Journal
POLYHEDRON
Volume 103, Issue -, Pages 126-130Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2015.09.003
Keywords
Diruthenium; High oxidation state; Magnetism; Electrochemistry; Hybrid-structure
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Funding
- National Science Foundation [CHE 1362214]
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A new diruthenium compound, Ru-2(eta(2)-DmAniF)(2)(mu-DmAniF)(2)(OAc)(O) (1), where DmAniF is N,N'-di(m-methoxyphenyl)formamidinate, was isolated as a secondary product from the reaction between Ru-2(DmAniF)(3)(OAc)Cl and K2CO3, and its formulation was established using both single crystal X-ray diffraction and high resolution mass-spectrometry techniques. Compound 1 has an S=3/2 ground state, and exhibits an unusually large zero-field splitting (D = 308 cm(-1)) as revealed by the measurement of temperature dependent magnetism. (C) 2015 Elsevier Ltd. All rights reserved.
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