Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 22, Issue 2, Pages 526-530Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201504292
Keywords
azides; nitrogen heterocycles; oxidation; photochemistry; redox chemistry; visible light
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Funding
- Department of Science and Technology, Ministry of Science and Technology [GAP-0378, 0470, 0414, 0512]
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Structurally diverse imidazole derivatives were synthesized by a visible-light/[Ru(bpy)(3)][(PF6)(2)]-mediated coupling of vinyl azides and secondary amines in flow microreactors. This operationally simple and atom-economical protocol allows the formation of three new C-N bonds through the functionalization of sp(3) C-H bonds adjacent to the secondary nitrogen atom. In order to get mechanistic insight of the coupling reaction, several control experiments were carried out and discussed.
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