Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 357, Issue 2-3, Pages 463-473Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201400931
Keywords
C-C coupling; C-H activation; oxidative Heck reaction; palladium; quinolones
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Funding
- Ministerio de Economia y Competitividad [CTQ2013-41229-P]
- Gobierno Vasco [IT-623-13]
- Universidad del Pais Vasco/Euskal Herriko Unibertsitatea UPV/EHU [UFI11/22, PPM12/03]
- Gobierno Vasco
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Highly substituted quinolones are obtained through an efficient and atom economical procedure that involves two consecutive palladium(II)-catalyzed C-H alkenylation reactions. A selective 6-endo intramolecular C-H alkenylation leads to 4-substituted quinolones that have been further functional-ized at C-3 through a second intermolecular C-H alkenylation reaction.
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