Journal
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
Volume 71, Issue 7, Pages 737-764Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1515/znb-2016-0101
Keywords
cerium compounds; crystal structure; intermetallics; physical properties; structure-property relationship
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Funding
- Deutsche Forschungsgemeinschaft
- NRW Forschungsschule Molecules and Materials - A Common Design Principle
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Intermetallic compounds with the equiatomic composition CeTX that crystallize with the orthorhombic TiNiSi-type structure can be synthesized with electron-rich transition metals (T) and X = Zn, Al, Ga, Si, Ge, Sn, As, Sb, and Bi. The present review focusses on the crystal chemistry and chemical bonding of these CeTX phases and on their physical properties, Sn-119 and Sb-121 Mossbauer spectra, high-pressure effects, hydrogenation reactions and the formation of solid solutions in order to elucidate structure-property relationships. This paper is the final one of a series of four reviews on equiatomic intermetallic cerium compounds [Part I: Z. Naturforsch. 2015, 70b, 289; Part II: Z. Naturforsch. 2015, 70b, 695; Part III: Z. Naturforsch. 2016, 71b, 165].
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