Journal
TETRAHEDRON
Volume 72, Issue 38, Pages 5818-5823Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2016.08.012
Keywords
Copper catalyst; Diarylation; Chalcogen; Arylboronic acid; Oxidative coupling
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Transition metal-catalyzed diarylations of sulfur, selenium and tellurium were achieved using arylboronic acids in air. A copper-catalyzed reaction of sulfur or selenium efficiently yielded numerous symmetrical diaryl sulfides or selenides in the presence of NH4BF4. However, the diarylation of tellurium was not possible using this method, and required a palladium catalyst in the presence of KI and air for the reaction to proceed. (C) 2016 Elsevier Ltd. All rights reserved.
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