Journal
ORGANIC LETTERS
Volume 18, Issue 19, Pages 5062-5065Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b02508
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Funding
- Indian Institute of Science
- UGC, New-Delhi
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Production of hydrogen from renewable sources, particularly from water, is an intensive area of research, which-has far-reaching relevance in hydrogen economy. A homogeneous catalytic method is presented for producing clean hydrogen gas from water, in a reaction of water with a diboron compound as the reductant, under ambient reaction conditions. The Pd-catalytic system is stable in water and displays excellent recyclability. Hydroxy analogues such as alcohols are compatible with the Pd/B(2)Pin(2) system and generate hydrogen gas efficiently. The B(2)Pin(2)-H2O system, in the presence of palladium, is an excellent catalytic system for selective hydrogenation of olefins.
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