Journal
ORGANIC LETTERS
Volume 18, Issue 15, Pages 3726-3729Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01747
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Funding
- National Natural Science Foundation of China [21372268, 21372266]
- Fundamental Research Funds for the Central Universities [106112016CDJZR228806]
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Vicinal diamination of domino aryne precursors was achieved with sulfamides. The reaction proceeds through a two-aryne pathway, accepting two N-nucleophiles at the 1,2-positions of an arene ring. Symmetrical and unsymmetrical diaminobenzenes were readily obtained.
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