Journal
ORGANOMETALLICS
Volume 35, Issue 17, Pages 2944-2954Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.6b00472
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Funding
- Ministry of Higher Education and Scientific Research of Iraq
- EU [212942]
- ARC [FT120100073, DP140100855]
- International Postgraduate Research Scholarship
- University of Western Australia
- EPSRC [EP/H035184/1, EP/K007785/1]
- EPSRC [EP/K039687/1, EP/K007785/1, EP/M029522/1, EP/H035184/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/M029522/1, EP/K039687/1, EP/H035184/1, EP/K007785/1] Funding Source: researchfish
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The single-molecule conductance of metal complexes of the general forms trans-Ru(C CArC CY)(2)(dppe)(2) and trans-Pt(C C=CY)(2)(PPh3)(2) (Ar = 1,4-C6H2-2,5-(OC6H13)(2); Y = 4-C5H4N, 4-C6H4SMe) have been determined using the STM I(s) technique. The complexes display high conductance (Y = 4-C5H4N, M = Ru (0.4 +/- 0.18 nS), Pt (0.8 +/- 0.5 nS); Y = 4-C6H5SMe, M = Ru (1.4 +/- 0.4 nS), Pt (1.8 +/- 0.6 nS)) for molecular structures of ca. 3 nm in length, which has been attributed to transport processes arising from tunneling through the tails of LUMO states.
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