Article
Environmental Sciences
Xinyue Ma, Qiao Li, Rui Li, Wei Zhang, Xiuyun Sun, Jiansheng Li, Jinyou Shen, Weiqing Han
Summary: This study synthesized sulphidated ferrihydrite with different S:Fe molar ratios and found that sulphidated ferrihydrite with an S:Fe molar ratio of 0.74 exhibited a strong affinity towards Sb(V), making it a promising material for eliminating Sb(V) contamination from water.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2022)
Article
Chemistry, Multidisciplinary
Philip Netzsch, Regina Stroh, Florian Pielnhofer, Ingo Krossing, Henning A. Hoeppe
Summary: Borosulfates offer fascinating structures and properties beyond pure silicate analogy. Mg-3[H2O -> B(SO4)(3)](2) is the first borosulfate with a boron atom coordinated by three tetrahedra, exhibiting higher Lewis and Brønsted acidity.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Marcel Schorpp, Ravi Yadav, Daniel Roth, Lutz Greb
Summary: This paper describes a strategy to unleash Lewis superacidity by electromerism, where coordinating a Lewis base to Delta-calix[4]pyrrolato-antimony(III) triggers a ligand redox-noninnocent coupled transfer into antimony(V)-state that exhibits Lewis superacidic features. This approach of Lewis acidity by electromerism establishes a concept of potential generality for powerful yet robust reagents and on-site substrate activation approaches.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Inorganic & Nuclear
Fabian Schaefer, Jan-Hendrik Lamm, Beate Neumann, Hans-Georg Stammler, Norbert W. Mitzel
Summary: Connecting various organic spacer functions via silicon core units leads to organosilanes suitable as backbones for poly-Lewis acids, resulting in rigid and flexible PLAs. Solid-state structures and host-guest experiments demonstrate the characteristics of these PLAs, showing their ability to complex with neutral guest molecules.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Physical
Rui Xu, Qian Li, Xiaolong Nan, Guoqing Jiang, Limin Wang, Jing Xiong, Yongbin Yang, Bin Xu, Tao Jiang
Summary: A green kaolin@Fe-Mn binary (hydr)oxides composite synthesized by iron oxidizing bacteria (IOB) mediation was developed as a potential adsorbent for the simultaneous removal of antimony (Sb) and arsenic (As) from contaminated water. The composite showed high specific surface area and pore volume, and exhibited efficient removal of Sb and As with adsorption capacities of 177.19, 56.26, 62.92, and 42.18 mg/g for Sb(III), Sb(V), As(III), and As(V), respectively. The kinetics data followed the pseudo-second-order kinetic and Elovich models, and the mechanism of adsorption involved inner-sphere complexation, surface complexation, hydrogen bonding, and oxidation.
APPLIED CLAY SCIENCE
(2022)
Article
Engineering, Environmental
Chi Zhang, Libin Liu, Xueyao Chen, Yunchao Dai, Hanzhong Jia
Summary: This study investigates the complexation mechanism of Sb(V) onto montmorillonite at the molecular scale through first-principles molecular dynamics simulations. The results show that Sb-Al/Fe complexes are more favorable in the interlayer space, and Sb-Al bidentate complex is the most stable and favorable edge species on edge surfaces.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Environmental Sciences
Yongchao Zhou, Wenxin Zheng, Wenming Zhang, Yiping Zhang, Lei Fang
Summary: In this study, electrocoagulation (EC) with composite scrap iron and manganese filings as an anode (Fe-Mn EC) was investigated for the efficient removal of pentavalent antimony (Sb(V)). The results showed that Fe-Mn EC enhanced the removal of Sb(V) by 11.18-17.36% compared to traditional iron electrocoagulation (Fe EC). The removal rate of Sb(V) increased with the current concentration and Mn content in the anode, but was inhibited when the Mn content exceeded 20%. Analysis of the flocs generated during Fe and Fe-Mn EC revealed that the Fe-Mn flocs had a higher Sb(V) adsorption rate and capacity compared to Fe flocs, with a structure of nanometer flakes and large internal surface areas. Thermodynamics constants indicated that adsorption was associated with monolayer physical adsorption. This study provides a new idea and potential technical support for the removal of Sb(V) by introducing composite scrap iron-manganese as an anode in electrocoagulation.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Chemistry, Inorganic & Nuclear
Eva M. Heppke, Steffen Klenner, Oliver Janka, Rainer Poettgen, Thomas Bredow, Martin Lerch
Summary: A new member, Cu2ZnSbS4, within the A(2)IB(II)C(IV)X(4) compound family was successfully synthesized using ball milling and postannealing in H2S-atmosphere, and showed isostructural similarity with Cu3SbS4. Both compounds exhibit monovalent diamagnetic copper and substantial covalent bonding, as confirmed by Mossbauer spectroscopy and electronic structure calculations.
INORGANIC CHEMISTRY
(2021)
Article
Environmental Sciences
Tianning Wang, Yonghong Jiao, Mengchang He, Wei Ouyang, Chunye Lin, Xitao Liu
Summary: The study successfully co-eliminated aquatic As(V) and Sb(V) using Fe-Cu (FC) binary materials, with a determined optimal Fe/Cu ratio increasing co-adsorption capacity. Morphological and structural analyses revealed changes in material properties with increasing Cu content.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Materials Science, Multidisciplinary
K. Abouabassi, M. Ouafi, A. Ait Hssi, L. Atourki, H. Kirou, N. Labchir, L. Boulkaddat, E. Gilioli, A. Sala, A. Elfanaoui, A. Taleb, K. Bouabid, A. Ihlal
Summary: In this study, high-quality Sb2Se3 thin films were prepared using electrodeposition and annealing processes. The effects of bath solution pH and applied potential on the film properties were investigated.
Article
Environmental Sciences
Saeed Bagherifam, Sridhar Komarneni, Eric D. van Hullebusch, Marija Stjepanovic
Summary: The study found that Fe(III)-modified montmorillonite can efficiently remove up to 95% of Sb(V) from aqueous solutions and effectively immobilize Sb(V) in soils, reducing the concentrations of Sb(V) significantly in both exchangeable fraction and distilled water extracts. Additionally, the bioaccessibility of Sb(V) in simulated human gastric juice decreased remarkably, confirming the potential of Fe-Mt for remediation of Sb(V) in terrestrial environments.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Article
Chemistry, Multidisciplinary
Chih-Chung Lai, Feng-Hao Hsu, Su-Yang Hsu, Ming-Jay Deng, Kueih-Tzu Lu, Jin-Ming Chen
Summary: By utilizing agarose as a novel binder, an activated carbon supercapacitor with a wider potential window was successfully fabricated, leading to enhanced energy density and excellent cycling performance.
Article
Chemistry, Physical
Tripti Chhabra, Suman Dhingra, C. M. Nagaraja, Venkata Krishnan
Summary: This study investigates the influence of Lewis and Bronsted acidic sites on metal-free graphitic carbon nitride catalysts for the conversion of monosaccharides to 5-hydroxymethylfurfural. By doping boron and functionalizing with sulfonic acid, different acidic sites combinations were tested with varying yields of the desired product. This research provides insights on the optimal acidic sites composition for biomass conversion reactions.
Article
Chemistry, Inorganic & Nuclear
Sarah B. Duckworth, Xavier Gaona, Alexander Baumann, Kathy Dardenne, Joerg Rothe, Dieter Schild, Marcus Altmaier, Horst Geckeis
Summary: This study investigated the solubility of Tc-99(IV) under undersaturation conditions in various salt systems with different pH ranges. The results indicated that Tc exists predominantly in its +IV redox state and the presence of sulfate has minimal impact on its solubility.
Article
Biochemistry & Molecular Biology
Ivan V. Smolyaninov, Georgy K. Fukin, Nadezhda T. Berberova, Andrey I. Poddel'sky
Summary: A new series of triphenylantimony(V) complexes with different substituents were synthesized and characterized, showing variations in their crystal structures, electrochemical oxidation behavior, and radical scavenging activities.
Article
Chemistry, Multidisciplinary
Gyeongjin Park, Mohammadjavad Karimi, Wei-Chun Liu, Francois P. Gabbai
Summary: By discovering suitable metal platforms and utilizing specific ligands, efficient photoreductive halogen elimination reactions can be achieved under visible light. The xanthylium unit in the [7](+) complex plays a crucial role in promoting the high quantum yield of the visible-light-induced photoreduction process.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Multidisciplinary
Elishua D. Litle, Francois P. Gabbai
Summary: This study reports on the formation process of M -> C-carbenium bonds in a series of Group 10 complexes and confirms their dative nature through combined experimental and computational studies.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Inorganic & Nuclear
Mohammadjavad Karimi, Francois P. Gabbai
Summary: This study reports the synthesis and photoreduction of a complex featuring a tetravalent platinum center connected to a germyl ligand. In the presence of a chlorine trap, the complex undergoes a clean photolysis to produce two different products, which were confirmed and quantified using NMR spectroscopy and GC-MS analysis.
