Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 357, Issue 16-17, Pages 3463-3468Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201500700
Keywords
carbon monoxide equivalent; imidazoles; indoles; molybdenum; palladium
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Funding
- University of Illinois at Chicago
- Office of the Vice-Chancellor for Research, Huaqiao University
- Fujian Hundred Talents Program
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The development of a method that employs a two-chamber reaction vessel and uses molybdenum hexacarbonyl [Mo(CO)(6)] as the carbon monoxide (CO) source for the palladium-catalyzed transformation of nitroarenes into indoles or imidazoles is reported. The scope and limitations of our method are illustrated with 23 examples. Experiments that indicate the mechanism of the C-H bond amination reaction to be stepwise are also reported.
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