Article
Biochemistry & Molecular Biology
Abhishek Udnoor, Manjunath Lokolkar, Basappa C. Yallur, Raju Kale, Muttanagoud N. Kalasad, Umesha Katrahalli, Devagondanahalli H. Manjunatha
Summary: Inducing bio-functionalization in noble metal nanoparticles is crucial for their biocompatibility in biological activities. In this study, ZnO/Ag nanoparticles were synthesized and their interaction with bovine serum albumin was evaluated. The results showed that ZnO/Ag nanoparticles significantly reduced the intrinsic fluorescence intensity of bovine serum albumin and induced conformational modifications.
JOURNAL OF BIOMOLECULAR STRUCTURE & DYNAMICS
(2023)
Article
Biochemistry & Molecular Biology
Hamid Dezhampanah, Asadollah Mohammadi, Amineh Mousazadeh Moghaddam Pour
Summary: This study used spectroscopic techniques and molecular docking to investigate the interaction mechanisms between bovine serum albumin (BSA) and two newly synthesized azo dyes. The results showed that the dyes formed complexes with BSA, leading to quenching of fluorescence emission. UV-Vis spectroscopy confirmed conformational and micro environmental changes of BSA upon complex formation. Thermodynamic calculations indicated spontaneous binding of the dyes to BSA, with van der Waals force and hydrogen bonding playing a major role in the process. Molecular docking studies revealed the probable binding site of the dyes on subdomain IB of BSA through hydrophobic interaction and hydrogen bond. Additionally, the dyes induced conformational changes in BSA, altering its biological functions.
JOURNAL OF BIOMOLECULAR STRUCTURE & DYNAMICS
(2023)
Article
Biochemistry & Molecular Biology
Kaushik Kuche, Vivek Yadav, M. Dharshini, Rohan Ghadi, Dasharath Chaudhari, Tushar Date, Sanyog Jain
Summary: This study investigates the synergistic effect of sorafenib and simvastatin in triggering ferroptosis for cancer therapy. The researchers developed bovine serum albumin nanoparticles loaded with both drugs and observed a significant reduction in tumor volume in in-vivo experiments. The study highlights the potential of this drug delivery system for inducing ferroptosis and improving therapeutic efficacy.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Chemistry, Physical
U. S. Kanchana, Thomas V. Mathew
Summary: This study successfully surface functionalized ZnO nanoparticles using BSA as a biocompatible system and conducted various characterizations. The antimicrobial resistance of the functionalized ZnO NP product and its cytotoxicity against Dalton's lymphoma ascites (DLA) cell lines were also investigated.
SURFACES AND INTERFACES
(2021)
Article
Engineering, Electrical & Electronic
Limei Xue, Ermiao Liang, Jiwen Wang
Summary: The magnetic recoverable ZnO/ZnFe2O4/diatomite (ZZFDT) composite was synthesized by hydrothermal-precipitation method. The ZZFDT-1 exhibited excellent photocatalytic activity and magnetic properties, and can be easily separated from the solution. Additionally, ZZFDT-1 has a specific mesoporous structure and visible light response.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2022)
Article
Chemistry, Applied
Mingmin Zhang, Robin A. Hutchinson
Summary: Three process variations were developed to synthesize dextran-bovine serum albumin (BSA) model conjugate through the Maillard reaction and a Schiff base-Amadori solid phase rearrangement mechanism. The purified conjugate solution was further heated to form nanogels with a hydrodynamic diameter of 195-400 nm.
CARBOHYDRATE POLYMERS
(2022)
Article
Engineering, Environmental
Sanam Ayatollahi, Ehsan Karimi, Masoud Homayouni Tabrizi
Summary: In this study, bovine serum albumin and zinc oxide nanoparticles were used as a model system to improve the solubility and absorption of the nanoparticles. By loading disogenin and attaching folate to the nanoparticles, they showed selective toxicity against cancer cells and activated the intrinsic apoptotic pathway. The results confirmed the effectiveness of these nanoparticles in increasing the bioavailability and anti-cancer effects of bioactive compounds.
