Proton-Coupled Electron Transfer Reactions Catalysed by 3 d Metal Complexes

Electrocatalytic Water Oxidation by a Dinuclear Copper Complex in a Neutral Aqueous Solution

(2015) Xiao-Jun Su et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ammonia Synthesis by Hydrogenolysis of Titanium–Nitrogen Bonds Using Proton Coupled Electron Transfer

(2015) Iraklis Pappas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrode initiated proton-coupled electron transfer to promote degradation of a nickel(ii) coordination complex

(2015) Brian D. McCarthy et al.   Chemical Science

A molecular structural analog of proposed dinuclear active sites in cobalt-based water oxidation catalysts

(2014) Timothy C. Davenport et al.   CHEMICAL COMMUNICATIONS

Biochemistry and Theory of Proton-Coupled Electron Transfer

(2014) Agostino Migliore et al.   CHEMICAL REVIEWS

Cobalt Catalyst with a Proton-Responsive Ligand for Water Oxidation

(2014) Inke Siewert et al.   CHEMISTRY-A EUROPEAN JOURNAL

Unraveling the Mechanism of Water Oxidation Catalyzed by Nonheme Iron Complexes

(2014) Ferran Acuña-Parés et al.   CHEMISTRY-A EUROPEAN JOURNAL

Studies of the Pathways Open to Copper Water Oxidation Catalysts Containing Proximal Hydroxy Groups During Basic Electrocatalysis

(2014) Deidra L. Gerlach et al.   INORGANIC CHEMISTRY

The Mechanism of Homogeneous CO2 Reduction by Ni(cyclam): Product Selectivity, Concerted Proton–Electron Transfer and C–O Bond Cleavage

(2014) Jinshuai Song et al.   INORGANIC CHEMISTRY

Development of Molecular Electrocatalysts for Energy Storage

(2014) Daniel L. DuBois   INORGANIC CHEMISTRY

Status of Reactive Non-Heme Metal–Oxygen Intermediates in Chemical and Enzymatic Reactions

(2014) Kallol Ray et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pendant Acid–Base Groups in Molecular Catalysts: H-Bond Promoters or Proton Relays? Mechanisms of the Conversion of CO2 to CO by Electrogenerated Iron(0)Porphyrins Bearing Prepositioned Phenol Functionalities

(2014) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt porphyrin electrode films for electrocatalytic water oxidation

(2014) Ali Han et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Dinuclear manganese complexes for water oxidation: evaluation of electronic effects and catalytic activity

(2014) Wael A. A. Arafa et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Role of pendant proton relays and proton-coupled electron transfer on the hydrogen evolution reaction by nickel hangman porphyrins

(2014) D. Kwabena Bediako et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Theoretical Analysis of Cobalt Hangman Porphyrins: Ligand Dearomatization and Mechanistic Implications for Hydrogen Evolution

(2014) Brian H. Solis et al.   ACS Catalysis

Selective 4e–/4H+ O2 Reduction by an Iron(tetraferrocenyl)Porphyrin Complex: From Proton Transfer Followed by Electron Transfer in Organic Solvent to Proton Coupled Electron Transfer in Aqueous Medium

(2013) Kaustuv Mittra et al.   INORGANIC CHEMISTRY

Theoretical Design of Molecular Electrocatalysts with Flexible Pendant Amines for Hydrogen Production and Oxidation

(2013) Laura E. Fernandez et al.   Journal of Physical Chemistry Letters

Proton-Coupled Electron Transfer Cleavage of Heavy-Atom Bonds in Electrocatalytic Processes. Cleavage of a C–O Bond in the Catalyzed Electrochemical Reduction of CO2

(2013) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Acid-Induced Mechanism Change and Overpotential Decrease in Dioxygen Reduction Catalysis with a Dinuclear Copper Complex

(2013) Dipanwita Das et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enhanced Catalytic Four-Electron Dioxygen (O2) and Two-Electron Hydrogen Peroxide (H2O2) Reduction with a Copper(II) Complex Possessing a Pendant Ligand Pivalamido Group

(2013) Saya Kakuda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N–N Bond Cleavage of Hydrazines with a Multiproton-Responsive Pincer-Type Iron Complex

