Article
Chemistry, Organic
Tandra Kundu, Bijeta Mitra, Pranab Ghosh
Summary: This article describes a simple and efficient synthesis method based on humic acid, which can catalyze the synthesis of 1-amidoalkyl-2-naphthols and 1-thioamidoalkyl-2-naphthols in water. The method has advantages such as moderate to excellent yields, easy operation, mild reaction conditions, the use of water as a green solvent, and a reusable catalyst.
SYNTHETIC COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Mohammad Amin Manavi, Mohammad Hosein Fathian Nasab, Fatemeh Dashti, Setareh Moghimi, Parastoo Saniee, Behjat Pouramiri, Alireza Foroumadi, Morteza Pirali-Hamedani
Summary: This work presents an efficient method for the synthesis of amidoalkyl naphthol derivatives and their in vitro anti-Helicobacter pylori activity. The method uses a green and reusable catalyst, shows high yields, requires no column chromatography, and is cost-effective.
RESEARCH ON CHEMICAL INTERMEDIATES
(2022)
Article
Chemistry, Multidisciplinary
Rachid Azzallou, Oussama Ouerghi, Mohammed H. Geesi, Yassine Riadi, Mohamed Ait Taleb, Rachid Mamouni, Said Lazar, Abdellah Kaiba, Mehnaz Kamal, Sylvie Villain
Summary: Waste-derived materials have emerged as promising catalysts for green chemistry. In this study, waste bovine bone-derived hydroxyapatite (BBHA) loaded with zinc chloride (ZnCl2) was used as a catalyst for synthesizing 1-amidoalkyl-2-naphthols derivatives. The reaction conditions were optimized and the desired compounds were obtained with high yields and sustainability.
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
(2022)
Article
Engineering, Environmental
Xinxin Dong, Jinji Xi, Bing Song, Mengjie Zhang, Baosheng Jin
Summary: In this study, waste granular silica gel was reused as a nickel-based catalyst support. The Ni/WGSG catalysts showed good performance in the dry reforming of methane (DRM) reaction, with the Ni/WGSG-2 catalyst exhibiting the highest activity. The catalysts also demonstrated good stability under different working conditions.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Organic
Chiliveru Priyanka, Muppidi Subbarao, Nagender Punna
Summary: A highly regio- and stereoselective palladium-catalyzed ortho-vinylation of beta-naphthols has been reported using accessible CF3-allyl carbonates, leading to the formation of (Z)-CF3-vinylnaphthols in good yields. Furthermore, a one-pot synthesis of CF3-naphtho[2,1-b]furans was achieved through an uninterrupted ortho-vinylation/oxidative radical cyclization reaction sequence.
ORGANIC & BIOMOLECULAR CHEMISTRY
(2021)
Article
Chemistry, Applied
Wipark Anutrasakda, Pawnprapa Pitakjakpipop
Summary: This study synthesized nickel phosphide nanocatalysts with different ratios and investigated their performance in the conversion of cellobiose to sorbitol. The results showed that different crystalline phases of nickel phosphide influenced the product proportions, and the impact of reaction temperature and support materials on catalytic performance was also studied.
Article
Chemistry, Applied
Masoud Mohammadi, Arash Ghorbani-Choghamarani
Summary: This study reports the synthesis of Hercynite nanoparticles capped with a novel Schiff base-manganese(II) complex. The catalyst exhibits excellent dispersibility, stability, and small size, resulting in high catalytic activity and selectivity. The catalyst is also sustainable and recyclable, allowing for the rapid synthesis of organic compounds at ambient conditions.
APPLIED ORGANOMETALLIC CHEMISTRY
(2022)
Article
Materials Science, Multidisciplinary
Wei Han, Songfa Qiu, Junfeng Chen, Ximing Zhong, Li Hao, Huayao Chen, Xinhua Zhou, Hongjun Zhou
Summary: A one-pot method was proposed in this work to prepare polydopamine-coated mesoporous silica-supported nano-metal oxide composites with good antibacterial properties. The composites showed a regular spherical shape with nano-metal oxides formed in the pores of mesoporous silica. Among them, MSN-C/ZnO and MSN-C/CuZnO exhibited better antibacterial performance and lower minimal inhibitory concentration. Therefore, these composites have potential applications as effective antibacterial products in the medical field.
MATERIALS CHEMISTRY AND PHYSICS
(2022)
Article
Chemistry, Multidisciplinary
Aleksei N. Smirnov, Simar F. Aslanov, Denis V. Danilov, Olga Yu. Kurapova, Elena V. Solovyeva
Summary: This work proposes a simple and rapid method for preparing bone-shaped gold nanoparticles with a dye-impregnated silica shell. Functionalization of the nanostructures with a delivery vector using folic acid is demonstrated. The prepared tags show surface-enhanced Raman scattering (SERS) spectra and can be used for cell imaging. The MTT assay reveals higher viability for HEP G2 cells.
