CATALYSIS
(2021)
Article
Chemistry, Multidisciplinary
Arkaprabha Giri, Abhijit Patra
Summary: This research introduces the application of porous organic polymers (POPs) in heterogeneous catalysis. Amorphous POPs activate substrates or encapsulate catalytically active metal centers, while conjugated POPs are used for photoinduced chemical transformations. The authors summarize their research achievements over the past ten years and discuss the prospects of POPs and POP-based hybrid materials in future catalytic applications.