(2013) Kazuki Umehara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Biomimetic Copper Water Oxidation Catalyst with Low Overpotential

(2013) Teng Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient water oxidation catalyzed by homogeneous cationic cobalt porphyrins with critical roles for the buffer base

(2013) D. Wang et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Distant protonated pyridine groups in water-soluble iron porphyrin electrocatalysts promote selective oxygen reduction to water

(2012) Benjamin D. Matson et al.   CHEMICAL COMMUNICATIONS

Interrogation of electrocatalytic water oxidation mediated by a cobalt complex

(2012) Derek J. Wasylenko et al.   CHEMICAL COMMUNICATIONS

Proton-Coupled Electron Transfer

(2012) David R. Weinberg et al.   CHEMICAL REVIEWS

Kinetics and thermodynamics of formation and electron-transfer reactions of Cu–O2 and Cu2–O2 complexes

(2012) Shunichi Fukuzumi et al.   COORDINATION CHEMISTRY REVIEWS

Electron-transfer properties of high-valent metal-oxo complexes

(2012) Shunichi Fukuzumi   COORDINATION CHEMISTRY REVIEWS

Quantum chemical characterization of the mechanism of a supported cobalt-based water oxidation catalyst

(2012) Mehmed Z. Ertem et al.   DALTON TRANSACTIONS

Proton-coupled electron transfer: classification scheme and guide to theoretical methods

(2012) Sharon Hammes-Schiffer   Energy & Environmental Science

Proton-coupled electron transfer kinetics for the hydrogen evolution reaction of hangman porphyrins

(2012) Manolis M. Roubelakis et al.   Energy & Environmental Science

Homogeneous CO2 Reduction by Ni(cyclam) at a Glassy Carbon Electrode

(2012) Jesse D. Froehlich et al.   INORGANIC CHEMISTRY

Catalytic Four-Electron Reduction of O2 via Rate-Determining Proton-Coupled Electron Transfer to a Dinuclear Cobalt-μ-1,2-peroxo Complex

(2012) Shunichi Fukuzumi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Factors That Control Catalytic Two- versus Four-Electron Reduction of Dioxygen by Copper Complexes

(2012) Shunichi Fukuzumi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic Oxygen Reduction by Iron Tetra-arylporphyrins Bearing Pendant Proton Relays

(2012) Colin T. Carver et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthetic Models for the Active Site of the [FeFe]-Hydrogenase: Catalytic Proton Reduction and the Structure of the Doubly Protonated Intermediate

(2012) Maria E. Carroll et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Computational Study of Anomalous Reduction Potentials for Hydrogen Evolution Catalyzed by Cobalt Dithiolene Complexes

(2012) Brian H. Solis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A soluble copper–bipyridine water-oxidation electrocatalyst

(2012) Shoshanna M. Barnett et al.   Nature Chemistry

Insights into proton-coupled electron transfer mechanisms of electrocatalytic H2 oxidation and production

(2012) S. Horvath et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Cobalt-dithiolene complexes for the photocatalytic and electrocatalytic reduction of protons in aqueous solutions

(2012) W. R. McNamara et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

A Local Proton Source Enhances CO2 Electroreduction to CO by a Molecular Fe Catalyst

(2012) C. Costentin et al.   SCIENCE

Cobalt analogs of Ru-based water oxidation catalysts: overcoming thermodynamic instability and kinetic lability to achieve electrocatalytic O2 evolution

(2012) Matthew L. Rigsby et al.   Chemical Science

Proton-coupled electron transfer at a [Co-OHx]zunit in aqueous media: evidence for a concerted mechanism

(2012) Derek J. Wasylenko et al.   Chemical Science

Electrochemical evidence for catalytic water oxidation mediated by a high-valent cobalt complex

(2011) Derek J. Wasylenko et al.   CHEMICAL COMMUNICATIONS

Resolving Heterogeneity Problems and Impurity Artifacts in Operationally Homogeneous Transition Metal Catalysts

(2011) Robert H. Crabtree   CHEMICAL REVIEWS

Proton management as a design principle for hydrogenase-inspired catalysts

(2011) Yolanda A. Small et al.   Energy & Environmental Science

Four-Electron Oxygen Reduction by Brominated Cobalt Corrole

(2011) Alex Schechter et al.   INORGANIC CHEMISTRY

Theoretical Analysis of Mechanistic Pathways for Hydrogen Evolution Catalyzed by Cobaloximes

