Journal
CHEMICAL ENGINEERING SCIENCE
Volume 135, Issue -, Pages 193-201Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ces.2015.04.034
Keywords
CO2 reduction; Reverse water gas shift; Bimetallic nanoparticles; Palladium; In2O3; DFT
Categories
Funding
- National Natural Science Foundation of China [91334206]
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A Pd-In/SiO2 catalyst was prepared by the wet impregnation method and used for CO2 reduction at atmospheric pressure. The catalyst was shown to have 100% selectivity toward CO with no detectable CH4 formation. In order to understand the high CO selectivity of Pd-In/SiO2, a detailed catalyst characterization in combination with the DFT study was conducted and compared with that over the Pd/SiO2 catalyst. The XRD and TEM analyses indicate the formation of the PdIn bimetallic nanoparticles on Pd-In/SiO2 after H-2 reduction. The unique catalytic property of Pd-In/SiO2 was attributed to the formation of the bimetallic particles. Characterizations including H-2 chemisorption and DRIFT and DFT modeling show that the formation of PdIn bimetallic nanoparticles reduces the activity toward H-2 dissociative adsorption, weakens CO binding on the surface and increases the barrier of CO hydrogenation, suppressing the further hydrogenation beyond CO. (C) 2015 Elsevier Ltd. All rights reserved.
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