Diffusion in nanoporous materials: fundamental principles, insights and challenges

The predictive power of classical transition state theory revealed in diffusion studies with MOF ZIF-8

(2016) Christian Chmelik et al.   MICROPOROUS AND MESOPOROUS MATERIALS

Microimaging of Transient Concentration Profiles of Reactant and Product Molecules during Catalytic Conversion in Nanoporous Materials

(2015) Tobias Titze et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Optimizing spatial pore-size and porosity distributions of adsorbents for enhanced adsorption and desorption performance

(2015) Guanghua Ye et al.   CHEMICAL ENGINEERING SCIENCE

Uphill diffusion in multicomponent mixtures

(2015) Rajamani Krishna   CHEMICAL SOCIETY REVIEWS

Mesopore-Promoted Transport in Microporous Materials

(2015) Daniel Schneider et al.   CHEMIE INGENIEUR TECHNIK

2D Surface Structures in Small Zeolite MFI Crystals

(2015) Andrew R. Teixeira et al.   CHEMISTRY OF MATERIALS

Development of a Semiautomated Zero Length Column Technique for Carbon Capture Applications: Rapid Capacity Ranking of Novel Adsorbents

(2015) Xiayi Hu et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Relationship between long-range diffusion and diffusion in the ZIF-8 and polymer phases of a mixed-matrix membrane by high field NMR diffusometry

(2015) Robert Mueller et al.   JOURNAL OF MEMBRANE SCIENCE

Mesoporous mordenites obtained by desilication: Mechanistic considerations and evaluation in catalytic oligomerization of pentene

(2015) Chloé Bertrand-Drira et al.   MICROPOROUS AND MESOPOROUS MATERIALS

The role of crystal diversity in understanding mass transfer in nanoporous materials

(2015) Julien Cousin Saint Remi et al.   NATURE MATERIALS

Uphill diffusion and overshooting in the adsorption of binary mixtures in nanoporous solids

(2015) Alexander Lauerer et al.   Nature Communications

Transport Phenomena in Nanoporous Materials

(2014) Jörg Kärger   CHEMPHYSCHEM

On Asymmetric Surface Barriers in MFI Zeolites Revealed by Frequency Response

(2014) Andrew R. Teixeira et al.   Journal of Physical Chemistry C

Uncommon Synergy between Adsorption and Diffusion of Hexane Isomer Mixtures in MFI Zeolite Induced by Configurational Entropy Effects

(2014) Tobias Titze et al.   Journal of Physical Chemistry C

Diffusion of Light Hydrocarbons in the Flexible MIL-53(Cr) Metal–Organic Framework: A Combination of Quasi-Elastic Neutron Scattering Experiments and Molecular Dynamics Simulations

(2014) N. Rosenbach et al.   Journal of Physical Chemistry C

Microimaging of transient guest profiles to monitor mass transfer in nanoporous materials

(2014) Jörg Kärger et al.   NATURE MATERIALS

Editorial overview: Reaction engineering and catalysis—A multi-scale, integrated approach

(2014) Marc-Olivier Coppens et al.   Current Opinion in Chemical Engineering

Superior Mass Transfer Properties of Technical Zeolite Bodies with Hierarchical Porosity

(2013) Laurent Gueudré et al.   ADVANCED FUNCTIONAL MATERIALS

Mesoporosity – a new dimension for zeolites

(2013) Karin Möller et al.   CHEMICAL SOCIETY REVIEWS

Mass transfer in mesoporous materials: the benefit of microscopic diffusion measurement

(2013) Jörg Kärger et al.   CHEMICAL SOCIETY REVIEWS

Transport into Nanosheets: Diffusion Equations Put to Test

(2013) Nils E. R. Zimmermann et al.   Journal of Physical Chemistry C

Molecular Simulation of Adsorption and Transport in Hierarchical Porous Materials

