Transition metal complexes bearing tridentate ligands for precise olefin polymerization

Discovery and Development of Pyridine-bis(imine) and Related Catalysts for Olefin Polymerization and Oligomerization

(2015) Brooke L. Small   ACCOUNTS OF CHEMICAL RESEARCH

Ethylene oligomerization promoted by chromium complexes bearing pyrrolide–imine–amine/ether tridentate ligands

(2015) A. C. Pinheiro et al.   DALTON TRANSACTIONS

Bis(alkyl) rare-earth complexes supported by a new tridentate amidinate ligand with a pendant diphenylphosphine oxide group. Synthesis, structures and catalytic activity in isoprene polymerization

(2015) Aleksei O. Tolpygin et al.   DALTON TRANSACTIONS

Highly active chromium(iii) complexes based on tridentate pyrazolyl pyridyl ligands for ethylene polymerization and oligomerization

(2015) Jong-Eun Park et al.   DALTON TRANSACTIONS

Tridentate Aryloxy-Based Titanium Catalysts towards Ethylene Oligomerization and Polymerization

(2015) Hugo Audouin et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis, characterization, and ethylene polymerization behavior of Cr(III) catalysts based on bis(pyrazolylmethyl)pyridine and its derivatives

(2015) Jeong Oh Woo et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Tunable regioselectivity in 1,3-butadiene polymerization by using 2,6-bis(dimethyl-2-oxazolin-2-yl)pyridine incorporated transition metal (Cr, Fe and Co) catalysts

(2015) Dirong Gong et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

(Pyrazolyl)-(phosphinoyl)pyridine iron(II), cobalt(II) and nickel(II) complexes: Synthesis, characterization and ethylene oligomerization studies

(2015) George S. Nyamato et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Convenient Syntheses and Versatile Functionalizations of Isotactic Polypropylene Containing Plentiful Pendant Styrene Groups with High Efficiency

(2015) Xiao-Yan Wang et al.   MACROMOLECULES

Chromium Complexes with N,N,N-Tridentate Quinolinyl Anilido-Imine Ligand: Synthesis, Characterization, and Catalysis in Ethylene Polymerization

(2015) Zhiqiang Hao et al.   ORGANOMETALLICS

Cyclic olefin copolymers of propylene with asymmetric Si-containing α,ω-diolefins: The tailored thermal and mechanical properties

(2015) Bin Wang et al.   POLYMER

Pyridylamido Bi-Hafnium Olefin Polymerization Catalysis: Conformationally Supported Hf···Hf Enchainment Cooperativity

(2015) Yanshan Gao et al.   ACS Catalysis

Ethylene polymerization by PN3-type pincer chromium(III) complexes

(2014) Dirong Gong et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Synthesis and characterization of novel chromium complexes based on β-enaminoketonato ligands and their application to ethylene polymerization

(2014) Jing-Yu Liu et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Preparation of [bis(amido)-phosphine] and [amido-phosphine sulfide or oxide] hafnium and zirconium complexes for olefin polymerization

(2014) Chun Sun Lee et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Synthesis, structural characterization, and ethylene polymerization behavior of (arylimido)vanadium(V) complexes bearing tridentate Schiff base ligands

(2014) Ling-Pan Lu et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Cyclopolymerization of Si-Containing α,ω-Diolefins by a Pyridylamidohafnium Catalyst with High Cyclization Selectivity and Stereoselectivity

(2014) Bin Wang et al.   MACROMOLECULES

Syntheses of Well-Defined Functional Isotactic Polypropylenes via Efficient Copolymerization of Propylene with ω-Halo-α-alkenes by Post-metallocene Hafnium Catalyst

(2014) Xiaoyan Wang et al.   MACROMOLECULES

Highly 3,4-Selective Living Polymerization of Isoprene and Copolymerization with ε-Caprolactone by an Amidino N-Heterocyclic Carbene Ligated Lutetium Bis(alkyl) Complex

(2014) Changguang Yao et al.   ORGANOMETALLICS

Chiral Palladium(II) and Nickel(II) Complexes with C2-Symmetrical Tridentate Bis(oxazoline) Ligands: Synthesis, Characterization, and Catalytic Norbornene Polymerization

(2014) Jianyun He et al.   ORGANOMETALLICS

Coordinative Chain Transfer Polymerization

(2013) Andreia Valente et al.   CHEMICAL REVIEWS

Addition of a phosphine ligand switches an N-heterocyclic carbene-zirconium catalyst from oligomerization to polymerization of 1-hexene

(2013) Emmanuelle Despagnet-Ayoub et al.   DALTON TRANSACTIONS

Solvent and co-catalyst dependent pyrazolylpyridinamine and pyrazolylpyrroleamine nickel(II) catalyzed oligomerization and polymerization of ethylene

