Recent developments in synthetic methods for benzo[b]heteroles

Copper-Catalyzed Cycloaddition between Secondary Phosphine Oxides and Alkynes: Synthesis of Benzophosphole Oxides

(2016) Pengbo Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

TBAI-catalyzed oxidative C–H functionalization: a new route to benzo[b]phosphole oxides

(2016) Yun Zhang et al.   CHEMICAL COMMUNICATIONS

Sulfoxide-directed metal-free cross-couplings in the expedient synthesis of benzothiophene-based components of materials

(2016) Andrew J. Eberhart et al.   Chemical Science

Conversion of Zirconacyclopentadienes into Metalloles: Fagan–Nugent Reaction and Beyond

(2015) Xiaoyu Yan et al.   ACCOUNTS OF CHEMICAL RESEARCH

Environment-Sensitive Fluorescent Probe: A Benzophosphole Oxide with an Electron-Donating Substituent

(2015) Eriko Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphorescence within benzotellurophenes and color tunable tellurophenes under ambient conditions

(2015) Gang He et al.   CHEMICAL COMMUNICATIONS

Diversity-Oriented Synthesis of Substituted Benzo[b]thiophenes and Their Hetero-Fused Analogues through Palladium-Catalyzed Oxidative CH Functionalization/Intramolecular Arylthiolation

(2015) Anand Acharya  et al.   CHEMISTRY-A EUROPEAN JOURNAL

Comparison of 2-Arylnaphtho[2,3-b]phospholes and 2-Arylbenzo[b]phospholes: Effects of 2-Aryl Groups and Fused Arene Moieties on Their Optical and Photophysical Properties

(2015) Yoshihiro Matano et al.   JOURNAL OF ORGANIC CHEMISTRY

One-Pot Synthesis of Functionalized Benzo[b]thiophenes and Their Hetero-Fused Analogues via Intramolecular Copper-Catalyzed S-Arylation of In Situ Generated Enethiolates

(2015) Anand Acharya et al.   JOURNAL OF ORGANIC CHEMISTRY

Ag-mediated cascade decarboxylative coupling and annulation: a convenient route to 2-phosphinobenzo[b]phosphole oxides

(2015) Gaobo Hu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

One-Pot Benzo[b]phosphole Synthesis through Sequential Alkyne Arylmagnesiation, Electrophilic Trapping, and Intramolecular Phospha-Friedel–Crafts Cyclization

(2015) Bin Wu et al.   ORGANIC LETTERS

Intramolecular, Pd/Cu-Co-catalyzed P–C Bond Cleavage and Addition onto an Alkyne: A Route to Benzophospholes

(2015) Yang Zhou et al.   ORGANIC LETTERS

Versatile Synthesis of Phospholides from Open-Chain Precursors. Application to Annelated Pyrrole– and Silole–Phosphole Rings

(2015) Youzhi Xu et al.   ORGANIC LETTERS

Synthesis of silafluorenes and silaindenes via silyl radicals from arylhydrosilanes: intramolecular cyclization and intermolecular annulation with alkynes

(2015) Liang Xu et al.   Organic Chemistry Frontiers

A Highly Modular One-Pot Multicomponent Approach to Functionalized Benzo[b]phosphole Derivatives

(2014) Bin Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A facile and general route to 3-((trifluoromethyl)thio)benzofurans and 3-((trifluoromethyl)thio)benzothiophenes

(2014) Jie Sheng et al.   CHEMICAL COMMUNICATIONS

Phosphorus-Containing Materials for Organic Electronics

(2014) Monika Stolar et al.   Chemistry-An Asian Journal

An Approach to the Selenobromination of Aryl(thienyl)alkynes: Access to 3-Bromobenzo[b]selenophenes and Selenophenothiophenes

(2014) Edgars Paegle et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Direct Synthesis of Diverse 2-Aminobenzo[b]thiophenes via Palladium-Catalyzed Carbon–Sulfur Bond Formation Using Na2S2O3 as the Sulfur Source

(2014) Chuanwei Hou et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Ortho-Alkenylation through C–H Bond Cleavage Directed by Sulfoxide Groups