Article
Chemistry, Multidisciplinary
Mohammadjavad Karimi, Elishua Litle, Francois P. Gabbai
Summary: In this study, gold complexes with halogermanes as ligands were synthesized and investigated. Experimental and computational analyses revealed the presence of an Au -> Ge interaction in these complexes. Chloride abstraction reactions were also studied, and a putative dication was formed by double chloride abstraction with AgSbF6. This dication showed higher catalytic activity than its monocationic analog in alkyne hydroamination reactions.
ISRAEL JOURNAL OF CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Elishua D. Litle, Francois P. Gabbai
Summary: In this study, two compounds were synthesized to investigate the interaction of gold with fluorenyl cation. Computational results showed that one of the compounds possesses a strong Au -> C+ bond and can effectively activate enyne compounds.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Francois P. Gabbai, Jesse E. Smith
Summary: As part of our investigations into the Lewis acidic behavior of antimony derivatives, we studied the properties of 5-phenyl-5,5-dichloro-lambda 5-dibenzostibole (1), a dichlorostiborane with an antimony atom confined to a five-membered heterocycle. Our work confirmed that the geometric constraints of this compound enhance the Lewis acidity of the antimony atom, as evidenced by crystal structure analysis and solution studies. The compound's enhanced Lewis acidic properties were also observed in pnictogen bonding catalysis experiments involving imine reductions.
Article
Chemistry, Multidisciplinary
Wei-Chun Liu, Francois P. Gabbai
Summary: We have described a new gold chloride complex with an ambiphilic phosphine/xanthylium ligand, in which the AuCl interacts with the pi(+) surface of the xanthylium unit. Energy decomposition analyses on a model system revealed the dominance of non-covalent interactions, particularly electrostatic and dispersion terms. The presence of these AuCl-pi(+) interactions correlates with the high catalytic activity of the complex in various cyclisation reactions.
Article
Chemistry, Multidisciplinary
Benyu Zhou, Francois P. Gabbai
Summary: This study investigates the reaction of O-2 with two distibines in the presence of an ortho-quinone, resulting in the formation of tetraolate complexes. The formation process involves oxidation of the antimony atoms to the +V state and the formation of an alpha,alpha,beta,beta-tetraolate ligand that bridges the two antimony(V) centers. Under aerobic conditions, the tetraolate complexes react with O-2 to form semiquinone/peroxoantimony intermediates and then evolve into bis(antimony(V)) alpha,alpha,beta,beta-tetraolate complexes. The controlled protonolysis and reduction of the bis(antimony(V)) alpha,alpha,beta,beta-tetraolate complexes regenerate the starting distibine and ortho-quinone, producing two equivalents of water as the product of O-2 reduction.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Inorganic & Nuclear
Logan T. Maltz, Francois P. Gabbai
Summary: We present the findings of a computational study on the binding of fluoride by various pentavalent pnictogen Lewis acids. Through activation strain and energy decomposition analyses, we identified the electrostatic and orbital contributions to these acid-base interactions, as well as the significance of Pauli repulsion and molecular flexibility in determining relative Lewis acidity among the pnictogens. Our results highlight antimony-based species as the strongest fluoride binders, and emphasize the importance of Pauli repulsion and molecular flexibility in determining this relative Lewis acidity.
INORGANIC CHEMISTRY
(2023)
Review
Chemistry, Multidisciplinary
Brendan L. Murphy, Francois P. Gabbai
Summary: This article introduces the research on the use of antimony compounds as new platforms for anion capture, sensing, and transport, emphasizing the excellent Lewis acidic properties of antimony and its potential in supramolecular chemistry and catalysis. It also mentions the recent advances in anion sensing in aqueous media and anion binding catalysis and anion transport across phospholipid membranes.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Inorganic & Nuclear
Asima Munawar, Logan T. Maltz, Wei-Chun Liu, Francois P. Gabbai
Summary: This study presents the design of a novel ligand structure, allowing facile introduction of cationic charge through methylation, to investigate the effect of positive charge insertion on the catalytic activity of gold catalysts. Experimental results demonstrate significant differences in catalytic activity between neutral and cationic gold species.