(2013) Benoit Coasne et al.   LANGMUIR

Signatures of normal and anomalous diffusion in nanotube systems by NMR

(2013) M. Dvoyashkin et al.   MICROPOROUS AND MESOPOROUS MATERIALS

A diffusion study of small hydrocarbons in DDR zeolites by micro-imaging

(2013) Tomas Binder et al.   MICROPOROUS AND MESOPOROUS MATERIALS

The Maxwell–Stefan description of mixture diffusion in nanoporous crystalline materials

(2013) Rajamani Krishna   MICROPOROUS AND MESOPOROUS MATERIALS

Adsorption and desorption surface dynamics of gaseous adsorbate on silicate-1 by molecular dynamics simulation

(2013) Jean-Marc Simon et al.   MOLECULAR SIMULATION

No-go theorem for ergodicity and an Einstein relation

(2013) D. Froemberg et al.   PHYSICAL REVIEW E

Diffusion Study by IR Micro-Imaging of Molecular Uptake and Release on Mesoporous Zeolites of Structure Type CHA and LTA

(2013) Mauricio Bonilla et al.   Materials

The Mechanism of Pseudomorphic Transformation of Spherical Silica Gel into MCM-41 Studied by PFG NMR Diffusometry

(2013) Wolf-Dietrich Einicke et al.   Materials

Transport into Metal-Organic Frameworks from Solution Is Not Purely Diffusive

(2012) Shuangbing Han et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diffusion in porous crystalline materials

(2012) Rajamani Krishna   CHEMICAL SOCIETY REVIEWS

Micro–mesoporous materials obtained by zeoliterecrystallization: synthesis, characterization and catalytic applications

(2012) Irina I. Ivanova et al.   CHEMICAL SOCIETY REVIEWS

Intracrystalline Diffusion in Mesoporous Zeolites

(2012) Dirk Mehlhorn et al.   CHEMPHYSCHEM

Hindering effects in diffusion of CO2/CH4 mixtures in ZIF-8 crystals

(2012) Christian Chmelik et al.   JOURNAL OF MEMBRANE SCIENCE

Surface Barriers of Hydrocarbon Transport Triggered by Ideal Zeolite Structures

(2012) Nils E. R. Zimmermann et al.   Journal of Physical Chemistry C

Monitoring Molecular Mass Transfer in Cation-Free Nanoporous Host Crystals of Type AlPO-LTA

(2012) Florian Hibbe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diffusion in Hierarchical Mesoporous Materials: Applicability and Generalization of the Fast-Exchange Diffusion Model

(2012) P. Zeigermann et al.   LANGMUIR

Carbon templated SAPO-34 with improved adsorption kinetics and catalytic performance in the MTO-reaction

(2012) Franz Schmidt et al.   MICROPOROUS AND MESOPOROUS MATERIALS

Exploring the hierarchy of transport phenomena in hierarchical pore systems by NMR diffusion measurement

(2012) Dirk Mehlhorn et al.   MICROPOROUS AND MESOPOROUS MATERIALS

Micro-Imaging by Interference Microscopy: A Case Study of Orientation-Dependent Guest Diffusion in MFI-Type Zeolite Host Crystals

(2012) Laurent Gueudré et al.   Materials

A nature-inspired approach to reactor and catalysis engineering

(2012) Marc-Olivier Coppens   Current Opinion in Chemical Engineering

Single-Particle and Ensemble Diffusivities-Test of Ergodicity

(2011) Florian Feil et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Increasing robustness against deactivation of nanoporous catalysts by introducing an optimized hierarchical pore network—Application to hydrodemetalation

(2011) Sanjeev M. Rao et al.   CHEMICAL ENGINEERING SCIENCE

Nanoporous Glass as a Model System for a Consistency Check of the Different Techniques of Diffusion Measurement

(2011) Christian Chmelik et al.   CHEMPHYSCHEM

Influence of Zeolite Surface in the Sorption of Methane from Molecular Dynamics

(2011) Aldo F. Combariza et al.   Journal of Physical Chemistry C

Exploration of the Long-Chain N-Alkanes Adsorption and Diffusion in the MOF-Type MIL-47 (V) Material by Combining Experimental and Molecular Simulation Tools