Article
Agricultural Engineering
Lihe Zhu, Xueting Shao, Xuejun Pan, Zhong Sun, Xiangyu Li, Xixin Duan, Junyou Shi
Summary: Catalytic conversion of waste biomass to furfural using hetero-polyacid catalysts supported on H-ZSM-5 zeolite was investigated. The PW12/ZSM-5 catalyst with low PW12 loading showed high efficiency in converting biomass (xylose, xylan, and corn stover) to furfural at moderate temperature (130°C), with yields of 73.3% (xylose) and 75.1% (xylan). The PW12 loading and acid sites distribution were found to be crucial for the catalytic performance. Additionally, the presence of LiBr enhanced the furfural yield due to its Lewis acidity. The PW12/ZSM-5 based solid polyacid catalyst showed promise for efficient furfural production from biomass with high yield and easy separation.
BIOMASS & BIOENERGY
(2023)
Article
Chemistry, Organic
Baofu Zhu, Jiaming He, Kai Zou, Anquan Li, Chen Zhang, Jiaji Zhao, Hua Cao
Summary: This study established a three-component reaction catalyzed by base, involving ynals, isocyanates, amines, and alcohols. The strategy enables a wide range of substrates and provides a simple process for the preparation of diverse pyridine derivatives with good yields and high regioselectivities.
JOURNAL OF ORGANIC CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Jamal Davarpanah, Parizad Rezaee, Mahboubeh Ghahremani, Nafiseh Hajiabdolah
Summary: In this research, a new catalyst SBA-NH-NHCO-COOH is synthesized and classified through various characterization techniques. The catalytic activity of the nanocomposite is successfully demonstrated in the synthesis of 1-amidoalkyl-2-naphthols. Furthermore, the chemical shift values, X-ray spectra, and structural characteristics of the compound are studied in depth and compared with computed values.
RESEARCH ON CHEMICAL INTERMEDIATES
(2022)
Article
Chemistry, Multidisciplinary
Razieh Rahimizadeh, Akbar Mobinikhaledi, Hassan Moghanian, Seyedeh Sara Kashaninejad
Summary: The functionalized silica-coated Fe3O4 nanoparticles Fe3O4@SiO2-TETA-SO3H were synthesized by stabilizing the sulfonic group on the surface. The nanoparticles exhibited excellent catalytic activity for the synthesis of amidoalkyl naphthols using fatty acids as resources, with high yields and easy work-up. Additionally, the synthesized products showed biological activity against Staphylococcus aureus and Escherichia coli.
RESEARCH ON CHEMICAL INTERMEDIATES
(2022)
Article
Chemistry, Multidisciplinary
Zeyang Liu, Yongjie Wang, Kaihong Liu, Shanshan Wang, Haocheng Liao, Yuanli Zhu, Baoming Hou, Chunxia Tan, Guohua Liu
Summary: This study developed a cost-efficient hydration/asymmetric transfer hydrogenation (ATH) process for the synthesis of valuable chiral alcohols from alkynes, achieving good yields with up to 99% ee values. The immobilized Ru/diamine catalyst could be recycled at least three times in the sequential reaction system, demonstrating a general method for sustainable organic synthesis through one-pot asymmetric sequential catalysis.
FRONTIERS IN CHEMISTRY
(2021)
Article
Chemistry, Applied
Tianxiang Zhao, Guangcai Long, Hua Liang, Wenjie Xiong, Xingbang Hu
Summary: A series of [Im][HCO3]@SBA-15 supported ionic liquids (SILs) catalysts were prepared by anion exchange and solvent-free mehcanochemical grafting strategies for the direct synthesis of cyclic carbonates from olefins and CO2. The as-prepared [Im][HCO3]@SBA-15 catalysts exhibited excellent catalytic activity and selectivity for the one-pot synthesis of cyclic carbonates, providing moderate to excellent yields. The catalysts showed excellent reusability and stability, making them a promising option for CO2 conversion.
MICROPOROUS AND MESOPOROUS MATERIALS
(2023)
Article
Chemistry, Physical
Esmail Rezaei-Seresht, Hasan Balali, Behrooz Maleki
Summary: Adamantane has garnered significant attention for its distinct structure and properties in constructing nanostructured entities. This study successfully synthesized a novel hexakis (4-hydroxyphenyl) derivative and a hexahydroxy derivative.
FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES
(2023)
Article
Chemistry, Organic
Farin Laffafchi, Mahmood Tajbakhsh, Yaghoub Sarrafi, Behrooz Maleki, Milad Ghani
Summary: The present study developed a mild and green synthesis method for synthesizing 1,2,3-triazoles through click reaction. Creatine derivative functional groups were linked to the magnetic nanostructure, and Cu(II) ions were introduced as the catalyst for efficient catalytic action. This method offers advantages such as high reusability and efficiency.
POLYCYCLIC AROMATIC COMPOUNDS
(2023)
Article
Chemistry, Multidisciplinary
Esmail Rezaei-Seresht, Fatemeh Tafazzoli Gazkoh, Behrooz Maleki
Summary: This work describes the synthesis and characterization of a heterogeneous catalyst consisting of piperazine-functionalized reduced graphene oxide decorated with Fe3O4 nanoparticles. The catalyst showed great catalytic activity for Pechmann synthesis of coumarins, and its reusability was also studied. The results indicate that the catalyst is efficient, easy to separate, and can be used for multiple reactions.
Article
Chemistry, Organic
Seyedeh Fatemeh Hojati, Nasrin Moeini-Eghbali, Sara Mohammadi, Ali Jamshidi, Farokhzad Mohammadi Zonoz, Behrooz Maleki
Summary: A nanohybrid ionic liquid based on polyoxometalate has been synthesized and characterized, and its catalytic activity in multi-component reactions to generate pyran and spiro indoline derivatives has been studied. Tetrahydrobenzo[b]pyrans and multi-substituted spiro[indoline-3,4?-pyrano[2,3-c]pyrazole] have been successfully synthesized using this heterogeneous nano-catalyst, with advantages of high yields, easy work-up procedure, short reaction time, stability, non-toxicity, cheapness and reusability of the catalyst.
POLYCYCLIC AROMATIC COMPOUNDS
(2023)
Article
Chemistry, Organic
Hanieh Boroumand, Heshmatollah Alinezhad, Behrooz Maleki, Sahar Peiman
Summary: In this study, a reusable magnetic graphene oxide catalyst was used for the efficient preparation of 2-amino-4H-benzopyran derivatives. The method exhibited green reaction conditions, easy separation, cost-effectiveness, and high yield. Furthermore, the catalyst showed good recyclability with minimal performance degradation after multiple cycles.
POLYCYCLIC AROMATIC COMPOUNDS
(2023)
Article
Materials Science, Multidisciplinary
Behrooz Maleki, Ehsan Koushki, Heshmatollah Alinezhad, Mahmood Tajbakhsh, Milad Ghani, Sahar Peiman, Faegheh Ghasempour Nesheli
Summary: This study focuses on synthesizing tetrazole dye and conducting Z-scan measurements on the synthesized compounds. The results obtained shed light on the origin of positive nonlinear absorption coefficients in dye molecules. The linear optical properties of the synthesized dyes were investigated using UV absorption and fluorescence emission spectrum. Additionally, density functional theory (DFT) was utilized to optimize the electronic characteristics and molecular geometry of the sensitizers, to study the impact of dye structure on their nonlinear optical performances.
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
(2023)
Article
Chemistry, Inorganic & Nuclear
Maryam Abasian, Rahele Zhiani, Alireza Motavalizadehkakhky, Hossein Eshghi, Jamshid Mehrzad
Summary: A green and cost-effective method for reducing CO2 to synthesize formate salts using nanosized polyoxomolybdate caprate [Mo368] supported by cellulose inter-dendritic fibrous nanosilica (DFNS) was reported. The cellulose acted as a substrate to control metal leaching and the products were easily isolated from the catalyst. The experimental results confirmed the role of sodium polyoxomolybdate in the hydrogenation of CO2.
INORGANIC CHEMISTRY COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Ehsan Khoshkalam, Amir Fotovat, Akram Halajnia, Hossein Kazemian, Hossein Eshghi
Summary: This research studied the stability and reactivity of green iron oxide nanoparticles (EL-Fe NPs) synthesized from Eucalyptus globulus leaf extract in removing NO3- ions from polluted water. Various characterization techniques were used to analyze the EL-Fe NPs, and the effect of different factors such as contact time, pH, KCl salt, and anions on the adsorption of NO3- by EL-Fe NPs was evaluated. The results showed that EL-Fe NPs had irregular nano-particulate structures and exhibited strong adsorption capacity for NO3- at certain conditions, but the adsorption was influenced by pH, salt concentration, and the presence of phosphate ions.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Chemistry, Applied
Hossein Torabi, Kamran Lamei, Hossein Eshghi, Ali Hafizi
Summary: In this study, a successful strategy for generating palladium nanoparticles on porous P-doped carbon spheres with a high surface area was reported. The synthesized Pd/P-CS was used as a catalyst for the CO2 fixation reaction with various epoxides under solvent-free conditions. The prepared Pd-0/P-CS nanocatalyst was confirmed through various analysis techniques and exhibited outstanding catalytic performance in the synthesis of cyclic carbonates under solvent-free conditions.