JOURNAL OF POLYMERS AND THE ENVIRONMENT
(2022)
Article
Environmental Sciences
Yiming Fang, Hiroshi Sakai
Summary: UV-activated persulfate showed more efficient treatment of humic substances compared to hydrogen peroxide and direct irradiation, with treatment effectiveness depending on persulfate concentrations and UV wavelengths. Lower molecular weight components were more susceptible to degradation, eventually leading to effective removal of humic substances.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2022)
Review
Biochemistry & Molecular Biology
Xinhao Xu, Jinyu Hu, Huaqian Xue, Yingying Hu, Ya-nan Liu, Guanyang Lin, Liangle Liu, Ren-ai Xu
Summary: This paper reviews the applications of human and bovine serum albumin in biomedical engineering, including their structural differences, extraction methods, characteristics, functions, applications, and future research directions.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Chemistry, Physical
Mykola Seredych, Kathleen Maleski, Tyler S. S. Mathis, Yury Gogotsi
Summary: This study reports on the formation of stable colloidal solutions of MXene nanosheets using a dispersing and electrostatic exfoliation method in the presence of albumin. The albumin-coated MXenes showed good stability and can find applications in various fields due to the significant role of protein adsorption onto nanomaterial surfaces.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
Article
Food Science & Technology
Lei Xu, Hu Hou, Brian Farkas, Kevin M. Keener, Allen L. Garner, Bernard Tao
Summary: This study investigated the effects of high voltage atmospheric cold plasma on bovine serum albumin, leading to structural alterations, protein precipitation, and peptide bond cleavage. The findings suggest that interactions between HVACP-induced reactive species and proteins can introduce significant changes to protein structure and composition in aqueous conditions.
LWT-FOOD SCIENCE AND TECHNOLOGY
(2021)
Article
Environmental Sciences
Yanan Ma, Zhaoyang Wang, Junfeng Li, Bo Song, Shenglin Liu
Summary: The electrochemical-assisted ultraviolet light coupled peroxodisulfate system (E-UV-PDS) was used to degrade ciprofloxacin (CIP). The study found that electrolysis and ultraviolet photolysis had synergistic effects, and explored the effects of initial pH, voltage, peroxodisulfate dosage, CIP concentration, and coexisting anions on the degradation process. The results showed that CIP could be efficiently degraded under certain conditions, and intermediate products were identified and degradation pathways were speculated using LCMS.
Article
Materials Science, Multidisciplinary
Debapriya Pradhan, Ermelinda Falletta, Suresh Kumar Dash
Summary: A solar light driven photo degradation approach using Co3O4 and Cr-Co3O4 spinel nanoparticles was studied for the degradation of methylene blue (MB) and malachite green (MG) dyes. The effect of Cr doping on the catalytic activity was investigated, showing that Cr doping enhanced the photocatalytic performance. The increase in performance was attributed to the increased separation of electron-hole pairs and the decreased band gap energy. The degradation kinetics followed a pseudo-first-order mode, and the photocatalysts showed good stability and high performance even after multiple recycles.
Article
Materials Science, Multidisciplinary
Amin Imani, Mohammadali Shahsavari, R. K. Singh Raman, Edouard Asselin
Summary: The study investigates the effects of albumins from bovine and chicken egg sources on the biodegradation of commercially pure Mg in a saline environment. It reveals that albumins from different sources have varying influences on the degradation behavior of Mg, emphasizing the importance of considering the source of albumin for in vitro assessment of Mg-based biomaterials.
Article
Environmental Sciences
B. Janani, Lija L. Raju, Ajith M. Thomas, Mohammed Nasser Alyemeni, Gani Asa Dudin, Leonard Wijaya, Abdulaziz Abdullah Alsahli, Parvaiz Ahmad, S. Sudheer Khan
Summary: The toxic effect of zinc oxide nanoparticles (ZnO NPs) in the presence and absence of bovine serum albumin (BSA) was analyzed, with BSA reducing the toxicity of ZnO NPs. Different environmental models were studied to compare the toxicity of bare ZnO and BSA-coated ZnO. The study suggests that BSA-stabilized ZnO NPs could have more potential applications in biotechnology and bioengineering.
