Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 14, Issue 28, Pages 6683-6686Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob01172a
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Funding
- National Natural Science Foundation of China [21222207, 21572231, 21521002]
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Metal-free hydrogenation of 2,7-disubstituted 1,8-naphthyridines was successfully realized for the first time using in situ generated borane catalysts under mild conditions to furnish 1,2,3,4-tetrahydro-1,8-naphthyridine derivatives in 83-98% yields. Significantly, up to 74% ee was achieved for the corresponding asymmetric hydrogenation reactions.
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