Journal
CHEMICAL PHYSICS LETTERS
Volume 633, Issue -, Pages 190-194Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2015.05.038
Keywords
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Funding
- Japan Society for the Promotion of Science (JSPS) [24310090]
- Ministry of Education, Culture, Sports, Science, and Technology of Japan (MEXT) [2401, 24102014, 25102516]
- Grants-in-Aid for Scientific Research [25102516, 24102014] Funding Source: KAKEN
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Carborane-substituted triphenylamines were prepared to demonstrate the effective fluorescent enhancement of triphenylamine as a typical non-fluorescent pi-conjugated compound on the basis of molecular design to suppress the non-radiative decay by reduced vibronic coupling. Non-fluorescent carborane substituents work to reduce only the HOMO distribution in the non-fluorescent parent pi-conjugated core, thereby leading to increase in fluorescence quantum yield by suppressing internal conversion. (C) 2015 Elsevier B.V. All rights reserved.
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