Article
Dentistry, Oral Surgery & Medicine
Lingxiao Wang, Chao Liang, Xiao Lin, Changying Liu, Jun Li
Summary: This study elucidated the role of miR-491-5p in osteogenic differentiation, particularly in patients with type 2 diabetes. The downregulation of miR-491-5p was found to be a major factor contributing to decreased osteogenic differentiation. Regulation of miR-491-5p expression has the potential to improve osteogenic differentiation in patients with type 2 diabetes.
Article
Materials Science, Multidisciplinary
Yaqing Wei, Jun He, Jie Zhang, Mingyang Ou, Yanpeng Guo, Jiajun Chen, Cheng Zeng, Jia Xu, Jiantao Han, Tianyou Zhai, Huiqiao Li
Summary: This study proposes a seamless integration strategy by merging the voltage and capacity of phosphorus and antimony into a solid solution alloy. Experimental results show that this alloy exhibits superior cycle stability, rate performance, and even delivers high capacity at low temperature.
ENERGY & ENVIRONMENTAL MATERIALS
(2023)
Review
Plant Sciences
Wei Li, Jinyu He, Xiuzhuo Wang, Matthew Ashline, Zirui Wu, Fengquan Liu, Zheng Qing Fu, Ming Chang
Summary: PBS3 is an acyl acid amido synthetase that plays a critical role in the biosynthesis of salicylic acid in Arabidopsis. It acts as a positive regulator of plant immunity and is involved in stress responses and plant development.
Article
Chemistry, Multidisciplinary
Hao Yan, Qian Wang, Jingyun Wang, Wenting Shang, Zhiyuan Xiong, Lingyun Zhao, Xiaodan Sun, Jie Tian, Feiyu Kang, Seok-Hyun Yun
Summary: By using a bottom-up molecular approach, graphene quantum dots (GQDs) can be planted in the poly(ethylene glycol) (PEG) layer of PEGylated nanoparticles to form NPs-GQDs-PEG nanocomposite, allowing for sustainable and multimodality tumor bioimaging in vivo. The planted GQDs show prolonged blood circulation and increased tumor accumulation compared to typical GQDs, and also enable long-term real-time visualization of the local pharmacokinetics of nanoparticles in vivo.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Physical
Kaihang Sun, Chenyang Shen, Rui Zou, Chang -jun Liu
Summary: This study demonstrates high activity and enhanced CO tolerance for CO2 hydrogenation to methanol on Pt/In2O3-ZrO2 catalyst. The addition of ZrO2 enables stronger electron transfer between Pt and In2O3-ZrO2, leading to weaker CO adsorption and improved CO tolerance of Pt catalyst. The ZrO2-modified oxygen vacancy promotes CO2 activation.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Biodiversity Conservation
Peng Chen, Biao Wang, Yanlan Wu, Qijun Wang, Zuoji Huang, Chunlin Wang
Summary: This study proposed a multi-source remote sensing water quality inversion method based on a small number of samples, which solved the problem of scale inconsistency among multi-source remote sensing data and achieved large-scale and efficient inversion of urban river water quality.
ECOLOGICAL INDICATORS
(2023)
Article
Engineering, Electrical & Electronic
Xu Gao, Ke Yang, Yi-xuan Zhu, Jun-qi Liu, Shen-qiang Zhai, Shu-man Liu, Ning Zhuo, Jin-chuan Zhang, Li-jun Wang, Feng-qi Liu, Xiao-hua Wang, Zhi-peng Wei
Summary: The authors demonstrate a high-speed 8.5-μm quantum cascade laser (QCL) that operates continuously at room temperature. A maximum output power of 141 mW is achieved at 20 degrees C. By monolithically integrating a pi-shaped metal contact electrode, the parasitic capacitance of the device is reduced from 36.6 to 7.1 pF, resulting in an increased -3 dB RF modulation bandwidth from 870 MHz to 4.5 GHz compared to the conventional electrode configuration.
