4.3 Article

Superparamagnetism of Artificial Glasses Based on Rocks: Experimental Data and Theoretical Modeling

Journal

MAGNETOCHEMISTRY
Volume 9, Issue 10, Pages -

Publisher

MDPI
DOI: 10.3390/magnetochemistry9100220

Keywords

artificial glasses; rocks; superparamagnetism; nanoparticles; magnetometry; magnetite; hematite; micromagnetic modeling; two-phase particles; magnetostatic interaction

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Artificial glasses containing nanoscale inclusions of iron oxides, including magnetite and hematite, were obtained through high-temperature melting of rocks. The magnetic properties of the glasses are influenced by the initial composition of the charge and the cooling conditions. Analysis of magnetic granulometry and frequency-field dependencies showed a significant presence of superparamagnetic fraction in the samples. Coordinated theoretical modeling using two independent models allowed for the calculation of hysteresis characteristics matching the experiment and the estimation of ferrimagnetic concentrations, including the superparamagnetic fraction, in the samples.
Artificial glasses containing nanoscale inclusions of iron oxides, including magnetite and hematite, were obtained via the method of the high-temperature melting of rocks. The main factors influencing the magnetic properties of glasses are the composition of the initial charge and the conditions of cooling of the melt. The data of magnetic granulometry and frequency-field dependencies of magnetic susceptibility showed the presence of a sufficiently large superparamagnetic fraction in the samples. Coordinated theoretical modeling using two independent models that take into consideration possible the chemical inhomogeneity of particles and magnetostatic interaction between them made it possible to calculate hysteresis characteristics corresponding to the experiment and to estimate ferrimagnetic concentrations in the samples, including the superparamagnetic fraction.

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