4.7 Article

Brominated, chlorinated and phosphate organic contaminants in house dust from Portugal

Journal

SCIENCE OF THE TOTAL ENVIRONMENT
Volume 569, Issue -, Pages 442-449

Publisher

ELSEVIER
DOI: 10.1016/j.scitotenv.2016.06.137

Keywords

Dust; BFRs; EBFRs

Funding

  1. European Funds through COMPETE
  2. National Funds through the Portuguese Science Foundation (FCT) [PEst-C/MAR/LA0017/2013, PEst-OE/SAU/UI0709/2014]
  3. FCT (Human Potential Operational Programme POPH, National Strategic Reference Framework) [SFRH/BPD/65884/2009, SFRH/BD/78168/2011]
  4. FCT (European Social Fund) [SFRH/BPD/65884/2009, SFRH/BD/78168/2011]
  5. Ministry of Education, Culture, Sports, Science and Technology, Japan (MEXT)
  6. Japanese Ministry of Education, Science, Sports, Culture and Technology (MEXT) [26220103, 25257403, 16H01784, 25281050]
  7. Japan Society for the Promotion of Science (JSPS)
  8. Grants-in-Aid for Scientific Research [16H01784, 26220103, 25281050, 25257403] Funding Source: KAKEN
  9. Fundação para a Ciência e a Tecnologia [SFRH/BD/78168/2011, SFRH/BPD/65884/2009] Funding Source: FCT

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House dust is an important matrix to evaluate the human exposure to a large number of contaminants including organochlorine compounds and flame retardants. In this study, we measured the levels of polybrominated diphenyl ethers (PBDEs), hexabromocyclododecanes (HBCDDs), 1,2-bis(2,4,6-tribromophenoxy) ethane (BTBPE), decabromodiphenyl ethane (DBDPE), polychlorinated biphenyls (PCBs) and several organophosphorus flames retardants (PFRs) in 28 house dust samples collected between 2010 and 2011 in two Portuguese cities, Aveiro and Coimbra. Among the measured compounds, PFRs, particularly tris(2-ethylhexyl) phosphate (TEHP), triphenyl phosphate (TPHP), 2-ethylhexyl diphenyl phosphate (EHDPP) and tris(methylphenyl) phosphate (TMPP), were the dominant group (median: 3200 ng g(-1)). PBDE levels were the second highest (median: 340 ng g(-1)) with great predominance of BDE 209 (median 270 ng g(-1)), followed by HBCDDs (median: 150 ng g(-1)), DBDPE (54 ng g(-1)), PCBs (median: 6.3 ng g(-1)) and BTBPE (median: 1.2 ng g(-1)). Estimated daily intakes (EDIs) via dust ingestion showed a higher intake of PFRs (median: 4.6 ng kg-bw(-1) day); however for all contaminants the EDIs were much lower than the established reference dose (RfD) values. Therefore, the studied population is exposed to non-hazardous levels of the target compounds when considering the exposure through house dust ingestion. (C) 2016 Published by Elsevier B.V.

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