Journal
ACS CATALYSIS
Volume 6, Issue 3, Pages 2043-2046Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.5b02916
Keywords
rhodium; cyclobutadiene; reductive amination; homogeneous catalysis; chemoselectivity; amines
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Funding
- Russian Foundation for Basic Research [15-03-02548A]
- Council of the President of the Russian Federation [MK-6137.2015.3, MK-6254.2016.3]
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A catalyst of a new type, cyclobutadiene complex [(C4Et4)Rh(p-xylene)]PF6, was found to promote selective reductive amination in the presence of carbon monoxide under mild conditions (1-3 bar, 90 degrees C). The reaction demonstrated perfect compatibility with a wide range of functional groups prone to reduction by conventional reducing agents. The developed system represents the first systematic investigation of cyclobutadiene metal complexes as catalysts.
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