ELECTRONICS LETTERS
(2023)
Article
Agriculture, Multidisciplinary
Guoqing Wu, Jingxuan Xu, Qiyao Wang, Ziyang Fang, Yucheng Fang, Yujie Jiang, Xiaohong Zhang, Xiangrong Cheng, Jin Sun, Guowei Le
Summary: Dietary methionine restriction (MR) has various health-promoting effects, including the prevention of chronic diseases and cancer, as well as extension of lifespan. Recent studies have provided new insights into the mechanisms and phenotypes of MR, particularly in areas such as angiogenesis, neurodegenerative diseases, intestinal microbiota, and intestinal barrier function. This review comprehensively summarizes the novel roles and interpretations of the mechanisms underlying MR in the prevention of chronic diseases and aging.
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
(2023)
Article
Chemistry, Physical
Guanghui Yang, Jiyeon Kang, Amanda Carsbring, Wangzhong Mu, Peter Hedstrom, Jin-Kyung Kim, Joo Hyun Park
Summary: The precipitation of Cr-rich BCC particles was found to be dependent on the chemical composition of Fe-Cr-Ni medium entropy alloys. These particles played a significant role in the hardening of the alloys. The different precipitation behaviors at two temperatures resulted in variations in grain size distribution and hardness.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Microbiology
Yibei Zhang, Yuping Huang, Haoyuan Ding, Jiabao Ma, Xinyu Tong, Yuanxing Zhang, Zhen Tao, Qiyao Wang
Summary: This study revealed the important role of RpoE in controlling the infection process of P. plecoglossicida. Through temperature sensing, RpoE regulates gene expression related to bacterial signal transduction, membrane homeostasis, energy metabolism, and virulence.
MICROBIOLOGICAL RESEARCH
(2023)
Article
Mycology
Qiqi Wang, Wei Chen, Zhe Wan, Wei Liu
Summary: An outbreak of tinea capitis caused by Trichophyton tonsurans was reported among five juvenile athletes in a wrestling team in Beijing, China. The fungal pathogens were identified as T. tonsurans by morphology and sequencing. Multilocus genotyping analysis revealed a single genotype among the five isolates. Antifungal susceptibility testing showed that these isolates were susceptible to common antifungal drugs for treating tinea capitis.
Article
Virology
Zhenhe Xu, Zihan Ding, Yuanxing Zhang, Xiaohong Liu, Qiyao Wang, Shuai Shao, Qin Liu
Summary: Phage therapy is a potential alternative to antibiotics for bacterial infections. This study found that storing phages at 4 degrees C was optimal and that 10% dimethyl sulfoxide (DMSO) was more effective in protecting the phages at lower temperatures than glycerin. Additionally, the use of hydroxyapatite and a combination of trehalose with tryptic soy broth or skim milk powder alleviated phage inactivation during storage. Furthermore, a model for predicting phage shelf-life was established with high accuracy using the Accelerated Stability Assessment Program (ASAP) based on the Arrhenius equation.
Article
Crystallography
Kai Gao, Su-E. Zha, Chang-Ying Liu, Qiao-Juan Wang, Er-Qiang Wang
Summary: This paragraph describes the crystal structure parameters and cell parameters of a compound.
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES
(2023)
Article
Environmental Studies
Meng-tao Chen, Da-peng Yang, Wei-qi Zhang, Qi-jun Wang
Summary: This research investigates the impact of ESG performance on stock liquidity in Chinese stock market. The study finds that strong ESG disclosure enhances stock liquidity and functions as a positive signal to build firm reputation. However, the effect of ESG disclosure on stock liquidity is not significant for most service sector firms, while non-SOEs and firms in Midwest benefit more.
ENVIRONMENTAL IMPACT ASSESSMENT REVIEW
(2023)
Article
Linguistics
Olga Tararova, Martha Black, Qiyao Wang, Katrina Blong
Summary: This study investigates the acquisition of Spanish gender agreement by Russian or Mandarin speakers of English, and compares the results with English speakers of Spanish. The results suggest that beginner learners are influenced by the grammatical gender system of their L1s when identifying gender in Spanish.
