Journal
PURE AND APPLIED CHEMISTRY
Volume 88, Issue 10-11, Pages 979-992Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1515/pac-2016-0709
Keywords
adsorption; metal organic frameworks; phosphonates; POC-16
Categories
Funding
- Romanian National Authority for Scientific Research, CNCS - UEFISCDI [PN-II-RU-TE-2014-4-1398]
- Institute of Chemistry Timisoara of Romanian Academy [2, 2.3]
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Due to the large amount of industrial activity during the last century, heavy metal contamination of the environment has become a serious problem. Therefore, it is important to develop new and efficient methods of heavy metals removal from aqueous solutions. In this respect, three phosphonate metal organic frameworks were obtained in our labs by the reaction of divalent inorganic salt (CoSO4 center dot 7H 2 O), phosphonic acid [phosphonoacetic (CP), N,N-bis(phosphonomethyl) glycine (Gly) and vinylphosphonic (VP)] in hydrothermal conditions. The synthesized compounds were characterized by FTIR, X-Ray crystallography scanning electron microscopy and thermogravimetric analysis. These materials were used in the removal process of lead ions from aqueous solutions in order to determine the possibilities of their use as adsorbent materials. The effect of pH, lead initial concentrations and contact time upon the adsorption properties were investigated. From the experimental data it can be observed that the Co-Gly material developed a higher adsorption capacity for lead metal ions than the Co-VP and Co-CP, increasing following Co-CP < Co-VP < Co-Gly trend.
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