(2011) I. Déroche et al.   Journal of Physical Chemistry C

The Nature of Surface Barriers on Nanoporous Solids Explored by Microimaging of Transient Guest Distributions

(2011) Florian Hibbe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multicomponent Effective Medium–Correlated Random Walk Theory for the Diffusion of Fluid Mixtures through Porous Media

(2011) Mauricio R. Bonilla et al.   LANGMUIR

Influence of crystal size and probe molecule on diffusion in hierarchical ZSM-5 zeolites prepared by desilication

(2011) Frederic C. Meunier et al.   MICROPOROUS AND MESOPOROUS MATERIALS

Correlating Surface Permeability with Intracrystalline Diffusivity in Nanoporous Solids

(2011) Lars Heinke et al.   PHYSICAL REVIEW LETTERS

In situ study on molecular diffusion phenomena in nanoporous catalytic solids

(2010) Christian Chmelik et al.   CHEMICAL SOCIETY REVIEWS

Role of the Surface Modification on the Transport of Hexane Isomers in ZSM-5

(2010) O. C. Gobin et al.   Journal of Physical Chemistry C

Chromatography in a Single Metal−Organic Framework (MOF) Crystal

(2010) Shuangbing Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ethane/Ethene Separation Turned on Its Head: Selective Ethane Adsorption on the Metal−Organic Framework ZIF-7 through a Gate-Opening Mechanism

(2010) Canan Gücüyener et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mass Transfer in a Nanoscale Material Enhanced by an Opposing Flux

(2010) Christian Chmelik et al.   PHYSICAL REVIEW LETTERS

Assessing Surface Permeabilities from Transient Guest Profiles in Nanoporous Host Materials

(2009) Despina Tzoulaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemical Imaging of Spatial Heterogeneities in Catalytic Solids at Different Length and Time Scales

(2009) Bert M. Weckhuysen   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Functionalized Inorganic Monolithic Microreactors for High Productivity in Fine Chemicals Catalytic Synthesis

(2009) Abdelkrim El Kadib et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rational design of hierarchically structured porous catalysts for autothermal reforming of methane

(2009) Gang Wang et al.   CHEMICAL ENGINEERING SCIENCE

Large breathing effects in three-dimensional porous hybrid matter: facts, analyses, rules and consequences

(2009) Gérard Férey et al.   CHEMICAL SOCIETY REVIEWS

Generation of Mesoporosity in LTA Zeolites by Organosilane Surfactant for Rapid Molecular Transport in Catalytic Application

(2009) Kanghee Cho et al.   CHEMISTRY OF MATERIALS

Ensemble Measurement of Diffusion: Novel Beauty and Evidence

(2009) Christian Chmelik et al.   CHEMPHYSCHEM

Intracrystalline Transport Resistances in Nanoporous Zeolite X

(2009) Armin Feldhoff et al.   CHEMPHYSCHEM

Influence of Postsynthetic Surface Modification on Shape Selective Transport of Aromatic Molecules in HZSM-5

(2009) S. J. Reitmeier et al.   Journal of Physical Chemistry C

On the Effects of the External Surface on the Equilibrium Transport in Zeolite Crystals

(2009) N. E. R. Zimmermann et al.   Journal of Physical Chemistry C

Dynamic Monte Carlo simulations of binary self-diffusion in ZSM-5

(2009) Xin Liu et al.   MICROPOROUS AND MESOPOROUS MATERIALS

Effects of Self-Assembly on Diffusion Mechanisms of Triblock Copolymers in Aqueous Solution

(2009) Konstantin Ulrich et al.   PHYSICAL REVIEW LETTERS

Enhancement of Sorption Processes in the Zeolite H-ZSM5 by Postsynthetic Surface Modification

(2008) Stephan J. Reitmeier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrocarbon Adsorption in the Flexible Metal Organic Frameworks MIL-53(Al, Cr)

(2008) Thuy Khuong Trung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nonergodicity Mimics Inhomogeneity in Single Particle Tracking

(2008) Ariel Lubelski et al.   PHYSICAL REVIEW LETTERS