Formal Asymmetric Organocatalytic [3+2] Cyclization between Enecarbamates and 3-Indolylmethanols: Rapid Access to 3-Aminocyclopenta[b]indoles

Catalytic, highly enantioselective, direct amination of enecarbamates

(2015) Audrey Dumoulin et al.   CHEMICAL COMMUNICATIONS

Synthesis of polysubstituted cyclopenta[b]indoles via relay gold(i)/Brønsted acid catalysis

(2015) Seema Dhiman et al.   CHEMICAL COMMUNICATIONS

Chiral Brønsted acid-catalyzed Friedel–Crafts alkylation of electron-rich arenes with in situ-generated ortho-quinone methides: highly enantioselective synthesis of diarylindolylmethanes and triarylmethanes

(2015) Satyajit Saha et al.   CHEMICAL COMMUNICATIONS

Catalyst-Controlled Chemoselective Reaction of 3-Indolylmethanols with Cyclic Enaminones Leading to C2-Functionalized Indoles

(2015) Xin Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Chiral Phosphoric Acid-Catalyzed Enantioselective Three- Component Aza-Diels-Alder Reactions of Aminopyrroles and Aminopyrazoles

(2014) Julien Brioche et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantio- and Diastereoselective Access to Distant Stereocenters Embedded within Tetrahydroxanthenes: Utilizingortho-Quinone Methides as Reactive Intermediates in Asymmetric Brønsted Acid Catalysis

(2014) Chien-Chi Hsiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Brønsted Acid Catalyzed, Conjugate Addition of β-Dicarbonyls to In Situ Generatedortho-Quinone Methides-Enantioselective Synthesis of 4-Aryl-4H-Chromenes

(2014) Osama El-Sepelgy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Vinylogous Diels-Alder Reactions Catalyzed by a Chiral Phosphoric Acid

(2014) Xu Tian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic enantioselective and (Z)-selective allylation of 3-indolylmethanol via hydrogen-bond activation

(2014) Yan Liu et al.   CHEMICAL COMMUNICATIONS

Highly diastereo- and enantioselective construction of a spiro[cyclopenta[b]indole-1,3′-oxindole] scaffold via catalytic asymmetric formal [3+2] cycloadditions

(2014) Wei Tan et al.   CHEMICAL COMMUNICATIONS

Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

(2014) Dixit Parmar et al.   CHEMICAL REVIEWS

Chiral Calcium-BINOL Phosphate Catalyzed Diastereo- and Enantioselective Synthesis ofsyn-1,2-Disubstituted 1,2-Diamines: Scope and Mechanistic Studies

(2014) Claudia Lalli et al.   CHEMISTRY-A EUROPEAN JOURNAL

Gold(I)-Catalyzed 1,2-Acyloxy Migration/[3+2] Cycloaddition of 1,6-Diynes with an Ynamide Propargyl Ester Moiety: Highly Efficient Synthesis of Functionalized Cyclopenta[b]indoles

(2014) Jun Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Diastereo- and Enantioselective Construction of a Bispirooxindole Scaffold Containing a Tetrahydro-β-carboline Moiety through an Organocatalytic Asymmetric Cascade Reaction

(2014) Wei Dai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organocatalytic Asymmetric Cascade Reactions of 7-Vinylindoles: Diastereo- and Enantioselective Synthesis of C7-Functionalized Indoles

(2014) Feng Shi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Asymmetric Aza-ene Reaction of 3-Indolylmethanols with Cyclic Enaminones: Enantioselective Approach to C3-Functionalized Indoles

(2014) Wei Tan et al.   JOURNAL OF ORGANIC CHEMISTRY

Organocatalytic Arylation of 3-Indolylmethanols via Chemo- and Regiospecific C6-Functionalization of Indoles

(2014) Lu-Jia Zhou et al.   JOURNAL OF ORGANIC CHEMISTRY

Organocatalytic Chemo-, (E/Z)- and Enantioselective Formal Alkenylation of Indole-Derived Hydroxylactams Using o-Hydroxystyrenes as a Source of Alkenyl Group

(2014) Hong-Hao Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Intramolecular [3 + 2] Cyclocondensations of Alkenes with Indolidenes and Indolidenium Cations

(2014) Ken S. Feldman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphoric Acid Catalyzed Diastereo- and Enantioselective Synthesis of Substituted 1,3-Diaminotetralins

(2014) Guillaume Dagousset et al.   ORGANIC LETTERS

The Direct Asymmetric Alkylation of α-Amino Aldehydes with 3-Indolylmethanols by Enamine Catalysis

(2014) Zhi-Lei Guo et al.   ORGANIC LETTERS

Imine and iminium precursors as versatile intermediates in enantioselective organocatalysis

(2014) Antti O. Kataja et al.   TETRAHEDRON

Highly efficient [3 + 2] reaction of 3-vinylindoles with 3-indolylmethanols by Brønsted-acid catalysis

(2014) Cheng Zhang et al.   RSC Advances

Chiral Phosphoric Acid-Catalyzed Enantioselective Aza-Friedel-Crafts Alkylation of Indoles with γ-Hydroxy-γ-lactams

(2013) Thibaut Courant et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Enantioselective Aza-Diels-Alder Reaction of 1-Azadienes with Enecarbamates Catalyzed by Chiral Phosphoric Acids

(2013) Long He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium/Lewis Acid Mediated Domino Reaction of Pentafulvene Derived Diazabicyclic Olefins: Efficient Access to Spiropentacyclic Motif with an Indoline and Pyrazolidine Fused to Cyclopentene

