4.7 Article

Synthesis and characterization of supramolecular cross-linkers containing cyclodextrin dimer and trimer

Journal

POLYMER CHEMISTRY
Volume 7, Issue 21, Pages 3492-3495

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6py00367b

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology, Japan [26102512, 26011414]

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Vinylic supramolecular cross-linkers (VSCs) were prepared by mixing an alpha-cyclodextrin dimer or a trimer and a polyethylene glycol-type macromonomer. DOSY NMR study exhibited the size of VSC and its dependency on the concentration and the structure of the components. Polymerization of a vinyl monomer with VSC afforded rotaxane cross-linked polymers.

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