How and Why Does Ni0Promote Smooth Etheric CO Bond Cleavage and CC Bond Formation? A Theoretical Study

Exploration of Earth-Abundant Transition Metals (Fe, Co, and Ni) as Catalysts in Unreactive Chemical Bond Activations

(2015) Bo Su et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cross-Couplings Using Aryl Ethers via C–O Bond Activation Enabled by Nickel Catalysts

(2015) Mamoru Tobisu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Nickel catalyzed dealkoxylative Csp2–Csp3 cross coupling reactions – stereospecific synthesis of allylsilanes from enol ethers

(2015) Lin Guo et al.   CHEMICAL COMMUNICATIONS

Nickel-Catalyzed Alkynylation of Anisoles via C–O Bond Cleavage

(2015) Mamoru Tobisu et al.   ORGANIC LETTERS

Bite-angle bending as a key for understanding group-10 metal reactivity of d10-[M(NHC)2] complexes with sterically modest NHC ligands

(2015) Florian Hering et al.   Chemical Science

Synthesis of Annelated Phospholes through Intramolecular CH Activation by Monovalent Phosphorus

(2014) Xinda Wei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Catalyzed Dealkoxylative CarylC sp 3 Cross-Coupling-Replacement of Aromatic Methoxy Groups of Aryl Ethers by Employing a Functionalized Nucleophile

(2014) Matthias Leiendecker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-catalyzed activation of ethers via C–O bond cleavage: a new strategy for molecular diversity

(2014) Josep Cornella et al.   CHEMICAL SOCIETY REVIEWS

Mechanistic Study of Chemoselectivity in Ni-Catalyzed Coupling Reactions between Azoles and Aryl Carboxylates

(2014) Qianqian Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Beyond Directed ortho Metalation: Ru-Catalyzed CAr–O Activation/Cross-Coupling Reaction by Amide Chelation

(2014) Yigang Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Key Mechanistic Features of Ni-Catalyzed C–H/C–O Biaryl Coupling of Azoles and Naphthalen-2-yl Pivalates

(2014) Huiying Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanisms and Origins of Switchable Chemoselectivity of Ni-Catalyzed C(aryl)–O and C(acyl)–O Activation of Aryl Esters with Phosphine Ligands

(2014) Xin Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

1,3-Dicyclohexylimidazol-2-ylidene as a Superior Ligand for the Nickel-Catalyzed Cross-Couplings of Aryl and Benzyl Methyl Ethers with Organoboron Reagents

(2014) Mamoru Tobisu et al.   ORGANIC LETTERS

An efficient cleavage of the aryl ether C–O bond in supercritical carbon dioxide–water

(2013) Maya Chatterjee et al.   CHEMICAL COMMUNICATIONS

Demetalation of Metal Porphyrins via Magnesium Porphyrins by Reaction with Grignard Reagents

(2013) Kei Murakami et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanism of Palladium-Catalyzed Suzuki-Miyaura Reactions: Multiple and Antagonistic Roles of Anionic “Bases” and Their Countercations

(2013) Christian Amatore et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanism of Alkoxy Groups Substitution by Grignard Reagents on Aromatic Rings and Experimental Verification of Theoretical Predictions of Anomalous Reactions

(2013) Gonzalo Jiménez-Osés et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combined Experimental and Theoretical Study on the Reductive Cleavage of Inert C–O Bonds with Silanes: Ruling out a Classical Ni(0)/Ni(II) Catalytic Couple and Evidence for Ni(I) Intermediates

(2013) Josep Cornella et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Programmed Selective sp2 C–O Bond Activation toward Multiarylated Benzenes

(2013) Fei Zhao et al.   ORGANIC LETTERS

Ni-Catalyzed Stereoselective Arylation of Inert C–O bonds at Low Temperatures

(2013) Josep Cornella et al.   ORGANIC LETTERS

Systematic exploration of the mechanism of chemical reactions: the global reaction route mapping (GRRM) strategy using the ADDF and AFIR methods

(2013) Satoshi Maeda et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Asymmetric transition metal-catalyzed cross-coupling reactions for the construction of tertiary stereocenters

(2013) Elizabeth C. Swift et al.   TETRAHEDRON

Aryl Ether as a Negishi Coupling Partner: An Approach for Constructing CC Bonds under Mild Conditions

(2012) Chao Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel-Mediated Hydrogenolysis of C–O Bonds of Aryl Ethers: What Is the Source of the Hydrogen?