(2011) Brian H. Solis et al.   INORGANIC CHEMISTRY

Theoretical Analysis of the Sequential Proton-Coupled Electron Transfer Mechanisms for H2 Oxidation and Production Pathways Catalyzed by Nickel Molecular Electrocatalysts

(2011) Laura E. Fernandez et al.   Journal of Physical Chemistry C

Direct-Coupling O2 Bond Forming a Pathway in Cobalt Oxide Water Oxidation Catalysts

(2011) Lee-Ping Wang et al.   Journal of Physical Chemistry Letters

Catalytic Reduction of Dioxygen to Water with a Monomeric Manganese Complex at Room Temperature

(2011) Ryan L. Shook et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electocatalytic Water Oxidation by Cobalt(III) Hangman β-Octafluoro Corroles

(2011) Dilek K. Dogutan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen Generation by Hangman Metalloporphyrins

(2011) Chang Hoon Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Cobalt–Dithiolene Complex for the Photocatalytic and Electrocatalytic Reduction of Protons

(2011) William R. McNamara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient water oxidation catalysts based on readily available iron coordination complexes

(2011) Julio Lloret Fillol et al.   Nature Chemistry

Homogeneous catalytic O2 reduction to water by a cytochrome c oxidase model with trapping of intermediates and mechanistic insights

(2011) Z. Halime et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s-1 for H2 Production

(2011) M. L. Helm et al.   SCIENCE

Update 1 of: Electrochemical Approach to the Mechanistic Study of Proton-Coupled Electron Transfer

(2010) Cyrille Costentin et al.   CHEMICAL REVIEWS

Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications

(2010) Jeffrey J. Warren et al.   CHEMICAL REVIEWS

Reduction of oxygen catalyzed by nickel diphosphine complexes with positioned pendant amines

(2010) Jenny Y. Yang et al.   DALTON TRANSACTIONS

[(H2O)(terpy)Mn(μ-O)2Mn(terpy)(OH2)](NO3)3 (terpy = 2,2′:6,2′′-terpyridine) and its relevance to the oxygen-evolving complex of photosystem II examined through pH dependent cyclic voltammetry

(2010) Clyde W. Cady et al.   DALTON TRANSACTIONS

Copper dioxygen (bio)inorganic chemistry

(2010) Edward I. Solomon et al.   FARADAY DISCUSSIONS

H2Evolution and Molecular Electrocatalysts: Determination of Overpotentials and Effect of Homoconjugation

(2010) Vincent Fourmond et al.   INORGANIC CHEMISTRY

Kinetics of Electron Transfer Reactions of H2-Evolving Cobalt Diglyoxime Catalysts

(2010) Jillian L. Dempsey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hangman Corroles: Efficient Synthesis and Oxygen Reaction Chemistry

(2010) Dilek K. Dogutan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxygen reduction reactivity of cobalt(ii) hangman porphyrins

(2010) Robert McGuire Jr. et al.   Chemical Science

Hydrogen Evolution Catalyzed by Cobaloximes

(2009) Jillian L. Dempsey et al.   ACCOUNTS OF CHEMICAL RESEARCH

Principles, Efficiency, and Blueprint Character of Solar-Energy Conversion in Photosynthetic Water Oxidation

(2009) Holger Dau et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Ru−Hbpp Water Oxidation Catalyst

(2009) Fernando Bozoglian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt and nickel diimine-dioxime complexes as molecular electrocatalysts for hydrogen evolution with low overvoltages

(2009) P.-A. Jacques et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects

(2008) Jean-Michel Savéant   CHEMICAL REVIEWS

Electrocatalytic and homogeneous approaches to conversion of CO2to liquid fuels

(2008) Eric E. Benson et al.   CHEMICAL SOCIETY REVIEWS

Oxygen Evolution Catalysis by a Dimanganese Complex and Its Relation to Photosynthetic Water Oxidation

(2008) Ranitendranath Tagore et al.   INORGANIC CHEMISTRY