Journal
AEROSOL AND AIR QUALITY RESEARCH
Volume 15, Issue 5, Pages 2094-2103Publisher
TAIWAN ASSOC AEROSOL RES-TAAR
DOI: 10.4209/aaqr.2015.03.0176
Keywords
Elemental mercury; Multipollutant control; Metal oxide; Activated carbon; Coal combustion
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Funding
- Ministry of Science and Technology, Taiwan [100-2221-E-002-256-MY3]
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This research investigated the effects of transition metal oxide impregnation on the physical/chemical properties and on the multipollutant (i.e., Hg-0/SO2/NO) control of a commercial coconut shell-based activated carbon. V, Mn, and Cu oxides of 5 wt% as their precursor metal hydroxides were impregnated onto the activated carbon surface. After the transition metal oxide impregnation, the surface area and pore volume of activated carbon decreased. The surface morphology of activated carbons was similar prior to and after impregnation. Mn3+/Mn4+ and Cu+/Cu2+ were shown to be the major valence states presenting in the MnOx and CuOx/CAC samples, respectively. CuOx/CAC possessed the greatest Hg-0 removal efficiency of approximately 54.5% under N-2 condition and 98.9% under flue gas condition, respectively at 150 degrees C. When the gas temperature increased to 350 degrees C, the metal oxide-impregnated activated carbon still possessed appreciable Hg0 removal, especially for CuOx/CAC. The VOx/CAC had the largest SO2 removal enhancement of approximately 28.3% at 350 degrees C. The NO removal of raw and impregnated activated carbon was very small under flue gas condition, indicating that adsorption of NO using metal oxide-impregnated activated carbon may not be a suitable route for NO control.
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