The Diaza[5.5.6.6]fenestrane Skeleton-Synthesis of Leuconoxine Alkaloids

Biomimetic Total Synthesis of Santalin Y

(2015) Sebastian Strych et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Photoinduced Cyclization Cascade-Total Synthesis of (−)-Leuconoxine

(2015) Magnus Pfaffenbach et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Flexible Route to Indole Scaffolds - Formal Synthesis of (±)-Mersicarpine

(2015) Magnus Pfaffenbach et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Total synthesis of (−)-rhazinilam using 1,3-dipolar cycloaddition of optically active münchnone intermediate

(2015) Kenji Sugimoto et al.   TETRAHEDRON

Formal total synthesis of (±)-rhazinal and its B-ring carbamate analogue

(2015) Munnuri Sailu et al.   TETRAHEDRON

Synthesis of rhazinilam through intramolecular arylcyanation of alkenes catalyzed cooperatively by nickel/aluminum

(2015) Yuuya Yamada et al.   TETRAHEDRON

Selective syntheses of leuconolam, leuconoxine, and mersicarpine alkaloids from a common intermediate through regiocontrolled cyclizations by Staudinger reactions

(2015) Zining Li et al.   Organic Chemistry Frontiers

Phosphoric Acid Catalyzed Desymmetrization of Bicyclic Bislactones Bearing an All-Carbon Stereogenic Center: Total Syntheses of (−)-Rhazinilam and (−)-Leucomidine B

(2014) Jean-Baptiste Gualtierotti et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transformations of the 2,7-Seco Aspidosperma Alkaloid Leuconolam, Structure Revision of epi-Leuconolam, and Partial Syntheses of Leuconoxine and Leuconodines A and F

(2014) Yun-Yee Low et al.   JOURNAL OF NATURAL PRODUCTS

Total Synthesis of Mersicarpine through a Cationic Cyclization Approach

(2014) Zhe Lv et al.   ORGANIC LETTERS

Asymmetric Total Synthesis of (−)-Leuconoxine via Chiral Phosphoric Acid Catalyzed Desymmetrization of a Prochiral Diester

(2014) Kazuhiro Higuchi et al.   ORGANIC LETTERS

Solvent-Controlled Switchable C–H Alkenylation of 4-Aryl-1H-pyrrole-3-carboxylates: Application to the Total Synthesis of (±)-Rhazinilam

(2014) Youla Su et al.   ORGANIC LETTERS

Biosynthetically Inspired Divergent Approach to Monoterpene Indole Alkaloids: Total Synthesis of Mersicarpine, Leuconodines B and D, Leuconoxine, Melodinine E, Leuconolam, and Rhazinilam

(2014) Yang Yang et al.   ORGANIC LETTERS

Total Syntheses of Leuconoxine, Leuconodine B, and Melodinine E by Oxidative Cyclic Aminal Formation and Diastereoselective Ring-Closing Metathesis

(2014) Atsushi Umehara et al.   ORGANIC LETTERS

Corynanthean, eburnan, secoleuconoxine, and pauciflorine alkaloids from Kopsia pauciflora

(2014) Chew-Yan Gan et al.   PHYTOCHEMISTRY

The Witkop Cyclization: A Photoinduced CH Activation of the Indole System

(2013) Philipp J. Gritsch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fenestranes in Synthesis: Unique and Highly Inspiring Scaffolds

(2013) Aicha Boudhar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Protecting-Group-Free Total Synthesis of (−)-Rhazinilam and (−)-Rhazinicine using a Gold-Catalyzed Cascade Cyclization

(2013) Kenji Sugimoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantiocontrolled Total Synthesis of (−)-Mersicarpine

(2013) Yusuke Iwama et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhazinilam–Leuconolam–Leuconoxine Alkaloids from Leuconotis griffithii

(2013) Chew-Yan Gan et al.   JOURNAL OF NATURAL PRODUCTS

Enantioselective Total Syntheses of Leuconolam–Leuconoxine–Mersicarpine Group Monoterpene Indole Alkaloids

(2013) Zhengren Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Chemoselective Catellani Ortho-Arylation of Iodopyrroles: Rapid Total Synthesis of Rhazinal

