Journal
SYNTHESIS-STUTTGART
Volume 48, Issue 22, Pages 3863-3878Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1562520
Keywords
amine; alcohols; carbon dioxide; heterocycles; homogeneous catalysis; substrate activation
Categories
Funding
- ICIQ
- ICREA
- Spanish Ministerio de Economia y Competitividad (MINECO) [CTQ2014-60419-R]
- Severo Ochoa Excellence Accreditation [SEV-2013-0319]
- ICREA Funding Source: Custom
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The incorporation of CO2 into substrates containing alcohol or amine functional groups displays interesting substrate-controlled reactivity, both in terms of providing milder reaction conditions and the potential towards new reactivity modes. Various heterocyclic structures can be prepared using this substrate-driven approach starting from functional derivatives of (homo) allylic and propargylic alcohols/amines, epoxy alcohols, and hydroxy-oxetanes among others. This review summarizes the recent advances made in this area. 1 Introduction 2 Catalytic Conversion of Propargylic Alcohols 3 Catalytic Conversion of Propargylic Amines 4 Homoallylic and Allylic Alcohol Substrate Conversions 5 Transformation of Allylic Amines 6 Epoxy Alcohols/Amines as Substrates 7 Hydroxy-Substituted Oxetane and Azetidine Scaffolds 8 Conversion of Other Substrates 9 Summary and Outlook
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