Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 22, Pages 8090-8095Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201405748
Keywords
amination; electrochemistry; graphene; hydrothermal synthesis; oxygen reduction reaction
Categories
Funding
- Ministry of Education, Singapore [MOE2013-T2-1-056, ARC 35/13]
- Czech Science Foundation (GACR) [15-09001S]
- Specific University Research (MSMT) [20/2015]
Ask authors/readers for more resources
Nitrogen functionalization of graphene offers new hybrid materials with improved performance for important technological applications. Despite studies highlighting the dependence of the performance of nitrogen-functionalized graphene on the types of nitrogen functional groups that are present, precise synthetic control over their ratio is challenging. Herein, the synthesis of nitrogen-functionalized graphene rich in amino groups by a Bucherer-type reaction under hydrothermal conditions is reported. The efficiency of the synthetic method under two hydrothermal conditions was examined for graphite oxide produced by Hummers and Hofmann oxidation routes. The morphological and structural properties of the amino-functionalized graphene were fully characterized. The use of a synthetic method with a well-known mechanism for derivatization of graphene will open new avenues for highly reproducible functionalization of graphene materials.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available