Synthesis of Hydrazide-Containing Chroman-2-ones and Dihydroquinolin-2-ones via Photocatalytic Radical Cascade Reaction of Aroylhydrozones

A general and efficient visible light photocatalytic a-amino carbon radical -based cascade reaction of aroylhydra-zones has been described. This protocol tolerates a wide array of alpha-silylamines and aroylhydrazones to afford the corresponding diversely functionalized hydrazide-containing chroman-2-ones and dihydroquinolin-2-ones in generally good yields with excellent diastereoselectivities.