(2013) S. Sarath Chand et al.   ORGANIC LETTERS

Acid-promoted Cascade Cyclization to Produce Fused-polycyclic Indole Derivatives

(2013) Takuya Yokosaka et al.   ORGANIC LETTERS

Hetero Diels–Alder reaction of olefin with o-quinone methides generated using (±)-binolphosphoric acid for the stereoselective synthesis of 2,4-diarylbenzopyrans: application to the formal synthesis of myristinin B/C

(2013) Santosh J. Gharpure et al.   RSC Advances

Asymmetric Counteranion-Directed Catalysis: Concept, Definition, and Applications

(2012) Manuel Mahlau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Phosphoric Acid-Catalyzed Enantioselective Three-Component Povarov Reaction Using Cyclic Enethioureas as Dienophiles: Stereocontrolled Access to Enantioenriched Hexahydropyrroloquinolines

(2012) Guillaume Dagousset et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Enantioselective Electrophilic α-Bromination of Enecarbamates: Chiral Phosphoric Acid and Calcium Phosphate Salt Catalysts

(2012) Aurélien Alix et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multistep One-Pot Synthesis of Enantioenriched Polysubstituted Cyclopenta[b]indoles

(2011) Biao Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective N-H Functionalization of Indoles with α,β-Unsaturated γ-Lactams Catalyzed by Chiral Brønsted Acids

(2011) Yinjun Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Use of Nonfunctionalized Enamides and Enecarbamates in Asymmetric Synthesis

(2011) Kovuru Gopalaiah et al.   CHEMICAL REVIEWS

Chiral Brønsted acids in enantioselective carbonyl activations – activation modes and applications

(2011) Magnus Rueping et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective Carbon-Carbon Bond Forming Reactions Catalyzed by Chiral Phosphoric Acid Catalysts

(2011) Masahiro Terada   CURRENT ORGANIC CHEMISTRY

Chiral Phosphoric Acid-Catalyzed Enantioselective Three-Component Povarov Reaction Using Enecarbamates as Dienophiles: Highly Diastereo- and Enantioselective Synthesis of Substituted 4-Aminotetrahydroquinolines

(2011) Guillaume Dagousset et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Organic Contact Ion Pairs in Metal-Free Catalytic Asymmetric Allylic Substitutions

(2011) Magnus Rueping et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Discovery of an Acid-Promoted [3+2] Cyclodimerization of 3-Vinylindoles and the Development of a General Lewis Acid Catalyzed Process

(2011) James McNulty et al.   SYNLETT

Chiral Amine Synthesis - Recent Developments and Trends for Enamide Reduction, Reductive Amination, and Imine Reduction

(2010) Thomas C. Nugent et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Amplification in Phosphoric Acid Catalyzed Reactions

(2010) Nan Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Acid Catalyzed Intramolecular Direct Ene Reaction of Indoles

(2010) Bo Han et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Carbon–Carbon Bond Forming Reactions

(2010) Masahiro Terada   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Platinum(II)-Catalyzed Generation and [3+2] Cycloaddition Reaction of α,β-Unsaturated Carbene Complex Intermediates for the Preparation of Polycyclic Compounds

(2010) Kodai Saito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Calcium Organophosphate-Catalyzed Enantioselective Electrophilic Amination of Enamides

(2010) Fleur Drouet et al.   ORGANIC LETTERS

Recent Applications of α-Amido Sulfones as in situ Equivalents of Activated Imines for Asymmetric Catalytic Nucleophilic Addition Reactions

(2010) Biaolin Yin et al.   SYNTHESIS-STUTTGART

Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations

(2010) Masahiro Terada   SYNTHESIS-STUTTGART

Enantioselective Fujiwara-Moritani Indole and Pyrrole Annulations Catalyzed by Chiral Palladium(II)-NicOx Complexes

(2009) Julia A. Schiffner et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Application of a Rhodium-Catalyzed Addition/Cyclization Sequence toward the Synthesis of Polycyclic Heteroaromatics

(2009) Nai-Wen Tseng et al.   JOURNAL OF ORGANIC CHEMISTRY

An Enzymatic Cyclopentyl[b]indole Formation Involved in Scytonemin Biosynthesis

(2009) Emily P. Balskus et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Brønsted Acid-Catalyzed Enantioselective Three-Component Povarov Reaction

(2009) Hua Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 3-substituted indoles via reactive alkylideneindolenine intermediates

(2009) Alessandro Palmieri et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Highly Enantioselective Alkylation Reaction of Enamides by Brønsted-Acid Catalysis

(2009) Qi-Xiang Guo et al.   ORGANIC LETTERS

Chiral Brønsted Acid-Catalyzed Enantioselective Multicomponent Mannich Reaction: Synthesis ofanti-1,3-Diamines Using Enecarbamates as Nucleophiles

(2009) Guillaume Dagousset et al.   ORGANIC LETTERS

Enamides and Enecarbamates as Nucleophiles in Stereoselective C–C and C–N Bond-Forming Reactions

(2008) Ryosuke Matsubara et al.   ACCOUNTS OF CHEMICAL RESEARCH

Binaphthol-derived phosphoric acid as a versatile catalyst for enantioselective carbon–carbon bond forming reactions

(2008) Masahiro Terada   CHEMICAL COMMUNICATIONS

Enamides: valuable organic substrates

(2008) David R. Carbery   ORGANIC & BIOMOLECULAR CHEMISTRY

One-Pot Synthesis of Bicyclic β-Alkoxy Amides from Cyanohydrin Ethers

(2008) Qing Xiao et al.   ORGANIC LETTERS