(2013) Collins Obuah et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Nickel complexes bearing N,N,N-tridentate quinolinyl anilido–imine ligands: Synthesis, characterization and catalysis on norbornene addition polymerization

(2013) Zhiqiang Hao et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Half-titanocene 5-t-butyl-2-(1-(arylimino)methyl)quinolin-8-olate chlorides: Synthesis, characterization and ethylene (co-)polymerization behavior

(2013) Qing Yan et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Synthesis and characterization of tridentate [O−N(H)X] titanium complexes and their applications in olefin polymerization

(2013) Da-Wei Wan et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Copolymerization of Ethylene with Functionalized Olefins by [ONX] Titanium Complexes

(2013) Zhou Chen et al.   MACROMOLECULES

Quasi-Living trans-1,4-Polymerization of Isoprene by Cationic Rare Earth Metal Alkyl Species Bearing a Chiral (S,S)-Bis(oxazolinylphenyl)amido Ligand

(2013) Hui Liu et al.   MACROMOLECULES

Highly Thermally Stable Eight-Coordinate Dichloride Zirconium Complexes Supported by Tridentate [ONN] Ligands: Syntheses, Characterization, and Ethylene Polymerization Behavior

(2013) Aike Li et al.   ORGANOMETALLICS

Olefin Polymerization Behavior of Titanium(IV) Pyridine-2-phenolate-6-(σ-aryl) Catalysts: Impact of “py-Adjacent” and Phenolate Substituents

(2013) Jerry C. Y. Lo et al.   ORGANOMETALLICS

Neutral and Cationic N-Heterocyclic Carbene Zirconium and Hafnium Benzyl Complexes: Highly Regioselective Oligomerization of 1-Hexene with a Preference for Trimer Formation

(2013) Samuel Dagorne et al.   ORGANOMETALLICS

Nickel(II) and Palladium(II) Complexes with Tridentate [C,N,S] and [C,N,P] Ligands: Syntheses, Characterization, and Catalytic Norbornene Polymerization

(2013) Ya-Lin Qiao et al.   ORGANOMETALLICS

Tridentate ligands and beyond in group IV metal α-olefin homo-/co-polymerization catalysis

(2012) Carl Redshaw et al.   CHEMICAL SOCIETY REVIEWS

Sc(iii) complexes with neutral N3- and SNS-donor ligands – a spectroscopic study of the activation of ethene polymerisation catalysts

(2012) Stuart A. Bartlett et al.   DALTON TRANSACTIONS

Dialkyl Rare Earth Complexes Supported by Potentially Tridentate Amidinate Ligands: Synthesis, Structures, and Catalytic Activity in Isoprene Polymerization

(2012) Vassily Yu. Rad'kov et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis, structures and ethylene polymerization activity of chromium(III) complexes with N,O,N′-tridentate ligands

(2012) Fei Chen et al.   INORGANICA CHIMICA ACTA

Coordination compounds of chromium (+3) and vanadium (+3) and (+5) with 2,6-bis(diphenylhydroxymethyl)pyridyl ligand: Synthesis and study of catalytic activity in the polymerization of ethylene

(2012) Dmitry A. Kurmaev et al.   INORGANICA CHIMICA ACTA

Nickel halide complexes bearing 2-benzimidazolyl-N-arylquinoline-8-carboxamide derived ligands: Synthesis, characterization and catalytic behavior towards ethylene oligomerization and the vinyl polymerization of norbornene

(2012) Fan He et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Syntheses and structures of titanium complexes having O,N,O-tridentate ligands and their catalytic ability for ethylene polymerization

(2012) Noriyuki Suzuki et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Trans-1,2-diphenylethylene bridged salicylaldiminato–isoindoline titanium(IV) chloride complexes: Synthesis, characterization and catalytic polymerization

(2012) Li Wan et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

NNN-Tridentate Pyrrolyl Rare-Earth Metal Complexes: Structure and Catalysis on Specific Selective Living Polymerization of Isoprene

(2012) Lingfang Wang et al.   ORGANOMETALLICS

Evaluation of catalytic activity in ethylene polymerization and ethylene/10-undecen-1-ol copolymerization of new orthopalladated complexes derived from tridentade ligands [C,N,S]

(2011) Fernando Ortega-Jiménez et al.   APPLIED CATALYSIS A-GENERAL

Facing Unexpected Reactivity Paths with ZrIV-Pyridylamido Polymerization Catalysts

(2011) Lapo Luconi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Active Ethylene Polymerization and Regioselective 1-Hexene Oligomerization Using Zirconium and Titanium Catalysts with Tridentate [ONO] Ligands

(2011) Tieqi Xu et al.   INORGANIC CHEMISTRY

Synthesis, characterization and ethylene oligomerization behavior of 2-(chloro-substituted-1H-benzoimidazol-2-yl)-6-(1-aryliminoethyl)pyridylnickel dihalides