Article
Chemistry, Multidisciplinary
Alessio Cataldo, Matus Chvojka, Gyeongjin Park, Vladimir Sindelar, Francois P. Gabbai, Stephen J. Butler, Hennie Valkenier
Summary: Here we introduce a novel approach using a europium(iii) complex to monitor the transmembrane transport of fluoride into liposomes. By utilizing the long emission lifetime of this probe, we are able to accurately measure the transport activity of fluorescent transporters. The high sensitivity, selectivity, and versatility of this assay enable us to investigate various types of fluoride transporters and unravel their mechanisms of action.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Benyu Zhou, Shantabh Bedajna, Francois P. Gabbai
Summary: The design of a gold catalyst activation system through the formation of a pnictogen bond with a neighboring antimony unit is described. The resulting complex shows efficient catalytic reactivity, possibly through an intramolecular Au-Cl -> Sb(v) interaction for carbophilic catalysis.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Logan T. Maltz, Lewis C. Wilkins, Francois P. Gabbai
Summary: We synthesized and characterized two phosphine gold carbinol species designed to enhance intramolecular Au-M hydrogen bonding. By substituting the chloride ligand with a phenyl group, we observed a significant increase in the strength of this hydrogen bond, which was analyzed both experimentally and computationally.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
George Rajendra Kumar, Mengxi Yang, Benyu Zhou, Francois P. Gabbai
Summary: The synthesis, structure, and characterization of an antimony-rhodamine derivative with a phenyl-antimony moiety installed at the 10' position of the central ring are described. This compound exhibits red fluorescence (lambda(em) = 655 nm) with a quantum yield of 12% in acetonitrile.
MENDELEEV COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Alexander M. Prophet, Kritanjan Polley, Gary J. Van Berkel, David T. Limmer, Kevin R. Wilson
Summary: The oxidation kinetics of iodide by ozone at the air-water interface is studied in single microdroplets. Molecular simulations and kinetic modeling are used to understand the underlying multiphase mechanism.
Article
Chemistry, Multidisciplinary
Rong Zhang, Jiajing Lan, Fei Wang, Shumei Chen, Jian Zhang
Summary: By utilizing 1,1'-ferrocene dicarboxylic acid as a chelating and surface protection ligand, we have synthesized multi-nuclear indium oxide clusters with varying nuclear sizes, including heptanuclear and thirteen-nuclear clusters. These clusters possess labile coordination sites, allowing for structural modification and self-assembly, resulting in the formation of various cluster structures.
Article
Chemistry, Multidisciplinary
Hui Wang, Hui Liu, Mingsen Wang, Jiaheng Hou, Yongjun Li, Yuancheng Wang, Yingjie Zhao
Summary: Two supramolecular complexes were prepared using CBs and M1, and their single-crystal structures were analyzed by SCXRD. The unexpected 1:2 self-assembly structure between M1 and CB[8] was discovered for the first time. These complexes exhibit unique photophysical properties and provide valuable information about the structure and photophysical properties of supramolecular complexes.
Article
Chemistry, Multidisciplinary
Chang-Hee Lee, Sookil Park, Sanggil Kim, Ji Young Hyun, Hyun Soo Lee, Injae Shin
Summary: The epidermal growth factor receptor (EGFR) is a cell-surface glycoprotein involved in cell proliferation and tumor development. This study used a fluorescently labeled EGFR to investigate its time-dependent endocytosis in live cells and found that appended glycans affect EGFR internalization. Additionally, the study detected sialic acid residues attached to EGFR on the live cell surface using FRET-based imaging. This research provides valuable insights into the cellular functions of EGFR.
Article
Chemistry, Multidisciplinary
Subhankar Sahu, Lokesh Kumar, Sumita Das, Dipti Gupta, Ruchi Anand
Summary: This study proposes a strategy that combines organic electronics with biosensor scaffolds to create a compact device for monitoring environmental aromatic pollution. By coupling biosensing protein MopR with an organic electrochemical transistor (OECT), a sensor module capable of efficient detection of phenol was designed. Exclusive phenol detection with minimal loss of sensitivity could be achieved in complex pollutant mixtures and real environmental samples.
