Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 43, Pages 15118-15122Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201502822
Keywords
boron clusters; conjugates; DNA; nanomaterials; tripeds
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Funding
- National Science Centre, Poland [2014/13/B/NZ1/03989]
- IMB PAS
- Generalitat de Catalunya [2014/SGR/149]
- Spanish Ministry of Economy and Competitiveness [CTQ2013-44670-R]
- Institute for Medical Biology (Polish Academy of Sciences) [2010L0001]
- Institute of Material Science (C.S.I.C.) [2010L0001]
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A synthetic strategy for functionalization of the three vertices of o-carborane and the attachment of the obtained triped to the solid support was developed. Further functionalization of the triped with short DNA sequences by automated DNA synthesis was achieved. The proposed methodology is a first example of boron cluster chemistry on a solid support opening new perspectives in boron cluster functionalization.
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