4.7 Article

Advances of radical and photo reactions in natural products synthesis

Journal

SCIENCE CHINA-CHEMISTRY
Volume 59, Issue 9, Pages 1093-1108

Publisher

SCIENCE PRESS
DOI: 10.1007/s11426-016-0032-y

Keywords

radical reaction; photo reaction; natural product; total synthesis

Funding

  1. National Natural Science Foundation of China [21272076, 21422203]
  2. National Young Top-Notch Talent Support Program
  3. Qi Ming Xing Foundation of Shanghai Ministry of Science and Technology [14QA1401400]
  4. program for professor of special appointment (Eastern Scholar) at Shanghai institutions of higher learning
  5. Program for Changjiang Scholars and Innovative Research Team in University (PCSIRT)

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This review will focus on the recent advances of radical and photo reactions and their applications in the natural products total synthesis. A brief introduction to the development and mechanism of the newly developed radical and photo reactions will be presented. The organization of the each section is based on the type of reactions used. Examples of synthetic applications are discussed to demonstrate the potential of related methodologies and inspire future explorations.

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