4.6 Article

Exploration of Dimethylzinc-Mediated Radical Reactions

Journal

CHEMICAL RECORD
Volume 15, Issue 5, Pages 854-871

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.201500017

Keywords

carbon-carbon bond formation; C(sp(3))-H bond functionalization; dimethylzinc; radical reactions; umpolung

Funding

  1. Japan Society for Promotion of Science
  2. Ministry of Education, Culture, Sports, Science and Technology, Japan
  3. Grants-in-Aid for Scientific Research [24590035, 26460005, 26105732] Funding Source: KAKEN

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In this account, our studies on radical reactions that are promoted by dimethylzinc and air are described. Advantages of this reagent and differences from conventional radical initiators, such as triethylborane, are discussed.

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