Article
Chemistry, Inorganic & Nuclear
Alice Johnson, Cameron G. Royle, Claire N. Brodie, Antonio J. Martinez-Martinez, Simon B. Duckett, Andrew S. Weller
Summary: Rhodium-alkene complexes with different alkenes have been studied for their reactivity towards H-2, with only COD showing significant reaction to form a COE complex. The differences in reactivity are attributed to intramolecular alkene-assisted reductive elimination in the COD complex. Further experiments on ethene complex suggest that reductive elimination from a reversibly formed alkyl hydride intermediate is likely rate-limiting and with a high barrier.
INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Suvam Saha, Anagha Haridas, Faneesha Assanar, Charu Bansal, P. K. Sudhadevi Antharjanam, Sundargopal Ghosh
Summary: The reaction between Cp* based ruthenium and molybdenum complexes with different boranes was investigated. The result showed that the ruthenium complexes formed various dihydridoborate complexes at room temperature, while the molybdenum complexes formed agostic borate species at elevated temperatures.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Multidisciplinary
Samaneh Hokmi, Sadegh Salehzadeh, Yasin Gholiee
Summary: This paper presents a computational study on various metal complexes, investigating their bonding energies, bond properties, and the possible existence of cooperativity/anticooperativity between different types of bonds. The results provide valuable insights into the behavior of these complexes.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Sunny Kai San Tse, Herman Ho-Yung Sung, Ian Duncan Williams, Guochen Jia
Summary: The reactions of Cp*OsCl(PPh3)(2) with alkynes and alkynols have been investigated, revealing specific vinylidene and cyclocarbene complexes formed with different substrates. The outcome of the reactions with alkynols depends on the length of the linker, with different products obtained depending on the specific structure of the alcohol.
CANADIAN JOURNAL OF CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Peng Xu, Abdul Rauf, Muhammad Naeem, Adnan Aslam, Hafiz Muhammad Mueez Amin, Qammar Rubbab
Summary: Topological indices are quantitative parameters used to describe the atomic topology of graphs and can predict the physical and chemical characteristics of chemical compounds. Graph theory has significant applications in measuring the relationship between topological indices and associated graphs.
ARABIAN JOURNAL OF CHEMISTRY
(2022)
Article
Mathematics, Applied
Vinod Kumar Jatav, A. K. Shukla
Summary: The aim of this paper is to introduce and establish properties of matrix polynomials L(M, Δ, λ) n (x), including hypergeometric representation, generating matrix relations, integral representations, recurrence relations, summation formulas, series relation, fractional integral and derivative operators.
Article
Chemistry, Inorganic & Nuclear
Peng Yang, Mahmoud Elcheikh Mahmoud, Yixian Xiang, Zhengguo Lin, Xiang Ma, Jonathan H. Christian, Jasleen K. Bindra, Jared S. Kinyon, Yue Zhao, Chaoqin Chen, Talha Nisar, Veit Wagner, Naresh S. Dalal, Ulrich Kortz
Summary: A family of five host-guest assemblies with different metal ions were synthesized and characterized. CuPd12As8 was found to exhibit higher catalytic activity in the hydroconversion reaction.
INORGANIC CHEMISTRY
(2022)
Article
Mathematics
K. Pushpa, K. R. Vasuki
Summary: In this article, we evaluated the convolution sums Sigma(al+bm=n) sigma(l)sigma(m) for a . b = 15, where a, b are natural numbers, using an elementary method. The deduced results are in a more elegant form compared to the previous derivation by B. Ramakrishnan and B. Sahu [24]. Additionally, we derived a formula to determine the number of representations of a positive integer n by the octonary quadratic form.
INDIAN JOURNAL OF PURE & APPLIED MATHEMATICS
(2022)
Article
Chemistry, Inorganic & Nuclear
Thomas M. Scherer, Ingo Hartenbach, Falk Lissner, Brigitte Schwederski, Ralph Huebner, Jan Fiedler, Stanislav Zalis, Biprajit Sarkar, Wolfgang Kaim
Summary: Neutral complexes [M-II(C5Me5)(Q(2-))(NO+)] with M=Ru or Os and the catecholates Q(2-) with 3,5-di-tert-butyl (dtbc) or 3,4,5,6-tetrachloro substituents (tcc) were identified with determined oxidation and charge states. Reversible electron transfer process was analyzed through spectroelectrochemical methods, supported by DFT calculations, revealing the dependence of redox potentials on the donor or acceptor substitution pattern at Q(n).
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
(2021)
Article
Chemistry, Physical
Matthias Gottschalk
Summary: This passage discusses the calculation of integrals as functions of density and temperature using pair and triplet correlation functions derived from extensive Monte-Carlo simulations. It also mentions the calculation of quadruplet correlation functions for the M- and N-integrals using the trans-superposition approximation.
Article
Physics, Multidisciplinary
A. P. Chaynikov, A. G. Kochur, A. Dudenko, V. A. Yavna
Summary: The final ion yields and mean final ion charges of single vacancies in different electron shells of atomic silver were calculated using the method of construction and analysis of decay trees. The effect of shake-offs caused by cascade transitions on the final ion yields was found to be small. Total semi-relativistic Pauli-Fock energies were used to accurately calculate cascade transition energies and account for non-radiative transitions and multiplet splitting. Accurate calculation of transition energies and consideration of multiplet splitting were found to be crucial in simulating cascades in heavy atoms.
