Silicon-Heteroaromatic [FeFe] Hydrogenase Model Complexes: Insight into Protonation, Electrochemical Properties, and Molecular Structures

A sterically stabilized FeI–FeI semi-rotated conformation of [FeFe] hydrogenase subsite model

(2015) Roman Goy et al.   DALTON TRANSACTIONS

Mimicking hydrogenases: From biomimetics to artificial enzymes

(2014) Trevor R. Simmons et al.   COORDINATION CHEMISTRY REVIEWS

Redox Reactions of [FeFe]-Hydrogenase Models Containing an Internal Amine and a Pendant Phosphine

(2014) Dehua Zheng et al.   INORGANIC CHEMISTRY

The oxidative inactivation of FeFe hydrogenase reveals the flexibility of the H-cluster

(2014) Vincent Fourmond et al.   Nature Chemistry

Conformational Mobility and Pendent Base Effects on Electrochemistry of Synthetic Analogues of the [FeFe]-Hydrogenase Active Site

(2014) Danielle J. Crouthers et al.   ORGANOMETALLICS

Metalloprotein mimics – old tools in a new light

(2014) Thomas Happe et al.   TRENDS IN BIOTECHNOLOGY

Molecular dynamics study of the proposed proton transport pathways in [FeFe]-hydrogenase

(2013) Bojana Ginovska-Pangovska et al.   BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS

Crystallographic Characterization of a Fully Rotated, Basic Diiron Dithiolate: Model for the HredState?

(2013) Wenguang Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

New FeI-FeIComplex Featuring a Rotated Conformation Related to the [2 Fe]HSubsite of [Fe-Fe] Hydrogenase

(2013) Sabrina Munery et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Silicon-Heteroaromatic System as Photosensitizer for Light-Driven Hydrogen Production by Hydrogenase Mimics

(2013) Roman Goy et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

The Influence of OH Groups in [Fe(CO)3]2[(μ-ECH2)2C(CH2OH)2] (E = S, Se) Complexes toward the Cathodic Process

(2013) Ralf Trautwein et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Inaccessibility of the μ-hydride species in [FeFe] hydrogenases

(2013) Arndt R. Finkelmann et al.   Chemical Science

Identification and Characterization of the “Super-Reduced” State of the H-Cluster in [FeFe] Hydrogenase: A New Building Block for the Catalytic Cycle?

(2012) Agnieszka Adamska et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

{1,1′-(Dimethylsilylene)bis[methanechalcogenolato]}diiron Complexes [2Fe2E(Si)] (E=S, Se, Te) - [FeFe] Hydrogenase Models

(2012) Ulf-Peter Apfel et al.   HELVETICA CHIMICA ACTA

Synthetic Models for the Active Site of the [FeFe]-Hydrogenase: Catalytic Proton Reduction and the Structure of the Doubly Protonated Intermediate

(2012) Maria E. Carroll et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Terminal vs Bridging Hydrides of Diiron Dithiolates: Protonation of Fe2(dithiolate)(CO)2(PMe3)4

(2012) Riccardo Zaffaroni et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Spectroscopically characterized intermediates of catalytic H2 formation by [FeFe] hydrogenase models

(2011) Stefanie Tschierlei et al.   Energy & Environmental Science

XAFS and DFT Characterisation of Protonated Reduced Fe Hydrogenase Analogues and Their Implications for Electrocatalytic Proton Reduction

(2011) Mun Hon Cheah et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A Highly Efficient Method for the Copper-Catalyzed Selective Synthesis of Diaryl Chalcogenides from Easily Available Chalcogen Sources

(2011) Yaming Li et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

[Ni(PPh2NC6H4X2)2]2+Complexes as Electrocatalysts for H2Production: Effect of Substituents, Acids, and Water on Catalytic Rates

(2011) Uriah J. Kilgore et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Directing protonation in [FeFe] hydrogenase active site models by modifications in their second coordination sphere

(2010) Salah Ezzaher et al.   CHEMICAL COMMUNICATIONS

Mechanistic aspects of the protonation of [FeFe]-hydrogenase subsite analogues

(2010) Aušra Jablonskytė et al.   DALTON TRANSACTIONS

Influence of the Introduction of Cyanido and Phosphane Ligands in Multifunctionalized (Mercaptomethyl)silane [FeFe] Hydrogenase Model Systems

(2010) Ulf-Peter Apfel et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Models for the Active Site in [FeFe] Hydrogenase with Iron-Bound Ligands Derived from Bis-, Tris-, and Tetrakis(mercaptomethyl)silanes

(2010) Ulf-Peter Apfel et al.   INORGANIC CHEMISTRY

Synthesis of Diiron Hydrogenase Mimics Bearing Hydroquinone and Related Ligands. Electrochemical and Computational Studies of the Mechanism of Hydrogen Production and the Role of O−H···S Hydrogen Bonding†

(2010) Jinzhu Chen et al.   ORGANOMETALLICS

Biomimetic Model Featuring the NH Proton and Bridging Hydride Related to a Proposed Intermediate in Enzymatic H2Production by Fe-Only Hydrogenase

(2009) Ming-Hsi Chiang et al.   INORGANIC CHEMISTRY

DFT/TDDFT Exploration of the Potential Energy Surfaces of the Ground State and Excited States of Fe2(S2C3H6)(CO)6: A Simple Functional Model of the [FeFe] Hydrogenase Active Site

(2009) Luca Bertini et al.   JOURNAL OF PHYSICAL CHEMISTRY A

One- to Two-Electron Reduction of an [FeFe]-Hydrogenase Active Site Mimic: The Critical Role of Fluxionality of the [2Fe2S] Core

(2009) Greg A. N. Felton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unveiling How Stereoelectronic Factors Affect Kinetics and Thermodynamics of Protonation Regiochemistry in [FeFe] Hydrogenase Synthetic Models: A DFT Investigation

(2009) Giuseppe Zampella et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

One-Electron and Two-Electron Transfers in Electrochemistry and Homogeneous Solution Reactions

(2008) Dennis H. Evans   CHEMICAL REVIEWS

Hydrogen production using cobalt-based molecular catalysts containing a proton relay in the second coordination sphere

(2008) George M. Jacobsen et al.   Energy & Environmental Science

Influence of a Pendant Amine in the Second Coordination Sphere on Proton Transfer at a Dissymmetrically Disubstituted Diiron System Related to the [2Fe]HSubsite of [FeFe]H2ase

(2008) Salah Ezzaher et al.   INORGANIC CHEMISTRY

A New Class of Efficient Electrocatalysts for the Reduction of Protons into Hydrogen Based on the [Mo2O2S2]2+Building Block

(2008) Bineta Keita et al.   Journal of Physical Chemistry C

Aza- and Oxadithiolates Are Probable Proton Relays in Functional Models for the [FeFe]-Hydrogenases

(2008) Bryan E. Barton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY