4.6 Article

Structural properties and visible emission of Eu3+-activated SiO2-ZnO-TiO2 powders prepared by a soft chemical process

Journal

OPTICAL MATERIALS
Volume 62, Issue -, Pages 438-446

Publisher

ELSEVIER
DOI: 10.1016/j.optmat.2016.10.032

Keywords

Europium ion; Photoluminescence; SiO2-ZnO-TiO2 system; Powder; Soft chemical process

Funding

  1. CNPq
  2. CAPES
  3. FAPEG
  4. FAPESP
  5. IFG
  6. FUNAPE

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In this work, the structural and optical properties of the 60SiO(2)-20ZnO-20TiO(2) system (in mol%) doped with 1 mol% of Eu3+ were evaluated. Stable and transparent sols, homogeneous gels, and powders were prepared by a soft chemical process followed by annealing from 700 to 1100 degrees C. Visible emission was observed in the photoluminescence (PL) spectra from 570 to 700 nm owing to the Eu3+ ions, with the most intense emission peaks at 614 and 590 nm related to the D-5(0) -> F-7(2) and D-5(0) -> F-7(1) transitions, corresponding to red (R) and orange (O) colors, respectively. The R/O intensity ratios between 3.16 and 3.73 were observed and correlated to the structural properties of the host. X-ray diffraction patterns indicated that the reduction of PL at 614 nm and changes in the R/O values were due to the crystallization process. In addition, the FTIR spectra showed a gradual decrease of the hydroxyl absorption bands around 3436 and 1640 cm(-1) and an increase of the bands related to Ti-O-Ti and Si-O-Si linkages, indicating polymerization and densification process of the host was achieved above 700 degrees C. Moreover, increasing the annealing temperature resulted in the formation of ZnTiO3 and Zn2TiO4 crystalline phases, as well as rutile TiO2. Finally, intensity parameters (Omega(lambda)), and quantum efficiency were calculated by applying Judd-Ofelt theory to Eu3+ ions, which showed that the Eu3+-doped samples can be used in displays and LEDs. (C) 2016 Elsevier B.V. All rights reserved.

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