(2014) Kazunori Nobushige et al.   ORGANIC LETTERS

B(C6F5)3-Catalyzed Synthesis of Benzofused-Siloles

(2014) Liam D. Curless et al.   ORGANOMETALLICS

An Approach to Benzophosphole Oxides through Silver- or Manganese-Mediated Dehydrogenative Annulation Involving CC and CP Bond Formation

(2013) Yuto Unoh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile Synthesis of Benzothiophenes and Benzoselenophenes by Rapid Assembly of Arylzinc Reagents, Alkynes, and Elemental Chalcogens

(2013) Bin Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nucleophilicortho-Propargylation of Aryl Sulfoxides: An Interrupted Pummerer/Allenyl Thio-Claisen Rearrangement Sequence

(2013) Andrew J. Eberhart et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ambient arylmagnesiation of alkynes catalysed by ligandless nickel(ii)

(2013) Fei Xue et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed Synthesis of Benzo[b]thiophenes and Benzothiazoles Using Thiocarboxylic Acids as a Coupling Partner

(2013) Hui Yu et al.   JOURNAL OF ORGANIC CHEMISTRY

Silver-Mediated Oxidative C–H/P–H Functionalization: An Efficient Route for the Synthesis of Benzo[b]phosphole Oxides

(2013) Yun-Rong Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trace amount Cu (ppm)-catalyzed intramolecular cyclization of 2-(gem-dibromovinyl)phenols(thiophenols) to 2-bromobenzofurans(thiophenes)

(2013) Yong Ji et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Direct Benzothiophene Formation via Oxygen-Triggered Intermolecular Cyclization of Thiophenols and Alkynes Assisted by Manganese/PhCOOH

(2013) Kaisheng Liu et al.   ORGANIC LETTERS

Synthesis of 2-Alkenyl- and 2-Alkynyl-benzo[b]phospholes by Using Palladium-Catalyzed Cross-Coupling Reactions

(2013) Yoshihiro Matano et al.   ORGANIC LETTERS

Synthesis and Characterization of Benzo[b]phosphaferrocene Derivatives

(2013) Masamichi Ogasawara et al.   ORGANOMETALLICS

Palladium-catalyzed cleavage of the Me–Si bond in ortho-trimethylsilyl aryltriflates: synthesis of benzosilole derivatives from ortho-trimethylsilyl aryltriflates and alkynes

(2013) Tianhao Meng et al.   RSC Advances

A Highly Efficient Tandem Reaction of 2-(gem-Dibromovinyl)phenols(thiophenols) with Organosilanes to 2-Arylbenzofurans (thiophenes)

(2012) Jie Liu et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of Functionalized Benzo[b]thiophenes by the Intramolecular Copper-Catalyzed Carbomagnesiation of Alkynyl(aryl)thioethers

(2012) Thomas Kunz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Intermolecular Coupling of 2-Silylaryl Bromides with Alkynes: Synthesis of Benzosiloles and Heteroarene-Fused Siloles by Catalytic Cleavage of the C(sp3)Si Bond

(2012) Yun Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Addition of Arylzinc Reagents to Alkynes to Form ortho-Alkenylarylzinc Species through 1,4-Cobalt Migration

(2012) Boon-Hong Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Structure-Property Relationships of 2,2′-Bis(benzo[b]phosphole) and 2,2′-Benzo[b]phosphole-Benzo[b]heterole Hybrid π Systems

(2012) Yukiko Hayashi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electroluminescent and Photovoltaic Properties of Silole-Based Materials

(2012) Huiying Fu et al.   CURRENT ORGANIC CHEMISTRY

Rhodium-Catalyzed Carbon–Silicon Bond Activation for Synthesis of Benzosilole Derivatives

(2012) Masahiro Onoe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-catalysed intramolecular trans-bis-silylation of alkynes to synthesise 3-silyl-1-benzosiloles

(2012) Takanori Matsuda et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A highly efficient one-pot reaction of 2-(gem-dibromovinyl)phenols(thiophenols) with K4Fe(CN)6 to 2-cyanobenzofurans(thiophenes)