Article
Chemistry, Physical
Mingcheng Huang, Li Fan, Yiqi Jin, Yudi Niu, Xiaofang Bai, Shaoyi Xu, Jiantao Fan, Hui Li
Summary: SupportingIrO(2) with conductive oxides can increase the conductivity and decrease the loading of the catalyst layer in proton exchange membrane electrolyzers. This study proposed a high-throughput aerogel synthesis method to fabricate Sn-Sb-Nb ternary oxide supports and systematically investigated their thermal stability, conductivity, and acidic stability. The results showed that Nb addition improved the thermal stability and acidic stability of the ternary oxides.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Engineering, Multidisciplinary
Fahrettin Ozbey
Summary: This paper proposes a shock model for an m-consecutive-k, l-out-of-n: F system and presents a method for reliability analysis using phase-type distributions. The study aims to show how phase-type distributions can be used to determine system reliability while also addressing the optimal replacement time problem.
PROCEEDINGS OF THE INSTITUTION OF MECHANICAL ENGINEERS PART O-JOURNAL OF RISK AND RELIABILITY
(2022)
Article
Mathematics
O. M. Martynov
Summary: This paper considers projections of the space l(infinity)(mn) onto a certain class of subspaces of codimension m formed by using hyperplanes of l(infinity)(mn), and calculates relative projection constants and constants of strong uniqueness.
ANNALES POLONICI MATHEMATICI
(2022)
Article
Optics
A. P. Chaynikov, A. G. Kochur, A. I. Dudenko, V. A. Yavna
Summary: Cascade decays of single vacancies in the K, L, M, and N shells of the silver atom were studied. Calculations were performed for the spectra of cascade-produced electrons and photons emitted during the decay of single vacancies. The energy absorbed by the silver atom, as well as the energy carried away by cascade electrons and photons, was calculated for each initial vacancy. The study found that absorption of energy by the silver atom itself was significant only during N- and M-shell ionization.
JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER
(2023)
Article
Chemistry, Multidisciplinary
Ai-Min Li, Yi Wang, Domonique O. Downing, Fu Chen, Peter Zavalij, Alvaro Munoz-Castro, Bryan W. Eichhorn
CHEMISTRY-A EUROPEAN JOURNAL
(2020)
Article
Physics, Multidisciplinary
Chris Eckberg, Daniel J. Campbell, Tristin Metz, John Collini, Halyna Hodovanets, Tyler Drye, Peter Zavalij, Morten H. Christensen, Rafael M. Fernandes, Sangjun Lee, Peter Abbamonte, Jeffrey W. Lynn, Johnpierre Paglione
Article
Materials Science, Multidisciplinary
M. C. Palenik, C. A. Klug, M. W. Conroy, S. A. Fischer, D. Gunlycke, B. Dunlap, L. Stevens, P. Zavalij, B. Eichhorn
PHYSICAL REVIEW MATERIALS
(2020)
Article
Engineering, Manufacturing
Jacob C. Simmons, Xiaobo Chen, Arad Azizi, Matthias A. Daeumer, Peter Y. Zavalij, Guangwen Zhou, Scott N. Schiffres
ADDITIVE MANUFACTURING
(2020)
Article
Chemistry, Multidisciplinary
Weijian Xue, Peter Y. Zavalij, Lyle Isaacs
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2020)
Article
Chemistry, Physical
Greg Brewer, Raymond J. Butcher, Peter Zavalij
Article
Chemistry, Multidisciplinary
Steven Murkli, Jared Klemm, David King, Peter Y. Zavalij, Lyle Isaacs
CHEMISTRY-A EUROPEAN JOURNAL
(2020)
Article
Chemistry, Organic
Xiaoyong Lu, Sandra A. Zebaze Ndendjio, Peter Y. Zavalij, Lyle Isaacs
Article
Multidisciplinary Sciences
Y. G. Liang, S. Lee, H. S. Yu, H. R. Zhang, Y. J. Liang, P. Y. Zavalij, X. Chen, R. D. James, L. A. Bendersky, A. Davydov, X. H. Zhang, I Takeuchi
NATURE COMMUNICATIONS
(2020)
Article
Chemistry, Physical
Mark A. Wallace, Peter Y. Zavalij, Lawrence R. Sita
Article
Nanoscience & Nanotechnology
A. R. Kytsya, L. I. Bazylyak, I. Yu. Zavaliy, Yu. V. Verbovytskyy, P. Zavalij
Summary: Bimetallic Ni-Cu nanoparticles with different (Ni/Cu) ratio were synthesized through a fast and simple reduction process in water/ethylene glycol solutions. The nanoparticles showed polydisperse sizes within 20-70 nm, with the particle diameter slightly depending on the Ni/Cu ratio. Additionally, XRD and EDX analyses revealed changes in lattice parameters and core-shell structure, respectively.
APPLIED NANOSCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Ai-Min Li, Yi Wang, Peter Y. Zavalij, Fu Chen, Alvaro Munoz-Castro, Bryan W. Eichhorn
CHEMICAL COMMUNICATIONS
(2020)
Article
Chemistry, Multidisciplinary
Lei Liu, Wes Lee, Cassandra R. Youshaw, Mingbin Yuan, Michael B. Geherty, Peter Y. Zavalij, Osvaldo Gutierrez
Article
Chemistry, Multidisciplinary
Songjun Xiao, Wes Lee, Fu Chen, Peter Y. Zavalij, Osvaldo Gutierrez, Jeffery T. Davis
CHEMICAL COMMUNICATIONS
(2020)
Article
Chemistry, Multidisciplinary
Sandra Zebaze Ndendjio, Wenjin Liu, Nicolas Yvanez, Zihui Meng, Peter Y. Zavalij, Lyle Isaacs
NEW JOURNAL OF CHEMISTRY
(2020)