(2011) Xia Chen et al.   INORGANICA CHIMICA ACTA

New bis(azolylcarbonyl)pyridine chromium(III) complexes as initiators for ethylene polymerization

(2011) John Hurtado et al.   INORGANICA CHIMICA ACTA

Synthesis and olefin polymerization activity of (quinolin-8-ylamino)phenolate and (quinolin-8-ylamido)phenolate Group 4 metal complexes

(2011) Marina Lamberti et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Nickel and cationic palladium complexes bearing (imino)pyridyl alcohol ligands: Synthesis, characterization and vinyl polymerization of norbornene

(2011) Suyun Jie et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Synthesis, characterization, and ethylene (Co)polymerization behavior of trichlorotitanium 2-(1-(arylimino)propyl)quinolin-8-olates

(2011) Wei Huang et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Stereospecific Cyclopolymerization of α,ω-Diolefins by Pyridylamidohafnium Catalyst with the Highest Activity

(2011) Xin-cui Shi et al.   MACROMOLECULES

Carbazole-bis(oxazolines) as Monoanionic, Tridentate Chelates in Lanthanide Chemistry: Synthesis and Structural Studies of Thermally Robust and Kinetically Stable Dialkyl and Dichloride Complexes.

(2011) Jin Zou et al.   ORGANOMETALLICS

Highly Cis-1,4-Selective Living Polymerization of 1,3-Conjugated Dienes and Copolymerization with ε-Caprolactone by Bis(phosphino)carbazolide Rare-Earth-Metal Complexes

(2011) Lingfang Wang et al.   ORGANOMETALLICS

Pincer Chromium(II) and Chromium(III) Complexes Supported by Bis(imino)aryl NCN ligands: Synthesis and Catalysis on Isoprene Polymerization

(2011) Zhizhou Liu et al.   ORGANOMETALLICS

2-Benzimidazolyl-N-phenylquinoline-8-carboxamide Chromium(III) Trichlorides: Synthesis and Application for Ethylene Oligomerization and Polymerization

(2011) Deligeer Wang et al.   ORGANOMETALLICS

Vinyl-addition polymerization of norbornene catalyzed by (pyrazol-1-ylmethyl)pyridine divalent iron, cobalt and nickel complexes

(2011) Letitia L. Benade et al.   POLYHEDRON

Synthesis and characterization of trichlorotitanium 2-(2-pyridinyliminomethyl)phenolates and their ethylene (co-)polymerization behavior

(2011) Youhong Wang et al.   POLYMER

Isoprene polymerization with aminopyridinato ligand supported rare-earth metal complexes. Switching of the regio- and stereoselectivity

(2010) Yi Yang et al.   CHEMICAL COMMUNICATIONS

Design of Vanadium Complex Catalysts for Precise Olefin Polymerization

(2010) Kotohiro Nomura et al.   CHEMICAL REVIEWS

Syntheses of some new group 4 non-Cp complexes bearing schiff-base, thiophene diamide ligands respectively and their catalytic activities for α-olefin polymerization

(2010) Ji-Ling Huang et al.   CHINESE JOURNAL OF CHEMISTRY

Polymerization catalysis with transition metal amidinate and related complexes

(2010) Scott Collins   COORDINATION CHEMISTRY REVIEWS

Synthesis and ethylene trimerisation capability of new chromium(ii) and chromium(iii) heteroscorpionate complexes

(2010) Alexander F. R. Kilpatrick et al.   DALTON TRANSACTIONS

Intramolecular σ-Bond Metathesis/Protonolysis on Zirconium(IV) and Hafnium(IV) Pyridylamido Olefin Polymerization Catalyst Precursors: Exploring Unexpected Reactivity Paths

(2010) Lapo Luconi et al.   INORGANIC CHEMISTRY

Macrocyclic hexanuclear zirconium(IV) complex bearing a bisaryloxyl N-heterocyclic-carbene ligand: Synthesis, structure, and catalytic properties

(2010) Dao Zhang et al.   INORGANIC CHEMISTRY COMMUNICATIONS

Synthesis and ethylene polymerization behavior of {MeB(3-Ph-pyrazolyl)3}TiCl3

(2010) Changle Chen et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Novel polymerization catalysts and hydride clusters from rare-earth metal dialkyls

(2010) Masayoshi Nishiura et al.   Nature Chemistry

CCC-Pincer Bis(carbene) Lanthanide Dibromides. Catalysis on Highlycis-1,4-Selective Polymerization of Isoprene and Active Species

(2010) Kui Lv et al.   ORGANOMETALLICS

[O−NSR]TiCl3-Catalyzed Copolymerization of Ethylene with Functionalized Olefins

(2009) Xiao-Hong Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanism of stereospecific polymerization of α-olefins by late-transition metal and octahedral group 4 metal catalysts