(2012) Wei Zhou et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

General and Practical One-Pot Synthesis of Dihydrobenzosiloles from Styrenes

(2012) Alexey Kuznetsov et al.   ORGANIC LETTERS

Construction of Benzosiloles, Six- and Eight-Membered Silacyclic Skeletons, via a Pd-Catalyzed Intramolecular Mizoroki–Heck Reaction of Vinylsilanes

(2012) Kunbing Ouyang et al.   ORGANIC LETTERS

Visible Light Photocatalytic Synthesis of Benzothiophenes

(2012) Durga Prasad Hari et al.   ORGANIC LETTERS

Thienoacene-Based Organic Semiconductors

(2011) Kazuo Takimiya et al.   ADVANCED MATERIALS

A highly efficient TBAF-promoted intramolecular cyclization of gem-dibromoolefins for the synthesis of 2-bromobenzofurans(thiophenes)

(2011) Wei Chen et al.   CHEMICAL COMMUNICATIONS

One-pot synthesis of benzofused heteroaryl azoles via tandem C-heteroatom coupling/C–H activation of azoles

(2011) Xurong Qin et al.   CHEMICAL COMMUNICATIONS

Gold-catalysed alkenyl- and arylsilylation reactions forming 1-silaindenes

(2011) Takanori Matsuda et al.   CHEMICAL COMMUNICATIONS

Iron-catalyzed aryl- and alkenyllithiation of alkynes and its application to benzosilole synthesis

(2011) Eiji Shirakawa et al.   CHEMICAL COMMUNICATIONS

Synthesis of Heterocycles via Electrophilic Cyclization of Alkynes Containing Heteroatom

(2011) Benhur Godoi et al.   CHEMICAL REVIEWS

Semiconducting π-Conjugated Systems in Field-Effect Transistors: A Material Odyssey of Organic Electronics

(2011) Chengliang Wang et al.   CHEMICAL REVIEWS

Update 1 of: Synthesis and Functionalization of Indoles Through Palladium-Catalyzed Reactions

(2011) Sandro Cacchi et al.   CHEMICAL REVIEWS

CuI/TMEDA-Catalyzed Annulation of 2-Bromo Alkynylbenzenes with Na2S: Synthesis of Benzo[b]thiophenes

(2011) Lei-Lei Sun et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Benzothiophene Derivatives by Pd-Catalyzed or Radical-Promoted Heterocyclodehydration of 1-(2-Mercaptophenyl)-2-yn-1-ols

(2011) Bartolo Gabriele et al.   JOURNAL OF ORGANIC CHEMISTRY

Linear- and Angular-Shaped Naphthodithiophenes: Selective Synthesis, Properties, and Application to Organic Field-Effect Transistors

(2011) Shoji Shinamura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Synthesis of Germoles via the Activation of Carbon–Germanium Bonds

(2011) Mamoru Tobisu et al.   ORGANIC LETTERS

Palladium-Catalyzed C–S Coupling: Access to Thioethers, Benzo[b]thiophenes, and Thieno[3,2-b]thiophenes

(2011) Marius Kuhn et al.   ORGANIC LETTERS

A Practical, One-Pot Synthesis of Highly Substituted Thiophenes and Benzo[b]thiophenes from Bromoenynes ando-Alkynylbromobenzenes

(2011) Verónica Guilarte et al.   ORGANIC LETTERS

Palladium-Catalyzed Domino C–S Coupling/Carbonylation Reactions: An Efficient Synthesis of 2-Carbonylbenzo[b]thiophene Derivatives

(2011) Fanlong Zeng et al.   ORGANIC LETTERS

Marine Indole Alkaloids: Potential New Drug Leads for the Control of Depression and Anxiety

(2010) Anna J. Kochanowska-Karamyan et al.   CHEMICAL REVIEWS

Copper-Catalyzed Thiolation Annulations of 1,4-Dihalides with Sulfides Leading to 2-Trifluoromethyl Benzothiophenes and Benzothiazoles

(2010) Chun-Lin Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium-Catalyzed AreneOrtho-Silylation by Formal Hydroxyl-Directed C−H Activation