(2012) Paul Kelley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kumada–Tamao–Corriu Coupling of Heteroaromatic Chlorides and Aryl Ethers Catalyzed by (IPr)Ni(allyl)Cl

(2012) María José Iglesias et al.   ORGANIC LETTERS

Ni(0)/NHC-catalyzed amination of N-heteroaryl methyl ethers through the cleavage of carbon‒oxygen bonds

(2012) Mamoru Tobisu et al.   TETRAHEDRON

Nickel-catalyzed reductive cleavage of aryl–oxygen bonds in alkoxy- and pivaloxyarenes using hydrosilanes as a mild reducing agent

(2011) Mamoru Tobisu et al.   CHEMICAL COMMUNICATIONS

Cross-coupling of Aryl/Alkenyl Silyl Ethers with Grignard Reagents through Nickel-catalyzed C–O Bond Activation

(2011) Fei Zhao et al.   CHEMISTRY LETTERS

Cross-Coupling of Aryl/Alkenyl Ethers with Aryl Grignard Reagents through Nickel-Catalyzed CO Activation

(2011) Lan-Gui Xie et al.   CHEMISTRY-A EUROPEAN JOURNAL

Density Functional Theory Study of the Mechanism and Origins of Stereoselectivity in the Asymmetric Simmons–Smith Cyclopropanation with Charette Chiral Dioxaborolane Ligand

(2011) Tao Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Density Functional Theory Study of the Mechanism and Origins of Stereoselectivity in the Asymmetric Simmons–Smith Cyclopropanation with Charette Chiral Dioxaborolane Ligand

(2011) Tao Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Suzuki−Miyaura Cross-Coupling of Aryl Carbamates and Sulfamates: Experimental and Computational Studies

(2011) Kyle W. Quasdorf et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective, Nickel-Catalyzed Hydrogenolysis of Aryl Ethers

(2011) A. G. Sergeev et al.   SCIENCE

Direct Application of Phenolic Salts to Nickel-Catalyzed Cross-Coupling Reactions with Aryl Grignard Reagents

(2010) Da-Gang Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Cross-Couplings Involving Carbon−Oxygen Bonds

(2010) Brad M. Rosen et al.   CHEMICAL REVIEWS

Ni-Catalyzed Reduction of Inert C−O Bonds: A New Strategy for Using Aryl Ethers as Easily Removable Directing Groups

(2010) Paula Álvarez-Bercedo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The activation strain model of chemical reactivity

(2010) Willem-Jan van Zeist et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Carbon−Hydrogen Bond Oxidative Addition of Partially Fluorinated Aromatics to a Ni(PiPr3)2Synthon: The Influence of Steric Bulk on the Thermodynamics and Kinetics of C−H Bond Activation

(2010) Jillian A. Hatnean et al.   ORGANOMETALLICS

Hydroxyphosphine Ligand for Nickel-Catalyzed Cross-Coupling through Nickel/Magnesium Bimetallic Cooperation

(2009) Naohiko Yoshikai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Ni-Catalyzed Selective C−O Bond Activation in Cross-Coupling of Aryl Esters

(2009) Zhe Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Biaryl Cross-Coupling Reactions between Aryl Halides and Aryl Grignard Reagents: A New Catalyst Combination ofN-Heterocyclic Carbenes and Iron, Cobalt, and Nickel Fluorides

(2009) Takuji Hatakeyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Cross-Coupling Reaction of Alkenyl Methyl Ethers with Aryl Boronic Esters

(2009) Toshiaki Shimasaki et al.   ORGANIC LETTERS

Cross-Coupling Reaction of Alkyl Halides with Grignard Reagents Catalyzed by Ni, Pd, or Cu Complexes with π-Carbon Ligand(s)

(2008) Jun Terao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Nickel-Catalyzed Cross-Coupling of Aryl Methyl Ethers with Aryl Boronic Esters

(2008) Mamoru Tobisu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Methylation of arenes via Ni-catalyzed aryl C–O/F activation

(2008) Bing-Tao Guan et al.   CHEMICAL COMMUNICATIONS

Ligand Exchange as the First Irreversible Step in the Nickel-Catalyzed Cross-Coupling Reaction of Grignard Reagents

(2008) Naohiko Yoshikai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation, Structure, and Reactivity of Nonstabilized Organoiron Compounds. Implications for Iron-Catalyzed Cross Coupling Reactions

(2008) Alois Fürstner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Cheap Metal for a “Noble” Task:  Preparative and Mechanistic Aspects of Cycloisomerization and Cycloaddition Reactions Catalyzed by Low-Valent Iron Complexes

(2008) Alois Fürstner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental and Theoretical Examination of C−CN Bond Activation of Benzonitrile Using Zerovalent Nickel

(2008) Tülay A. Ateşin et al.   ORGANOMETALLICS