(2013) Xianwei Sui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple indole alkaloids and those with a non-rearranged monoterpenoid unit

(2013) Minoru Ishikura et al.   NATURAL PRODUCT REPORTS

Total synthesis of (±)-leuconolam: intramolecular allylic silane addition to a maleimide carbonyl group

(2013) Enver Cagri Izgu et al.   Chemical Science

Chemical Synthesis of Aspidosperma Alkaloids Inspired by the Reverse of the Biosynthesis of the Rhazinilam Family of Natural Products

(2012) Lindsay McMurray et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective Inter- and Intramolecular Formal [4+2] Cycloaddition of Cyclobutanones with Indoles and Total Synthesis of (±)-Aspidospermidine

(2012) Mizuki Kawano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Al-Catalyzed Facile Construction of Quaternary CC Bonds by the Allylic Substitution of Tertiary Alcohols: A Concise and Formal Synthesis of (±)-Mersicarpine

(2012) Xue Zhong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pd(II)-Catalyzed Regioselective 2-Alkylation of Indoles via a Norbornene-Mediated C–H Activation: Mechanism and Applications

(2012) Lei Jiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Concise Total Synthesis of (−)-Mersicarpine

(2012) Yusuke Iwama et al.   ORGANIC LETTERS

Model studies toward a synthesis of asperaculin A: exploration of iterative intramolecular Pauson–Khand reaction based strategies to access the dioxa[5.5.5.6]fenestrane framework

(2012) Goverdhan Mehta et al.   TETRAHEDRON LETTERS

Asperaculin A, a Sesquiterpenoid from a Marine-Derived Fungus,Aspergillus aculeatus

(2011) Nattha Ingavat et al.   JOURNAL OF NATURAL PRODUCTS

Collective synthesis of natural products by means of organocascade catalysis

(2011) Spencer B. Jones et al.   NATURE

Catalytic Selective Cyclizations of Aminocyclopropanes: Formal Synthesis of Aspidospermidine and Total Synthesis of Goniomitine

(2010) Filippo De Simone et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of (−)-Mersicarpine

(2010) Rie Nakajima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Halogenated Indole Alkaloids from Marine Invertebrates

(2010) Patrícia Mendonça Pauletti et al.   Marine Drugs

Simple indole alkaloids and those with a nonrearranged monoterpenoid unit

(2010) Minoru Ishikura et al.   NATURAL PRODUCT REPORTS

Synthesis of (±)-desethylrhazinal using a tandem radical addition-cyclization process

(2010) Ehecatl Paleo et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Total Synthesis of Rhazinilam: Axial to Point Chirality Transfer in an Enantiospecific Pd-Catalyzed Transannular Cyclization

(2010) Zhenhua Gu et al.   ORGANIC LETTERS

Demonstration of microtubule-like structures formed with (−)-rhazinilam from purified tubulin outside of cells and a simple tubulin-based assay for evaluation of analog activity

(2009) Michael C. Edler et al.   ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS

Melodinines A−G, Monoterpenoid Indole Alkaloids fromMelodinus henryi

(2009) Tao Feng et al.   JOURNAL OF NATURAL PRODUCTS

Total Synthesis of (±)-Rhazinal Using Novel Palladium-Catalyzed Cyclizations

(2009) Alfred L. Bowie et al.   JOURNAL OF ORGANIC CHEMISTRY

Total Synthesis of (−)-Penifulvin A, an Insecticide with a Dioxafenestrane Skeleton

(2009) Tanja Gaich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Flexible, Convergent Approach to Polycyclic Indole Structures: Formal Synthesis of (±)-Mersicarpine

(2009) Aurélien Biechy et al.   ORGANIC LETTERS

From Silphinenes to Penifulvins: A Biomimetic Approach to Penifulvins B and C

(2009) Tanja Gaich et al.   ORGANIC LETTERS

Monoterpenoid Indole Alkaloids from the Bark ofAlstonia scholaris

(2009) Tao Feng et al.   PLANTA MEDICA

Total Synthesis of (±)-Mersicarpine

(2008) Jakob Magolan et al.   ORGANIC LETTERS