Article
Chemistry, Multidisciplinary
Zihan Ma, Lishuang Wang, Tingting Chen, Guangning Wang
Summary: In this study, two kinds of 3D self-doped (N/O) lilac-based and coriander-based porous carbons with high performance have been prepared.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Qin Wang, Yun-Fan Yan, Jiao-Lin Weng, Ying Huang, Fu Yang, Hao-Hui Xie, Fei Tan, Fa-Kun Zheng, Jian-Gang Xu
Summary: Balancing energy and mechanical sensitivities is a challenging issue in the field of energetic materials. This study constructed a 3D energetic metal-organic framework with nitrogen-rich ligand and NO3- anions. The framework demonstrated high stability, energy density, and excellent mechanical sensitivities, making it a potential insensitive energetic material.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Marrium Saeed, Urooj Kamran, Amina Khan, Md Irfanul Haque Siddiqui, Hasan Jamal, Haq Nawaz Bhatti
Summary: In this study, magnesium-aluminum layered double hydroxides (Mg-Al-LDH) were synthesized using an environmentally friendly hydrothermal technique for adsorbing the dye reactive green 5 (RG5). To improve the adsorption capability, composites were prepared by combining Mg-Al-LDH with low-cost Mangifera indica stone biomass (MISB). The results showed that the composites had high adsorption capacities for RG5 dye and could be regenerated.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Xuanlin Zhan, Xiaojie Li, Yunyan Zeng, Siyan Jiang, Chao Pan, Shiyu Pan, Jiaquan Huang, Heqian Zhang, Zhiwei Qin
Summary: This study reports on the potential prospects of natural products derived from the rhizosphere for the development of antibiotics and herbicides, as well as the advancements in cultivating a mutant strain that produces a substantial quantity of lydicamycins, a potent family for herbicide development.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Jie Zhu, Jiangtao Yu, Linhua Zhu, Xiaoxiao Yu, Jixing Liu, Yanhong Chao, Jingzhou Yin, Peiwen Wu, Jian Liu, Wenshuai Zhu
Summary: This study successfully demonstrates the 3D printing of attapulgite monoliths and investigates the influence of thermal treatment on their properties. The thermal treated monoliths show superior catalytic performance at low temperatures.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yanzhu Ye, Yixiang Ye, Jiannan Cai, Zhongshui Li, Shen Lin
Summary: In this paper, a novel Pt/CoP/C photo-electro synergistic catalyst was successfully synthesized and its performance was investigated. The catalyst exhibited excellent photo-electro catalytic performance, with significantly higher hydrogen production compared to a commercial catalyst. The introduction of cobalt phosphide and the existence of Co3O4 were identified as key factors for enhancing the catalytic activity.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Nurul Hidayah Abu Bakar, Wan Norfazilah Wan Ismail, Hartina Mohd Yusop, Noreen Farzuhana Mohd Zulkifli
Summary: Hydrophobic coatings inspired by the lotus effect have gained popularity for their ability to solve various problems. The sol-gel method, utilizing silica, alumina, and titania, is explored as an environmentally friendly approach to produce water-based hydrophobic coatings. This study focuses on producing water-based hydrophobic coatings for cotton and polyester fabrics using a one-step sol-gel method. The coated fabrics exhibited improved hydrophobic properties, altered surface morphologies, and lower air permeability compared to uncoated fabrics. TEOS-PDMS coating provides a promising approach for enhancing the hydrophobic and surface properties of cotton and polyester fabrics.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Nikita Belko, Hanna Maltanava, Anatol Lugovski, Polina Shabunya, Sviatlana Fatykhava, Evgeny Bondarenko, Pavel Chulkin, Sergey Poznyak, Michael Samtsov
Summary: This study investigates the difference in electrochemical behavior between rhodamine B hydrazide and rhodamine B acylhydrazone, and finds that rhodamine B acylhydrazone exhibits higher reversibility in electrooxidation. These results can be applied for developing new sensors with desired electrochemical properties.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Showket Ahmad Bhat, Mohd Ikram
