Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 14, Pages 5328-5331Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201500335
Keywords
amination; hypervalent; iodine; oxidation; saccharin
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Funding
- National Science Foundation [CHE-1262479]
- Grants-in-Aid for Scientific Research [15K07852] Funding Source: KAKEN
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Three new saccharin-based hypervalent iodine compounds were prepared by the reaction of saccharine with (diacetoxyiodo)arenes or acetoxybenziodoxole. Structures of these new imidoiodanes were established by X-ray crystallography. The saccharin-based mu-oxo-bridged imidoiodane readily reacts with silyl enol ethers under mild conditions to give the corresponding alpha-aminated carbonyl compounds in moderate yields.
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