Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 14, Issue 23, Pages 5293-5297Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob00912c
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Funding
- China NSFC [21272047, 21372055, 21472030]
- SKLUWRE [2015DX01]
- Fundamental Research Funds for the Central Universities [HIT.BRETIV.201310]
- HLJNSF [B201406]
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A metal-free and cost-effective protocol for UV light-mediated difunctionalization of alkenes with CF3SO2Na was developed. This strategy realized the direct formation of Csp(3)-CF3 and C-C bonds through a proposed tandem radical cyclization process, which produced a variety of phenanthrene and anthrone derivatives in moderate yields.
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