Review
Chemistry, Multidisciplinary
Changseok Lee, Hyung-Joon Kang, Sungwoo Hong
Summary: The formation of C-N bonds through hydroamination reactions catalyzed by nickel hydrides has been a topic of recent interest. This approach offers a way to efficiently transform a variety of alkene and alkyne substrates into compounds enriched with C-N bonds. The review provides a concise overview of the underlying reaction mechanisms and aims to stimulate further progress in NiH-catalytic techniques and catalyst design.
Article
Chemistry, Multidisciplinary
Yueci Wu, Lu-Lu Sun, Hai-Hao Han, Xiao-Peng He, Weiguo Cao, Tony D. James
Summary: Drug-induced liver injury (DILI) is a common cause of acute liver failure in the USA and Europe, but most cases can be recovered or prevented by discontinuing the offending drug. Recent research has found that peroxynitrite (ONOO-) can be used as a potential indicator for early diagnosis of DILI, and there is an urgent need to establish a method to detect and track peroxynitrite in DILI cases. In this study, a FRET-based nano fluorescent probe CD-N-I was developed, which showed high selectivity and sensitivity in detecting peroxynitrite. The probe successfully detected exogenous peroxynitrite in live cells and endogenous peroxynitrite in APAP-induced liver injury of HepG2 cells.
Article
Chemistry, Multidisciplinary
Dmitry L. Lipilin, Mikhail O. Zubkov, Mikhail D. Kosobokov, Alexander D. Dilman
Summary: This article describes a direct photocatalytic method for the thiolation of unprotected acids, which was previously challenging. By using a thionocarbonate reagent with an N-O bond, the efficient conversion of carboxylic acids to thiols is achieved.
Article
Chemistry, Multidisciplinary
Jason Malenfant, Lucille Kuster, Yohann Gagne, Kouassi Signo, Maxime Denis, Sylvain Canesi, Mathieu Frenette
Summary: Raman microscopy can reveal compound-specific vibrational fingerprints without sample preparation. The combination of efficient theoretical calculations and a user-friendly software can accurately predict peak positions and provide match scores to assist with structure determination.
Article
Chemistry, Multidisciplinary
Jayoh A. Hernandez, Paul S. Micus, Sean Alec Lois Sunga, Luca Mazzei, Stefano Ciurli, Gabriele Meloni
Summary: Essential trace metals play crucial roles in the survival and virulence of bacterial pathogens. Helicobacter pylori requires nickel for colonization and persistence in the stomach, and NixA is an essential nickel transporter in this process. This study characterizes the selectivity and electrogenic nature of NixA-mediated nickel transport.
Article
Chemistry, Multidisciplinary
Tarali Devi, Kuheli Dutta, Jennifer Deutscher, Stefan Mebs, Uwe Kuhlmann, Michael Haumann, Beatrice Cula, Holger Dau, Peter Hildebrandt, Kallol Ray
Summary: This study emphasizes the importance of subtle electronic changes and secondary interactions in the stability of biologically relevant metal-dioxygen intermediates. It also shows that the role of the chloride ligand in stabilizing the Fe-III-(OOBu)-Bu-t moiety can extend to other anions, including the thiolate ligand.
Article
Chemistry, Multidisciplinary
Jacqueline R. Santhouse, Jeremy M. G. Leung, Lillian T. Chong, W. Seth Horne
Summary: By studying the folding kinetics and mechanism of the BdpA sequence, researchers found that altering the backbone connectivity can affect protein folding. This suggests that protein mimetic chains have a significant degree of plasticity in transitioning between unfolded and folded states.
Article
Chemistry, Multidisciplinary
Divanshu Gupta, Ralf Einholz, Holger F. Bettinger
Summary: This study presents the first direct spectroscopic evidence of a cyclic seven-membered iminoborane. Compared to linear amino-iminoboranes, this cyclic iminoborane exhibits weakened bond strength and lower Lewis acidity value. The study suggests that the reduced ring strain of cyclic iminoborane prevents nitrogen fixation but allows facile (2 + 2) cycloaddition reaction with C2H4.
Article
Chemistry, Multidisciplinary
Renny Mathew, Aniruddha Mazumder, Praveen Kumar, Julie Matula, Sharmarke Mohamed, Petr Brazda, Mahesh Hariharan, Brijith Thomas
Summary: This study reveals the packing arrangement of partially disordered nitro-perylenediimide (NO2-PDI) using a synergistic approach that combines 3D ED, ssNMR, and DFT techniques. By overcoming these challenges, this methodology opens up new avenues for material characterization, driving exciting advancements in the field.