JOURNAL OF POROUS MATERIALS
(2023)
Article
Multidisciplinary Sciences
Sara S. E. Ghodsinia, Hossein Eshghi, Arezou Mohammadinezhad
Summary: In this study, a double-shelled periodic mesoporous organosilica nanospheres/MIL-88A-Fe (DSS/MIL-88A-Fe) composite was synthesized through a hydrothermal method. Spectroscopic and microscopic techniques were used to characterize the structural and compositional features of the composite. The integration of MOF with PMO led to a structure with a dual-shelled morphology, microporous structure, and large specific surface area. The as-prepared composite exhibited high adsorption capacity and quick adsorption time for the removal of Pb2+ from water, along with acceptable recycling and stability.
SCIENTIFIC REPORTS
(2023)
Article
Multidisciplinary Sciences
Behrooz Maleki, Reza Sandaroos, Sahar Peiman
Summary: Six catalysts MnL1-MnL6, containing two crown ether rings and their analogs supported on the MCM-41 heterogeneous substrate (MnL1@MCM41-MnL5@MCM41), were synthesized and characterized. The mixture of molecular oxygen as an oxidant and these catalysts were used for the epoxidation of styrene. The supported catalysts showed better performance compared to the unsupported analogs, and they did not require an axial base and reducing agent.
Article
Environmental Sciences
Huazhong Liu, Mehdi Baghayeri, Amirhasan Amiri, Fatemeh Karimabadi, Marziyeh Nodehi, Maryam Fayazi, Behrooz Maleki, Ehsan Nazarzadeh Zare, Afsaneh Kaffash
Summary: In this work, a new dendrimer modified magnetic graphene oxide (GO) was used as a substrate for electrodeposition of Au nanoparticles. The modified magnetic electrode was employed for sensitive measuring of As(III) ion as a well-established human carcinogen. The prepared electrochemical device exhibits excellent activity towards As(III) detection using the square wave anodic stripping voltammetry (SWASV) protocol. At optimum conditions (deposition potential at -0.5 V for 100 s in 0.1 M acetate buffer with pH 5.0), a linear range from 1.0 to 125.0 μgL-1 with a low detection limit (calculated by S/N = 3) of 0.47 μg L-1 was obtained. In addition to the simplicity and sensitivity of the proposed sensor, its high selectivity against some major interfering agents, such as Cu(II) and Hg(II) makes it an appreciable sensing tool for the screening of As(III). In addition, the sensor revealed satisfactory results for detection of As(III) in different water samples, and the accuracy of obtained data were confirmed by inductively coupled plasma atomic emission spectroscopy (ICP-AES) setup. Accounting for the high sensitivity, remarkable selectivity and good reproducibility, the established electrochemical strategy has great potential for analysis of As(III) in environmental matrices.
ENVIRONMENTAL RESEARCH
(2023)
Article
Biochemical Research Methods
Hossein Sabet-Sarvestani, Hossein Eshghi, Mohammad Izadyar, Nazanin Noroozi-Shad, Foroogh Arkan
Summary: The effective factors in the performance of Oligo (p-phenylenes) (OPPs) and Polycyclic Aromatic Hydrocarbons (PAHs) as organocatalysts in photocatalytic CO2 transformations were investigated using density functional theory calculations. The study focused on the mechanistic aspects of C-C bond formation in a coupling reaction between CO2 center dot- and amine radical. The results showed that the charge density and aromatic properties of the studied organocatalysts and rings played important roles in the kinetic aspects of the electron transfer steps.
JOURNAL OF MOLECULAR GRAPHICS & MODELLING
(2023)
Article
Chemistry, Multidisciplinary
Fahimeh Assadzadeh, Toktam Afrough, Hossein Eshghi, Hossein Sabet-Sarvestani
Summary: A convenient one-pot two-step strategy was used to synthesize a novel tricyclic compound, and its inhibitory effect against bromodomain-containing protein 4 (BRD4) was evaluated.
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Sanaz Naderi, Reza Sandaroos, Sahar Peiman, Behrooz Maleki
Summary: A new Schiff base ligand complexed with Mn (III) metal was synthesized and used with oxone oxidant in water-chloroform biphasic oxidation. The complex was able to oxidize different alkenes to corresponding epoxides with yields of 70-96%, with the lowest efficiency observed for alkenes with electron-withdrawing groups.
CHEMICAL METHODOLOGIES
(2023)