(2010) Eric M. Simmons et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tandem free-radical addition/substitution chemistry and its application to the preparation of novel AT1receptor antagonists

(2010) Maree K. Staples et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

New development of synthesis and reactivity of seleno- and tellurophenes

(2010) Cristiano R. B. Rhoden et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper catalysis in the construction of indole and benzo[b]furan rings

(2010) Sandro Cacchi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Hydrosilylation-Metathesis Sequence Leading to 1-Silaindenes

(2010) Takanori Matsuda et al.   SYNLETT

Catalytic Functionalization of Indoles in a New Dimension

(2009) Marco Bandini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Synthesis of Benzothiophenes by an Unusual Palladium-Catalyzed Vinylic CS Coupling

(2009) Christopher S. Bryan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intramolecular cross-coupling of gem-dibromoolefins: a mild approach to 2-bromo benzofused heterocycles

(2009) Stephen G. Newman et al.   CHEMICAL COMMUNICATIONS

Benzo[b]phosphole-Containing π-Electron Systems: Synthesis Based on an Intramoleculartrans-Halophosphanylation and Some Insights into Their Properties

(2009) Aiko Fukazawa et al.   Chemistry-An Asian Journal

Ladder π-Conjugated Materials Containing Main-Group Elements

(2009) Aiko Fukazawa et al.   Chemistry-An Asian Journal

Platinum-Catalyzed Multisubstituted Benzo[b]selenophene Synthesis

(2009) Takuma Sato et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Benzo[b]phosphole sulfides. Highly electron-transporting and thermally stable molecular materials for organic semiconductor devices

(2009) Hayato Tsuji et al.   JOURNAL OF MATERIALS CHEMISTRY

Novel Route to 2,3-Substituted Benzo[b]thiophenes via Intramolecular Radical Cyclization⧧

(2009) Prabal P. Singh et al.   JOURNAL OF ORGANIC CHEMISTRY

Development of a Sila-Friedel−Crafts Reaction and Its Application to the Synthesis of Dibenzosilole Derivatives

(2009) Shunsuke Furukawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Coupling of 2-Silylphenylboronic Acids with Alkynes Leading to Benzosiloles: Catalytic Cleavage of the Carbon−Silicon Bond in Trialkylsilyl Groups

(2009) Mamoru Tobisu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Design and synthesis of phosphole-based π systems for novel organic materials

(2009) Yoshihiro Matano et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of Benzo[b]siloles via KH-Promoted Cyclization of (2-Alkynylphenyl)silanes

(2009) Laurean Ilies et al.   ORGANIC LETTERS

One-pot Synthesis of Benzo[b]thiophenes and Benzo[b]selenophenes fromo-Halo-Substituted Ethynylbenzenes: Convenient Approach to Mono-, Bis-, and Tris-Chalcogenophene-Annulated Benzenes

(2009) Tomoya Kashiki et al.   ORGANIC LETTERS

Phosphonium- and Borate-Bridged Zwitterionic Ladder Stilbene and Its Extended Analogues

(2008) Aiko Fukazawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-catalysed intramolecular trans-allylsilylation of alkynes forming 3-allyl-1-silaindenes

(2008) Takanori Matsuda et al.   CHEMICAL COMMUNICATIONS

Palladium-catalysed direct synthesis of benzo[b]thiophenes from thioenols

(2008) Kiyofumi Inamoto et al.   CHEMICAL COMMUNICATIONS

Modular Synthesis of Functionalized Benzosiloles by Tin-Mediated Cyclization of (o-Alkynylphenyl)silane

(2008) Laurean Ilies et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Base-Mediated Cyclization Reaction of 2-Alkynylphenylphosphine Oxides: Synthesis and Photophysical Properties of Benzo[b]phosphole Oxides

(2008) Takanobu Sanji et al.   ORGANIC LETTERS

Modular Synthesis of Benzo[b]phosphole Derivatives via BuLi-Mediated Cyclization of (o-Alkynylphenyl)phosphine

(2008) Hayato Tsuji et al.   ORGANIC LETTERS