Copper(I) Complexes Bearing Carbenes Beyond Classical N-Heterocyclic Carbenes: Synthesis and Catalytic Activity in “Click Chemistry”

Air-Stable (CAAC)CuCl and (CAAC)CuBH4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH3 NH3

(2015) Xingbang Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A simple access to transition metal cyclopropenylidene complexes

(2015) Yannick D. Bidal et al.   CHEMICAL COMMUNICATIONS

Isolation of Neutral Mononuclear Copper Complexes Stabilized by Two Cyclic (Alkyl)(amino)carbenes

(2014) David S. Weinberger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Abnormal N-Heterocyclic Carbene-Copper(I) Complex in Click Chemistry

(2013) Samaresh Chandra Sau et al.   ADVANCED SYNTHESIS & CATALYSIS

31P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes

(2013) Olivier Back et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Advancements in the mechanistic understanding of the copper-catalyzed azide–alkyne cycloaddition

(2013) Regina Berg et al.   Beilstein Journal of Organic Chemistry

A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes

(2013) Orlando Santoro et al.   CHEMICAL COMMUNICATIONS

Quantifying and understanding the electronic properties of N-heterocyclic carbenes

(2013) David J. Nelson et al.   CHEMICAL SOCIETY REVIEWS

Simplified Preparation of Copper(I) NHCs Using Aqueous Ammonia

(2013) Clémentine Gibard et al.   ORGANOMETALLICS

Are Cu(I)-mesoionic NHC carbenes associated with nitrogen additives the best Cu-carbene catalysts for the azide–alkyne click reaction in solution? A case study

(2013) Stephan Hohloch et al.   TETRAHEDRON LETTERS

Copper N-heterocyclic carbene complexes in catalysis

(2013) Jonathan D. Egbert et al.   Catalysis Science & Technology

Ynamides: stable ligand equivalents of unstable oxazol-4-ylidenes (novel mesoionic carbenes)

(2012) Gaël Ung et al.   CHEMICAL COMMUNICATIONS

Application of 1,2,3-triazolylidenes as versatile NHC-type ligands: synthesis, properties, and application in catalysis and beyond

(2012) Kate F. Donnelly et al.   CHEMICAL COMMUNICATIONS

Anionic 1,2,3-Triazole-4,5-diylidene: A 1,2-Dihapto Ligand for the Construction of Bimetallic Complexes

(2012) Xiaoyu Yan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Abnormal, mesoionic and remote N-heterocyclic carbene complexes

(2012) Robert H. Crabtree   COORDINATION CHEMISTRY REVIEWS

New catalysts with unsymmetrical N-heterocyclic carbene ligands

(2012) Johanna Tornatzky et al.   DALTON TRANSACTIONS

Microwave-Assisted Synthesis of (N-Heterocyclic carbene)MCl Complexes of Group 11 Metals

(2012) Brant Landers et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Electronic Structural Trends in Divalent Carbon Compounds

(2012) Han Vinh Huynh et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct C–H Carboxylation with Carbon Dioxide Using 1,2,3-Triazol-5-ylidene Copper(I) Complexes

(2012) Hiroshi Inomata et al.   ORGANIC LETTERS

Steric Control at the Wingtip of a Bis-N-Heterocyclic Carbene Ligand: Coordination Behavior and Catalytic Responses of Its Ruthenium Compounds

(2012) Sayantani Saha et al.   ORGANOMETALLICS

Pyrazolin-5-ylidene Palladium(II) Complexes: Synthesis, Characterization, and Application in the Direct Arylation of Pentafluorobenzene

(2012) Jan C. Bernhammer et al.   ORGANOMETALLICS

A direct and practical approach for the synthesis of N-heterocyclic carbene coinage metal complexes

(2012) Shifa Zhu et al.   TETRAHEDRON

N-Heterocyclic Carbene Gold(I) and Copper(I) Complexes in C–H Bond Activation

(2011) Sylvain Gaillard et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Stable Acyclic Ligand Equivalent of an Unstable 1,3-Dithiol-5-ylidene

(2011) Gaël Ung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mesoionic thiazol-5-ylidenes as ligands for transition metal complexes

(2011) Daniel Mendoza-Espinosa et al.   CHEMICAL COMMUNICATIONS

Abnormal NHC Palladium Complexes: Synthesis, Structure, and Reactivity

(2011) Aurelie Poulain et al.   CURRENT ORGANIC CHEMISTRY

Copper(I) Complexes of Normal and Abnormal Carbenes and Their Use as Catalysts for the Huisgen [3+2] Cycloaddition between Azides and Alkynes

(2011) Stephan Hohloch et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Protonolysis of a Ruthenium–Carbene Bond and Applications in Olefin Metathesis

