4.6 Article

Direct Synthesis of Palladium Catalyst on Supporting WS2 Nanotubes and its Reactivity in Cross-Coupling Reactions

Journal

CHEMISTRY-AN ASIAN JOURNAL
Volume 10, Issue 10, Pages 2234-2239

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201500271

Keywords

cross-coupling; Heck reaction; inorganic nanotubes; Pd catalysis; Suzuki reaction

Funding

  1. Division of Chemistry and Materials, Russian Academy of Sciences
  2. oFTA-INNI initiative of VATAT (Israel)
  3. Israel Science Foundation
  4. H. Perlman Foundation
  5. Irving Foundation
  6. Azelle Waltcher Foundation
  7. Irving and Cherna Moskowitz Center for Nano and Bio-Nano Imaging
  8. EU [ITN 317451]

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Palladium nanoparticles were deposited on multi-wall WS2 nanotubes. The composite nanoparticles were characterized by a variety of techniques. The Pd nanoparticles were deposited uniformly on the surface of WS2 nanotubes. An epitaxial relationship between the (111) plane of Pd and the (013) plane of WS2 was mostly observed. The composite nanoparticles were found to perform efficiently as catalysts for cross-coupling (Heck and Suzuki) reactions. The role of the nanotubes' support in the catalytic process is briefly discussed.

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