Journal
ORGANIC LETTERS
Volume 18, Issue 23, Pages 6212-6215Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b03304
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Funding
- JSPS KAKENHI Grant [15H03118, 16H01133, 26350971]
- Suntory Foundation for Life Sciences
- Platform for Drug Discovery, Informatics, and Structural Life Science of MEXT, Japan
- Platform for Drug Discovery, Informatics, and Structural Life Science of AMED, Japan
- Grants-in-Aid for Scientific Research [26350971, 16H01133, 15H03118] Funding Source: KAKEN
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A facile synthetic method for preparing 3-amino-2-silylaryl triflates via regioselective silylamination of 3(triflyloxy)arynes with N-silylamines is described. Fluoride mediated generation of 3-aminobenzyne from 3-amino-2-silylphenyl triflate, easily prepared by this method, in the presence of various arynophiles efficiently afforded diverse aniline derivatives, including a 5-aminocoumarin derivative, demonstrating the utility of aryne relay approach.
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