Summary: In this study, 0-3 particulate multiferroic composites were synthesized and characterized. The composites exhibited excellent ferroelectric and ferromagnetic properties, as well as high piezoelectric strain and magnetoelectric coupling effects.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Carla Gomes, Mariana Costa, Susana M. M. Lopes, Bernardo Albuquerque Nogueira, Rui Fausto, Jose A. Paixao, Teresa M. V. D. e Melo, Luisa M. D. R. S. Martins, Marta Pineiro
Summary: The development of sustainable processes requires the integration of green chemistry principles. In this study, a solvent-free synthesis method was developed to prepare new copper catalysts, which efficiently catalyze cycloaddition reactions under solvent-free mechanochemical conditions. Through this process, the principles of atom economy, reduction of solvents and auxiliaries, design for energy efficiency, and reduction of derivatives and catalysis are combined.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Zhihua Liu, Jinzhe Li, Jianguo Zhou
Summary: This study demonstrates the enhancement of photoelectrochemical activity of BiFeO3 photoelectrodes through ion modification, which increases visible light absorption and active area, leading to improved PEC water splitting performance.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yisheng Zhang, Wensong Li, Jing Li, Fang Li, Wei Xue, Xinqiang Zhao, Yanji Wang
Summary: Pt/C and SO42-/ZrO2 were used as catalysts for the synthesis of p-aminophenol through the catalytic transfer hydrogenation of nitrobenzene in water with formic acid as the hydrogen source. The optimal Pt loading for PAP selectivity was found to be 1 wt%. The presence of different valence states of Pt affected both the nitrobenzene hydrogenation and formic acid decomposition. Among different solid acid catalysts tested, SO42-/ZrO2 exhibited the highest catalytic activity for p-aminophenol formation. Under the optimized reaction conditions, the conversion of nitrobenzene reached 80.0%, with a selectivity of 47.6% for p-aminophenol.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Pradyota Kumar Behera, Papita Behera, Amlan Swain, Santosh Kumar Sahu, Ajeena Sahoo, Laxmidhar Rout
Summary: We have developed a simple and direct method for the synthesis of diaryl ether using an oxygen bridged bimetallic CuMoO4 nanocatalyst under mild reaction conditions. The catalyst exhibited tolerance towards a wide range of substrates with various functional groups. It is efficient and recyclable. This methodology allows easy access to nitrofen derivatives (herbicides) from unactivated 2,4-dichlorophenol, which are important for agriculture and pharmaceuticals.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Yihua Fu, Yan Zhang, Changwei Hu, Zhishan Su
Summary: The mechanism of the reaction between CO2 and styrene oxide for cyclic carbonate was revealed using density functional theory calculations. The noncatalytic reaction occurred via a concerted mechanism, while in the presence of guanidine and tetrabutylammonium iodide (TBAI) co-catalysts, the epoxide ring-opening by nucleophilic attack of an iodide anion was predicted to be the rate-determining step. Guanidine acted as the H-bond donor to activate styrene oxide, facilitating the reaction with a lower activation barrier.
NEW JOURNAL OF CHEMISTRY
(2024)
Article
Chemistry, Multidisciplinary
Saikat Khamarui, Sirshendu Ghosh
Summary: Copper nanorods (Cu-NRs) exhibit significant plasmonic behavior and can act as efficient catalysts in redox processes and coupling. A benign decarboxylative approach, utilizing localized surface plasmon resonance (LSPR) assisted catalysis with Cu-NRs, has been developed for the production of alkane analogues from alkyl carboxylic acids under visible light. The catalyst shows a broad substrate scope and high functional group tolerance, without the need for an external oxidant or proton source. A plausible mechanism for this recyclable nano-catalyst has also been proposed based on control experiments.
NEW JOURNAL OF CHEMISTRY
(2024)
