4.7 Article

A convenient colorimetric method for sensitive and specific detection of cyanide using Ag@Au core-shell nanoparticles

Journal

SENSORS AND ACTUATORS B-CHEMICAL
Volume 228, Issue -, Pages 366-372

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2016.01.022

Keywords

Ag@Au core-shell nanoparticles; Colorimetric; Cyanide detection; PS 40

Funding

  1. National Nature Scientific Foundations of China [21105123, 21505157]
  2. Applied Basic Research Project of Qingdao [15-9-1-94-JCH]
  3. Fundamental Research Funds for the Central Universities [14CX02216A, 15CX02070A]

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In this work, we synthesize Ag@Au core-shell nanoparticles (NPs) and use them as probes for the colorimetric detection of cyanide in aqueous solution. Ag@Au core-shell NPs before and after cyanide treatment are characterized with UV-vis spectroscopy, transmission electron microscopy and electrospray ionization time-of-flight mass spectrometry. The sensing mechanism is based on the fact that cyanide can successively etch gold shells and silver cores of the bimetallic NPs, leading to color changes from purple to orange, yellow and finally colorless. The decreased absorbance intensity at 520 nm is linear with the concentration of cyanide in the range of 0.4-32 iaM with a correlation coefficient of 0.995. The limit of detection is 0.16 iaM, which is, to our best knowledge, the lowest among the colorimetric methods. The colorimetric assay exhibits excellent selectivity for cyanide over the other 16 anions tested. The proposed method is used for the analysis of cyanide in drinking water, and the recoveries are in the range of 90.0-116.4% with the relative standard deviations lower than 6.7%. Furthermore, the Ag@Au core-shell NPs are functionalized with polysorbate 40 (PS 40), and the PS 40-Ag@Au core-shell NPs remain stable in the presence of high salt, which makes them feasible for the determination of cyanide in sewage samples with complex matrices. (C) 2016 Elsevier B.V. All rights reserved.

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