Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 49, Pages 17650-17656Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201502943
Keywords
carbonylation; cross-coupling; heterogeneous catalysis; palladium; synthesis design
Categories
Funding
- NSFC [21472174]
- Education Department of Zhejiang Province [Y201432060]
- Zhejiang Sci-Tech University [1206838-Y, 14062015-Y]
- Matthias Beller in LIKAT
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A practical palladium-catalyzed carbonylative Suzuki coupling of aryl halides under carbon monoxide gas-free conditions has been developed. Here, formic acid was utilized as the carbon monoxide source for the first time with acetic anhydride as the additive. A variety of diaryl-ketones were produced in moderate to excellent yields from the corresponding aryl halides and arylboronic acids.
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