(2011) Benjamin K. Keitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I) 1,2,3-Triazol-5-ylidene Complexes as Efficient Catalysts for Click Reactions of Azides with Alkynes

(2011) Tatsuhito Nakamura et al.   ORGANIC LETTERS

Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and Their Applications in Ruthenium-Catalyzed Olefin Metathesis

(2011) Jean Bouffard et al.   ORGANOMETALLICS

Influence of a Very BulkyN-Heterocyclic Carbene in Gold-Mediated Catalysis

(2011) Adrián Gómez-Suárez et al.   ORGANOMETALLICS

A Brief Survey of Our Contribution to Stable Carbene Chemistry

(2011) David Martin et al.   ORGANOMETALLICS

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Measure of All Rings-N-Heterocyclic Carbenes

(2010) Thomas Dröge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Crystalline 1H-1,2,3-Triazol-5-ylidenes: New Stable Mesoionic Carbenes (MICs)

(2010) Gregorio Guisado-Barrios et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Click chemistry: function follows form

(2010) M. G. Finn et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of a Room-Temperature-Stable Dimeric Copper(I) Hydride

(2010) Guido D. Frey et al.   Chemistry-An Asian Journal

Expanding the family of mesoionic complexes: donor properties and catalytic impact of palladated isoxazolylidenes

(2010) Manuel Iglesias et al.   DALTON TRANSACTIONS

Simple and versatile synthesis of copper and silver N-heterocyclic carbene complexes in water or organic solvents

(2010) Cécilia A. Citadelle et al.   DALTON TRANSACTIONS

[(NHC)CuX] complexes: Synthesis, characterization and catalytic activities in reduction reactions and Click Chemistry. On the advantage of using well-defined catalytic systems

(2010) Silvia Díez-González et al.   DALTON TRANSACTIONS

Aromatic Nitrogen Donors for Efficient Copper(I)-NHC CuAAC under Reductant-Free Conditions

(2010) Marie-Laure Teyssot et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist

(2010) Gregory R. Fulmer et al.   ORGANOMETALLICS

Beyond ConventionalN-Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization

(2009) Oliver Schuster et al.   CHEMICAL REVIEWS

Carbenes Introduction

(2009) Anthony J. Arduengo et al.   CHEMICAL REVIEWS

Coinage Metal−N-Heterocyclic Carbene Complexes

(2009) Joseph C. Y. Lin et al.   CHEMICAL REVIEWS

Improved Copper(I)-NHC Catalytic Efficiency on Huisgen Reaction by Addition of Aromatic Nitrogen Donors

(2009) Marie-Laure Teyssot et al.   CHEMISTRY-A EUROPEAN JOURNAL

N-heterocyclic carbenes bearing two, one and no nitrogen atoms at the ylidene carbon: insight from theoretical calculations

(2009) Aleksandr A. Tukov et al.   DALTON TRANSACTIONS

Palladium(II) Pyrazolin-4-ylidenes: Substituent Effects on the Formation and Catalytic Activity of Pyrazole-Based Remote NHC Complexes

(2009) Yuan Han et al.   ORGANOMETALLICS

Electronic and Steric Parameters of 76 N-Heterocyclic Carbenes in Ni(CO)3(NHC)

(2009) Dmitry G. Gusev   ORGANOMETALLICS

Isolation of a C5-Deprotonated Imidazolium, a Crystalline "Abnormal" N-Heterocyclic Carbene

(2009) E. Aldeco-Perez et al.   SCIENCE

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A [(NHC)CuCl] complex as a latent Click catalyst

(2008) Silvia Díez-González et al.   CHEMICAL COMMUNICATIONS

C4-bound imidazolylidenes: from curiosities to high-impact carbene ligands

(2008) Martin Albrecht   CHEMICAL COMMUNICATIONS

Cu-Catalyzed Azide−Alkyne Cycloaddition

(2008) Morten Meldal et al.   CHEMICAL REVIEWS

Carbenes: Synthesis, properties, and organometallic chemistry

(2008) Pierre de Frémont et al.   COORDINATION CHEMISTRY REVIEWS

Preparation of a Series of “Ru(p-cymene)” Complexes with Different N-Heterocyclic Carbene Ligands for the Catalytic β-Alkylation of Secondary Alcohols and Dimerization of Phenylacetylene

(2008) Amparo Prades et al.   ORGANOMETALLICS

SiO2–NHC–Cu(I): an efficient and reusable catalyst for [3+2] cycloaddition of organic azides and terminal alkynes under solvent-free reaction conditions at room temperature

(2008) Pinhua Li et al.   TETRAHEDRON