4.6 Article

Mesoscopic virial equation for nonequilibrium statistical mechanics

Journal

NEW JOURNAL OF PHYSICS
Volume 18, Issue -, Pages -

Publisher

IOP Publishing Ltd
DOI: 10.1088/1367-2630/18/9/093043

Keywords

nonequilibrium statistical mechanics; equations of state; virial theorem; Langevin dynamics

Funding

  1. Deutsche Forschungsgemeinschaft (DFG) [SPP 1726/1]

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We derive a class of mesoscopic virial equations governing energy partition between conjugate position and momentum variables of individual degrees of freedom. They are shown to apply to a wide range of nonequilibrium steady states with stochastic (Langevin) and deterministic (Nose-Hoover) dynamics, and to extend to collective modes for models of heat-conducting lattices. A macroscopic virial theorem ensues upon summation over all degrees of freedom. It allows for the derivation of generalised (nonequilibrium) equations of state that involve average dissipative heat flows besides genuine state variables, as exemplified for inertial Brownian motion with solid friction and overdamped active Brownian particles subject to inhomogeneous pressure.

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