(2009) Marina Lamberti et al.   COORDINATION CHEMISTRY REVIEWS

The role of the ionic radius in the ethylene polymerization catalyzed by new group 3 and lanthanide scorpionate complexes

(2009) Gino Paolucci et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Influences of steric bulkiness in hydrotris(pyrazolyl)borate ligands on ethylene polymerization reaction

(2009) Masaaki Nabika et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Synthesis of Early Transition Metal Bisphenolate Complexes and Their Use as Olefin Polymerization Catalysts

(2009) Suzanne R. Golisz et al.   MACROMOLECULES

Selective σ-Bond Metathesis in Alkyl−Aryl and Alkyl−Benzyl Yttrium Complexes. New Aryl− and Benzyl−Hydrido Yttrium Derivatives Supported by Amidopyridinate Ligands

(2009) D. M. Lyubov et al.   ORGANOMETALLICS

Synthesis, Structural Characterization, and Olefin Polymerization Behavior of Vanadium(III) Complexes Bearing Tridentate Schiff Base Ligands

(2009) Ji-Qian Wu et al.   ORGANOMETALLICS

On the First Insertion of α-Olefins in Hafnium Pyridyl-Amido Polymerization Catalysts

(2009) Cristiano Zuccaccia et al.   ORGANOMETALLICS

Group 4 Post-metallocene Complexes Incorporating Tridentate Silyl-Substituted Bis(naphthoxy)pyridine and Bis(naphthoxy)thiophene Ligands: Probing Systems for “Oscillating” Olefin Polymerization Catalysis

(2009) Evgueni Kirillov et al.   ORGANOMETALLICS

Highly 3,4-Selective Polymerization of Isoprene with NPN Ligand Stabilized Rare-Earth Metal Bis(alkyl)s. Structures and Performances

(2009) Shihui Li et al.   ORGANOMETALLICS

Synthesis and Characterization of NiIIand PdIIComplexes Bearing N,N,S Tridentate Ligands and Their Catalytic Properties for Norbornene Polymerization

(2008) Jieming Long et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Scandium complexes with [N,N,Cp] and [N,N,O] donor-set ancillary ligands as catalysts in olefin polymerization

(2008) Gino Paolucci et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Synthesis, structure, and catalytic ethylene oligomerization of nickel complexes bearing 2-pyrazolyl substituted 1,10-phenanthroline ligands

(2008) Yue Yang et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Highly selective nickel catalysts for ethylene oligomerization based on tridentate pyrazolyl ligands

(2008) Lucilene L. de Oliveira et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Synthesis, characterization, and catalytic activities in syndiospecific polymerization of styrene for half-sandwich titanium complexes with non-Cp tridentate dianionic ligands MeN(CH2CR2O−)2

(2008) Younjin Hong et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

2-Oxazoline/benzoxazole-1,10-phenanthrolinylmetal (iron, cobalt or nickel) dichloride: Synthesis, characterization and their catalytic reactivity for the ethylene oligomerization

(2008) Min Zhang et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Group 4 metal complexes bearing new tridentate (NNO) ligands: Benzyl migration and formation of unusual C–C coupled products

(2008) Renan Cariou et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Highlycis-1,4 Selective Polymerization of Dienes with Homogeneous Ziegler−Natta Catalysts Based on NCN-Pincer Rare Earth Metal Dichloride Precursors

(2008) Wei Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivity of Tantalum Complexes Supported by Bidentate X2and Tridentate LX2Ligands with Two Phenolates Linked to Pyridine, Thiophene, Furan, and Benzene Connectors: Mechanistic Studies of the Formation of a Tantalum Benzylidene and Insertion Chemistry for Tantalum−Carbon Bonds

(2008) Theodor Agapie et al.   ORGANOMETALLICS

Synthesis and Reactivity of a Sterically Crowded Tris(pyrazolyl)borate Hafnium Benzyl Complex

(2008) Han Lee et al.   ORGANOMETALLICS

Synthesis and Characterization of Pyrrole-imine [N−NP] Nickel(II) and Palladium(II) Complexes and Their Applications to Norbornene Polymerization

(2008) Fu-Bin Han et al.   ORGANOMETALLICS

Synthesis, DFT Studies, and Reactions of Scandium and Yttrium Dialkyl Cations Containing Neutralfac-N3andfac-S3Donor Ligands

(2008) Cara S. Tredget et al.   ORGANOMETALLICS

Titanium Complexes Bearing Bisaryloxy-N-heterocyclic Carbenes: Synthesis, Reactivity, and Ethylene Polymerization Study

(2008) Dao Zhang et al.   ORGANOMETALLICS