Journal
ORGANIC LETTERS
Volume 18, Issue 7, Pages 1678-1681Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00578
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Funding
- XJTU from a start-up fund
- National Natural Science Foundation of China [21202128, 21572175]
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A transition-metal-free procedure to access to functionalized 2-benzylphenyl ketones is described by direct insertion of arynes into benzylic C-C bonds. This reaction was promoted by cesium fluoride at room temperature, allowing the products to form in high selectivity and achieve good functional group tolerance.
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